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Development of Napthodithiophenediimide(NDTI)-based organic semiconducting materials

Research Project

Project/Area Number 26810109
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Organic and hybrid materials
Research InstitutionInstitute of Physical and Chemical Research

Principal Investigator

Masahiro Nakano  国立研究開発法人理化学研究所, 創発物性科学研究センター, 特別研究員 (80724822)

Project Period (FY) 2014-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2015: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2014: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywords有機半導体 / n型材料 / 両極性材料 / 有機トランジスタ / 有機薄膜太陽電池 / 有機熱電変換 / n型半導体 / 有機薄膜トランジスタ / 導電性高分子 / 熱電変換
Outline of Final Research Achievements

Organic semiconducting material is a key for the development of next-generation electronic devices, such as wearable and printable devices, owing to its high flexibility, lightweight, and ease of processing. Nowadays, p-type semiconducting materials with high mobility which is higher than that of amorphous silicon. On the other hand, the mobility of n-type semiconducting materials are still limited.
The purpose of this project is to develop n-type organic semiconducting materials with high-performance using naphthodithiophene diimide (NDTI) to apply them in organic fileld effect transistor (OFET), organic photovoltaics (OPV), and CMOS-like logic circuits. As a result, NDTI-based n-type OFET and OPV materials wigh good mobilty or photocurrent efficiency were reported. Moreover we also developted NDTI-based conducting materials with high conductivity for thermoelectric devices.

Report

(3 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • Research Products

    (15 results)

All 2016 2015 2014

All Journal Article (6 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 6 results,  Open Access: 6 results,  Acknowledgement Compliant: 5 results) Presentation (9 results) (of which Int'l Joint Research: 3 results)

  • [Journal Article] Naphthodithiophene Diimide-Based Copolymers: Ambipolar Semiconductors in Field-Effect Transistors and Electron Acceptors with Near-Infrared Response in Polymer Blend Solar Cells2016

    • Author(s)
      K. Nakano, M. Nakano, B. Xiao, E. Zhou, K. Suzuki, K. Takimiya, K. Tajima
    • Journal Title

      Macromolecules

      Volume: 8 Issue: 5 Pages: 1752-1760

    • DOI

      10.1021/acs.macromol.5b02658

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Naphthodithiophenediimide (NDTI)-based traiads for high-performance air-stable, solution-processed ambipolar organic field-effect transistors2015

    • Author(s)
      J.-Y. Hu, M. Nakano, I. Osaka, K. Takimiya
    • Journal Title

      Journal of Materials Chemistry C

      Volume: 3 Issue: 17 Pages: 4244-4249

    • DOI

      10.1039/c5tc00486a

    • Related Report
      2015 Annual Research Report 2014 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] α-Modified naphthodithiophene diimides; molecular design strategy for air-stable n-channel organic semiconductors2015

    • Author(s)
      M. Nakano, I. Osaka, D. Hashizume, K. Takimiya
    • Journal Title

      Chemical of Materials

      Volume: 27 Issue: 18 Pages: 6418-3425

    • DOI

      10.1021/acs.chemmater.5b02601

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Naphthodithiophene diimide (NDTI)-based semiconducting copolymers: from ambipolar to unipolar n-type polymers2015

    • Author(s)
      M. Nakano, I. Osaka, K. Takimiya
    • Journal Title

      Macromolecules

      Volume: 48 Issue: 3 Pages: 576-584

    • DOI

      10.1021/ma502306f

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Dibenzo[a,e]pentalene-embedded dicyanomethylene-substituted thienoquinoidals for n-channel organic semiconductors: synthesis ,properties, and device characteristics2015

    • Author(s)
      M. Nakano, I. Osaka, K. Takimiya
    • Journal Title

      Journal of materials chemistry C

      Volume: 3 Issue: 2 Pages: 283-290

    • DOI

      10.1039/c4tc02164a

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Organic semiconductors based on [1]benzothieno[3,2-b][1]benzothiophene substructure2014

    • Author(s)
      K. Takimiya, I. Osaka, T. Mori, M. Nakano
    • Journal Title

      Accounts of chemical research

      Volume: 47 Issue: 5 Pages: 1493-1502

    • DOI

      10.1021/ar400282g

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Presentation] 自己組織化単分子膜を用いた両極性半導体のキャリア制御2016

    • Author(s)
      中野正浩、尾坂格、瀧宮和男
    • Organizer
      第63回応用物理学会春季学術講演会
    • Place of Presentation
      東京工業大学(東京都・目黒区)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] Novel Dithiophene-fused π-Cores for Organic Semiconducting Materials2016

    • Author(s)
      Masahiro Nakano、Itaru Osaka、Kazuo Takimiya
    • Organizer
      CEMSupra 2016
    • Place of Presentation
      東京大学(東京都・文京区)
    • Year and Date
      2016-01-13
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Control of Major Carriers in an Ambipolar Semiconductiong Polymer by Self-Assembled Monolayers on the Dielectric Surface2016

    • Author(s)
      Masahiro Nakano、Itaru Osaka、Kazuo Takimiya
    • Organizer
      CEMSupra 2016
    • Place of Presentation
      東京大学(東京都・文京区)
    • Year and Date
      2016-01-13
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Naphthodithiophene Diimide (NDTI): a Useful Building Block for the Development of Ambipolar and Unipolar n-Type Polymers.2015

    • Author(s)
      Masahiro Nakano、Itaru Osaka、Kazuo Takimiya
    • Organizer
      M&BE8(第8回有機分子バイオエレクトロニクス国際会議)
    • Place of Presentation
      船橋タワーホール(東京都・江戸川区)
    • Year and Date
      2015-06-22
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Naphthodithiophenediimide (NDTI)-based novel semiconducting polymers.2015

    • Author(s)
      Masahiro Nakano、Itaru Osaka、Kazuo Takimiya
    • Organizer
      第64回高分子学会年次大会
    • Place of Presentation
      札幌コンベンションセンター(北海道・札幌市)
    • Year and Date
      2015-05-27
    • Related Report
      2015 Annual Research Report
  • [Presentation] ジベンゾ[a,e]ペンタレン(DBP)を基盤とする新規π共役分子の合成と有機 トランジスタ特性2015

    • Author(s)
      中野正浩, 尾坂格, 瀧宮和男
    • Organizer
      日本化学会第95春季年会2015
    • Place of Presentation
      日本大学理工学部船橋キャンパス, 東京都
    • Year and Date
      2015-03-27
    • Related Report
      2014 Research-status Report
  • [Presentation] ナフトキチオフェンジイミド(NDTI)を基盤とした新規半導体ポリマー, Naphthidithiopppphenediimide(NDTI)-based novel semiconductiong ploymers2014

    • Author(s)
      中野正浩, 尾坂格, 瀧宮和男, 小金澤智之
    • Organizer
      2014年第75回応用物理学会秋季学術討論会
    • Place of Presentation
      北海道大学札幌キャンパス, 北海道
    • Year and Date
      2014-12-03
    • Related Report
      2014 Research-status Report
  • [Presentation] Naphthodithiophenediimide (NDTI)-Based Semiconducting Polymers2014

    • Author(s)
      Masahiro Nakano,Itaru Osaka,Kazuo Takimiya,Tomoyuki Koganezawa
    • Organizer
      2014 MRS Fall Meeting
    • Place of Presentation
      the Hynes Convention Center and Sheraton Boston Hotel in Boston, Massachusetts,USA
    • Year and Date
      2014-12-03
    • Related Report
      2014 Research-status Report
  • [Presentation] Naphthodithiophenediimide (NDTI): a New Building Block for Versatile Organic Semiconductors2014

    • Author(s)
      Masahiro Nakano,Kazuo Takimiya,Itaru Osaka,Jian-yong.hu,Yuta Fukutomi
    • Organizer
      ICSM2014
    • Place of Presentation
      LOGOMO, Turku, Finland
    • Year and Date
      2014-07-01
    • Related Report
      2014 Research-status Report

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Published: 2014-04-04   Modified: 2017-05-10  

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