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Self-Stabilized Blue Phases Formed by Bent-Core Liquid Crystals: Physical Properties for Device Applications

Research Project

Project/Area Number 26810108
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Organic and hybrid materials
Research InstitutionTokyo University of Science (2015)
The Institute of Physical and Chemical Research (2014)

Principal Investigator

Le Khoa  東京理科大学, 理学部, 助教 (90725334)

Project Period (FY) 2014-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2015: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2014: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywordsブルー相 / バナナ形液晶 / 応答速度 / カー効果
Outline of Final Research Achievements

Blue phase liquid crystals have attracted much attention in recent years for their potential applications in ultrafast-responsive displays and light modulation devices. Aiming for device applications, in this work the electro-optic response in a bent-core liquid crystal which shows a stable amorphous blue phase (BPIII) over 15℃ was investigated. It is found that the response time is on the order of hundreds of microseconds in the isotropic phase and increases to 1-2 ms in the BPIII, then drastically increases up to a few tens of milliseconds upon further cooling in the BPIII. The material also shows a very large electric-field-induced birefringence (Kerr constant).Such an unusual behavior was explained on the basis of the existence of nanoscale smectic clusters.

Report

(3 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • Research Products

    (6 results)

All 2016 2015 2014

All Journal Article (4 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 4 results,  Acknowledgement Compliant: 1 results) Presentation (2 results)

  • [Journal Article] Unusual electro-optic Kerr response in a self-stabilized amorphous blue phase with nanoscale smectic clusters2016

    • Author(s)
      K. V. Le, M. Hafuri, H. Ocak, B. Bilgin-Eran, C. Tschierske, T. Sasaki, F. Araoka
    • Journal Title

      ChemPhysChem

      Volume: 印刷中 Issue: 10 Pages: 1425-1429

    • DOI

      10.1002/cphc.201501206

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Dismantlable thermosetting adhesives composed of a cross-linkable poly(olefin sulfone) with a photobase generator2016

    • Author(s)
      T. Sasaki, S. Hashimoto, N. Nogami, Y. Sugiyama, M. Mori, Y. Naka, K. V. Le
    • Journal Title

      ACS Appl. Mater. Interfaces

      Volume: 8 Issue: 8 Pages: 5580-5585

    • DOI

      10.1021/acsami.5b10110

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Large twist elastic constant in diphenylacetylene-core-based liquid crystals2015

    • Author(s)
      K. V. Le, S. Aya, S. Ogino, K. Okano, F. Araoka, H. Takezoe
    • Journal Title

      Mol. Cryst. Liq. Cryst.

      Volume: 614 Issue: 1 Pages: 124-127

    • DOI

      10.1080/15421406.2015.1050289

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structure-sensitive bend elastic constants between piconewton and subnanonewton in diphenylacetylene-core-based liquid crystals2014

    • Author(s)
      S. Aya, S. Ogino, Y. Hayashi, K. Okano, D. Pociecha, K. V. Le, F. Araoka, S. Kawauchi, E. Gorecka, N. Vaupotic, H. Takezoe, K. Ishikawa
    • Journal Title

      Phys.Rev.E

      Volume: 90 Issue: 4

    • DOI

      10.1103/physreve.90.042506

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Presentation] レゾルシノール誘導体からなるバナナ形液晶ブルー相の電気光学特性2015

    • Author(s)
      レバンコア, Tschierske Carsten, 佐々木健夫, 荒岡史人
    • Organizer
      2015年日本液晶学会討論会
    • Place of Presentation
      東京工業大学 すずかけ台キャンパス(神奈川県横浜市)
    • Year and Date
      2015-09-07
    • Related Report
      2015 Annual Research Report
  • [Presentation] Switching dynamics in isotropic phase and “foggy” blue phase of a chiral bent-core liquid crystal2014

    • Author(s)
      K. V. Le, H. Ocak, C. Tschierske, F. Araoka
    • Organizer
      25th International Liquid Crystal Conference (ILCC2014)
    • Place of Presentation
      Trinity College Dublin, Dublin 2, Ireland
    • Year and Date
      2014-06-29 – 2014-07-04
    • Related Report
      2014 Research-status Report

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Published: 2014-04-04   Modified: 2017-05-10  

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