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Mechanism of photocatalytic hydrogen production over graphite silica/TiO2 and their artificial synthesis

Research Project

Project/Area Number 26810117
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Inorganic industrial materials
Research InstitutionYamagata University

Principal Investigator

Arima Bashir Ahmmad  山形大学, 理工学研究科, 助教 (30596549)

Co-Investigator(Renkei-kenkyūsha) HIROSE Fumihiko  山形大学, 大学院理工学研究科, 教授 (50372339)
Project Period (FY) 2014-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2015: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2014: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Keywordsグラファイトシリカ / TiO2 / 水素製造 / ナノコンポジット / 二酸化チタン
Outline of Final Research Achievements

The mechanism of enhanced hydrogen production by GS over TiO2 has been studied. Previous studies show that clay portion of GS contributes to hydrogen production. Therefore, we used several natural clays (e.g. dolomite, sericite) and synthesized sericite to observe their effect on hydrogen production over TiO2. We also studied the effect of pH and the bandgaps of photocatalysts on hydrogen production over GS/TiO2. It is found that that pH or bandgap has no effect on hydrogen production over GS/TiO2. Moreover, we developed a new method for the fabrication of ultrafine nanoparticles of metal oxides. The average size of the nanoparticles is found to be 11nm with reduced oxygen vacancies in the crystal. The nanomaterials are potential for application in catalysis, sensor, electromagnetism and other optoelectronic devices.

Report

(3 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • Research Products

    (24 results)

All 2016 2015 2014 Other

All Journal Article (9 results) (of which Int'l Joint Research: 6 results,  Peer Reviewed: 9 results,  Open Access: 2 results,  Acknowledgement Compliant: 7 results) Presentation (13 results) (of which Int'l Joint Research: 7 results,  Invited: 7 results) Remarks (2 results)

  • [Journal Article] Anomalous coercivity enhancement with temperature and tunable exchange bias in Gd and Ti co-doped BiFeO3 multiferroics2016

    • Author(s)
      B. Ahmmad, M. Islam, A. Billah, M. Basith
    • Journal Title

      Journal of Physics D: Applied Physics

      Volume: 49 Issue: 9 Pages: 095001-095001

    • DOI

      10.1088/0022-3727/49/9/095001

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Size dependent magnetic and electrical properties of Ba-doped nanocrystalline BiFeO32016

    • Author(s)
      M. Hasan, M. A. Hakim, M. A. Basith, M. S. Hossain, B. Ahmmad
    • Journal Title

      AIP Advances

      Volume: 6 Issue: 3 Pages: 035314-035314

    • DOI

      10.1063/1.4944817

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Tunable exchange bias effect in magnetic Bi0.9Gd0.1Fe0.9Ti0.1O3 nanoparticles at temperatures up to 250 K2015

    • Author(s)
      M. A. Basith, F. A. Khan, B. Ahmmad, S. Kubota, F. Hirose, D.-T. Ngo, Q.-H. Tran, K. Molhave
    • Journal Title

      Journal of Applied Physics

      Volume: 118 Issue: 2 Pages: 023901-023901

    • DOI

      10.1063/1.4926424

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Synthesis of metal doped BiFeO3 nanoparticles and their dielectric and magnetic properties2015

    • Author(s)
      B Ahmmad, M.A. Basith, K. Koike, S. Kubota, and F. Hirose
    • Journal Title

      Advanced Materials Research

      Volume: 1101 Pages: 187-191

    • DOI

      10.4028/www.scientific.net/amr.1101.187

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Synthesis, characterization of gallium oxyhydroxide (a-GaOOH) self-assembly and its application in removal of perfluorinated compounds2015

    • Author(s)
      M. Muruganandham, R. P. S. Suri, M. S. M. Abdel Wahed, M. Sillanpa, J. J. Wu, and B. Ahmmad
    • Journal Title

      Journal of Nanoscience and Nanotechnology

      Volume: 15 Issue: 9 Pages: 6524-6532

    • DOI

      10.1166/jnn.2015.10716

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Growth kinetics of temperature-controlled atomic layer deposition of GaN using trimethlgallium and remote-plasma-excited NH32015

    • Author(s)
      P. Pugboon Pansila, K. Kanomata, M. Miura, B. Ahammad, S. Kubota, F. Hirose
    • Journal Title

      Applied Surface Science

      Volume: 357 Pages: 1920-1927

    • DOI

      10.1016/j.apsusc.2015.09.138

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Synthesis of metal doped BiFeO3 Nanoparticles and their dielectric and magnetic properties2015

    • Author(s)
      Bashir Ahmmad, M.A. Basith, Kunihito Koike, Shigeru Kubota, Fumihiko Hirose
    • Journal Title

      Advanced Materials Research

      Volume: 1101 Pages: 187-191

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Enhanced photocatalytic hydrogen production on TiO2 by using carbon materials2014

    • Author(s)
      Bashir Ahmmad, Kensaku Kanomata and Fumihiko Hirose
    • Journal Title

      International Journal of Chemical, Nuclear, Materials and Metallurgical Engineering

      Volume: 8 Pages: 24-29

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Bioplastic based on starch and cellulose nanocrystals from rice straw2014

    • Author(s)
      Melissa B. Agustin, Bashir Ahmmad, Shanna Marie M. Alonzo, Famille M. Patriana
    • Journal Title

      Journal of Reinforced Plastics and Composites

      Volume: 33 Issue: 24 Pages: 2205-2213

    • DOI

      10.1177/0731684414558325

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] Fabrication of 1D or 2D nanostructured TiO2 and ZnO thin films for solar energy devices2016

    • Author(s)
      B. Ahmmad, K. Kanomata, M.A. Basith, S. Kubota, F. Hirose
    • Organizer
      16th Asian Chemical Congress (16ACC)
    • Place of Presentation
      BUET大学、ダッカ (バングラデシュ)
    • Year and Date
      2016-03-16
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Preparation of Gd and Ti co-doped BiFeO3 multiferroic nanoparticles by ultrasonication of their bulk powder materials2016

    • Author(s)
      M. A. Basith, A. Billah, B. Ahmmad
    • Organizer
      16th Asian Chemical Congress (16ACC)
    • Place of Presentation
      BUET大学、ダッカ ( バングラデシュ)
    • Year and Date
      2016-03-16
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Multiferroic properties of Ba and Ti co-doped BiFeO3 nanoparticles2016

    • Author(s)
      M. A. Jalil, M. A. Basith and B. Ahmmad
    • Organizer
      International Conference on Physics
    • Place of Presentation
      ダッカ大学、ダッカ ( バングラデシュ)
    • Year and Date
      2016-03-10
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Enhanced coercivity and tunable exchange bias in Gd and Ti co-doped BiFeO3 multiferroics2016

    • Author(s)
      M. A. Basith, A. Billah, Z. Islam, B. Ahmmad
    • Organizer
      13th Joint MMM-Intermag 2016
    • Place of Presentation
      Hilton San Diego Bayfront ホテル, サンディエゴ (アメリカ合衆国)
    • Year and Date
      2016-01-11
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Multiferroic properties of Li doped BiFeO3 nanoparticles prepared by ultrasonication2015

    • Author(s)
      A. Billah, S. H. Firoz, B. Ahmmad, M. A. Basith
    • Organizer
      2nd International Bose Conference
    • Place of Presentation
      ダッカ大学、ダッカ (バングラデシュ)
    • Year and Date
      2015-12-03
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 超音波を利用したドープ型ビスマスフェライトのナノ粒子の合成及び磁化特性に関する研究2015

    • Author(s)
      有馬 ボシールアハンマド
    • Organizer
      第66回コロイド及び界面化学討論会
    • Place of Presentation
      鹿児島大学郡元キャンパス、鹿児島
    • Year and Date
      2015-09-10
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Structural changes in N719 dye molecule and improved performances of dye sensitized solar cells2015

    • Author(s)
      B. Ahmmad, E. Itoh, K. Kanomata, S. Kubota and F. Hirose
    • Organizer
      The 5th Conference on New Energy and Sustainable Development (NESD2015)
    • Place of Presentation
      Guangong Hotel, 上海 (中国)
    • Year and Date
      2015-07-19
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Synthesis of Ba/Gd and Ti co-doped BiFeO3 nanoparticles and their dielectric and magnetic properties2015

    • Author(s)
      B. Ahmmad
    • Organizer
      World Congress and Expo on Nanotechnology and Material Science
    • Place of Presentation
      Crown Plaza Dubai-Deira ホテル、ドバイ (アラブ首長国連邦)
    • Year and Date
      2015-04-13
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Fabrication of self-aligned 1D or 2D nanostructured ZnO and TiO2 films and their characterization2015

    • Author(s)
      Bashir Ahmmad, Kensaku Kanomata, Shigeru Kubota, Fumihiko Hirose
    • Organizer
      1st Annual World Congress of Smart Materials
    • Place of Presentation
      Busan, Korea
    • Year and Date
      2015-03-23 – 2015-03-25
    • Related Report
      2014 Research-status Report
  • [Presentation] Facile synthesis of smart nanomaterials and their characterization2015

    • Author(s)
      Bashir Ahmmad
    • Organizer
      1st Annual World Congress of Smart Materials
    • Place of Presentation
      Busan, Korea
    • Year and Date
      2015-03-23 – 2015-03-25
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Synthesis of metal doped BiFeO3 nanoparticles and their dielectric and magnetic properties2015

    • Author(s)
      Bashir Ahmmad
    • Organizer
      3rd International Conference on Nano and Materials Science
    • Place of Presentation
      Zhuhai, China
    • Year and Date
      2015-01-24 – 2015-01-26
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Dielectric and magnetic properties of metals doped BiFeO3 nanoparticles2014

    • Author(s)
      Bashir Ahmmad
    • Organizer
      4th Internationals Confernence on Nanotek and Expo, San Francisco
    • Place of Presentation
      San Francisco, USA
    • Year and Date
      2014-12-01 – 2014-12-03
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Fabrication and characterization of self-aligned ZnO and TiO2 nanostructured films2014

    • Author(s)
      Bashir Ahmmad*, Shogo Hayasaka, Kensaku Kanomata, Shigeru Kubota, Fumihiko Hirose
    • Organizer
      3rd International Conference on Informatics, Electronics & Vision
    • Place of Presentation
      Dhaka, Bangladesh
    • Year and Date
      2014-05-23 – 2014-05-24
    • Related Report
      2014 Research-status Report
  • [Remarks] 山形大学研究者情報

    • URL

      http://yudb.kj.yamagata-u.ac.jp/html/100000575_ja.html

    • Related Report
      2015 Annual Research Report
  • [Remarks] Google Scholar

    • URL

      https://scholar.google.co.jp/citations?hl=en&user=nPTWEEwAAAAJ&view_op=list_works&sortby=pubdate

    • Related Report
      2015 Annual Research Report

URL: 

Published: 2014-04-04   Modified: 2017-05-10  

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