• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Development of bio-based composites reinforced by porous polymeric material

Research Project

Project/Area Number 26810114
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Polymer/Textile materials
Research InstitutionOsaka University

Principal Investigator

TSUJIMOTO Takashi  大阪大学, 工学研究科, 助教 (90425041)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2015: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2014: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywords高分子多孔体 / 複合材料 / 再生可能資源 / 相分離 / セルロース
Outline of Final Research Achievements

In this study, a green composite was developed from cellulose and bacterial polyester, poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) (PHBH). Cellulose gel was prepared from a Ca(SCN)2 aqueous solution, and subsequent washing by ethanol gave regenerated porous cellulose without shrinkage. The PHBH/cellulose composite was fabricated by immersion of porous cellulose in a polymer solution. The cellulose content of the composite was controlled by changing the cellulose concentration of the Ca(SCN)2 aqueous solution. The resulting composites showed a relatively good transparency with improvements in mechanical properties such as tensile strength, toughness, and brittleness. Furthermore, the thermal stability of the composites was improved by the incorporation of porous cellulose. These composites from renewable resources are expected to contribute to the development of bio-based materials in composite science.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (16 results)

All 2017 2016 2015 2014

All Journal Article (14 results) (of which Peer Reviewed: 14 results,  Open Access: 6 results,  Acknowledgement Compliant: 10 results) Presentation (2 results)

  • [Journal Article] Fabrication of Amine-functionalized Acrylic Monoliths via Thermally Induced Phase Separation and Their Application for Separation Media2017

    • Author(s)
      T. Tsujimoto, T. Kitagawa, S. Yoneda, H. Uyama
    • Journal Title

      Journal of Porous Materials

      Volume: 24 Issue: 1 Pages: 233-239

    • DOI

      10.1007/s10934-016-0256-2

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Bio-based Polymeric Materials from Epoxidized Triglyceride and Rosin Derivatives2016

    • Author(s)
      T. Tsujimoto, H. Ueda, H. Kageyama, H. Uyama
    • Journal Title

      Trends in Green Chemistry

      Volume: 2 Issue: 1 Pages: 1-7

    • DOI

      10.21767/2471-9889.100010

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Bio-based Flexible Network Polymer from Epoxidized Soybean Oil Reinforced by Poly(butyl methacrylate)2016

    • Author(s)
      N. Hosoda, H. Hayashi, T. Tsujimoto
    • Journal Title

      International Journal of Chemistry

      Volume: 8 Issue: 1 Pages: 159-164

    • DOI

      10.5539/ijc.v8n1p159

    • Related Report
      2016 Annual Research Report 2015 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Fabrication of Porous Poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) Monoliths via Thermally Induced Phase Separation2016

    • Author(s)
      T. Tsujimoto, N. Hosoda, H. Uyama
    • Journal Title

      Polymers

      Volume: 8 Issue: 3 Pages: 66-66

    • DOI

      10.3390/polym8030066

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Bio-based Epoxy Resins from Epoxidized Plant Oils and Their Shape Memory Behaviors2016

    • Author(s)
      T. Tsujimoto, K. Takeshita, H. Uyama
    • Journal Title

      Journal of the American Oil Chemists' Society

      Volume: 93 Issue: 12 Pages: 1663-1669

    • DOI

      10.1007/s11746-016-2907-5

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Plant Oil-based Shape Memory Polymer Using Acrylic Monolith2015

    • Author(s)
      T. Tsujimoto, E. Ohta, H. Uyama
    • Journal Title

      eXPRESS Polymer Letters

      Volume: 9 Issue: 9 Pages: 757-763

    • DOI

      10.3144/expresspolymlett.2015.71

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Synthesis and Curing Behaviors of Reactive Cellulose Esters from Renewable Resources2015

    • Author(s)
      T. Tsujimoto, Y. Nishiumi, S. Kobayashi
    • Journal Title

      International Journal of Innovative Research in Science, Ebgineering and Technology

      Volume: 4 Issue: 6 Pages: 3909-3916

    • DOI

      10.15680/ijirset.2015.0406169

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Green Nanocomposites from Renewable Plant Oils and Polyhedral Oligomeric Silsesquioxanes2015

    • Author(s)
      T. Tsujimoto, H. Uyama, S. Kobayashi, H. Oikawa, M. Yamahiro
    • Journal Title

      Metals

      Volume: 5 Issue: 3 Pages: 1136-1147

    • DOI

      10.3390/met5031136

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Bio-based Branched Polymer Bearing Castor Oil Core as a Nucleating Agent for Poly(L-Lactic Acid)2015

    • Author(s)
      T. Tsujimoto, S. Nishio, H. Uyama
    • Journal Title

      Journal of Polymers and the Environment

      Volume: 23 Pages: 559-565

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Biodegradable Shape Memory Polymeric Material from Epoxidized Soybean Oil and Polycaprolactone2015

    • Author(s)
      T. Tsujimoto, T. Takayama, H. Uyama
    • Journal Title

      Polymers

      Volume: 7 Issue: 10 Pages: 2165-2174

    • DOI

      10.3390/polym7101506

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Green Composite of Poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) Reinforced with Porous Cellulose2014

    • Author(s)
      Nao Hosoda, Takashi Tsujimoto, Hiroshi Uyama
    • Journal Title

      ACS Sustainable Chemistry & Engineering

      Volume: 2 Issue: 2 Pages: 248-253

    • DOI

      10.1021/sc400290y

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Plant oil-based green composite using porous poly(3-hydroxybutyrate)2014

    • Author(s)
      Nao Hosoda, Takashi Tsujimoto, Hiroshi Uyama
    • Journal Title

      Polymer Journal

      Volume: 46 Issue: 5 Pages: 301-306

    • DOI

      10.1038/pj.2014.1

    • NAID

      40020051385

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Full biobased polymeric material from plant oil and poly(lactic acid) with a shapae memory property2014

    • Author(s)
      Takashi Tsujimoto, Hiroshi Uyama
    • Journal Title

      ACS Sustainable & Engineering

      Volume: 2 Issue: 8 Pages: 2057-2062

    • DOI

      10.1021/sc500310s

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Maleated trans-1,4-polyisoprene from Eucommia ulmoides oliver with dynamic network structure and its shape memory property2014

    • Author(s)
      Takashi Tsujimoto, Kenichi Toshimitsu, Hiroshi Uyama, Shinya Takeno, Yoshihisa Nakazawa
    • Journal Title

      Polymer

      Volume: 55 Issue: 25 Pages: 6488-6493

    • DOI

      10.1016/j.polymer.2014.10.035

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 熱誘起相分離法によるポリヒドロキシアルカン酸多孔体の作製2016

    • Author(s)
      辻本敬、細田直、宇山浩
    • Organizer
      第65回高分子討論会
    • Place of Presentation
      神奈川大学横浜キャンパス
    • Year and Date
      2016-09-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] ポリ(3-ヒドロキシ酪酸)多孔体を用いた植物油脂ベース複合材料2014

    • Author(s)
      細田 直、辻本 敬、宇山 浩
    • Organizer
      高分子学会 第63回討論会
    • Place of Presentation
      長崎大学
    • Year and Date
      2014-09-24 – 2014-09-26
    • Related Report
      2014 Research-status Report

URL: 

Published: 2014-04-04   Modified: 2018-03-22  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi