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Development of Functional Materials Utilizing Nano-Size Effects of Host-Guest Compounds

Research Project

Project/Area Number 26810118
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Inorganic industrial materials
Research InstitutionWaseda University

Principal Investigator

Kuroda Yoshiyuki  早稲田大学, 高等研究所, 助教 (50638640)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2016: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2015: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2014: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Keywordsホスト-ゲスト系化合物 / 多孔体 / 層状化合物 / イオン交換 / 触媒 / ナノシート / 超格子 / ホスト-ゲスト化合物 / ナノサイズ効果 / 三脚型配位子 / ハイブリッド / 層状複水酸化物 / 層状物質 / イオン交換体
Outline of Final Research Achievements

In this study, several new functional materials have been developed by using nano-size effects of host-guest compounds with controlled nanostructures. Tripodal ligands are found to be useful for the control of nanostructures of layered metal hydroxides. Layered double hydroxides as adsorbents for rapid removal of pollutants, highly active solid base catalysts, and novel nanosheet materials whose constituent elements and surface functional groups are independently controllable have been developed using tripodal ligands. By assembling silica nanoparticles, superlattice of nanospace and porous materials with single-crystalline quartz framework have also been prepared. These materials are expected to be useful for applications in catalysis, energy storage, and environmental purification (separation and adsorption).

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (38 results)

All 2017 2016 2015 2014

All Journal Article (5 results) (of which Peer Reviewed: 5 results,  Acknowledgement Compliant: 2 results,  Open Access: 1 results) Presentation (33 results) (of which Int'l Joint Research: 10 results,  Invited: 5 results)

  • [Journal Article] Direct Synthesis of Highly Designable Hybrid Metal Hydroxide Nanosheets Using Tripodal Ligands as One-Size-Fits-All Modifiers2017

    • Author(s)
      Yoshiyuki Kuroda, Tatsuyuki Koichi, Muramatsu Keisuke, Kazuya Yamaguchi, Noritaka Mizuno, Atsushi Shimojima, Hiroaki Wada, Kazuyuki Kuroda
    • Journal Title

      Chemistry - A European Journal

      Volume: 23 Issue: 21 Pages: 5023-5032

    • DOI

      10.1002/chem.201605698

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Mesoporous Superlattice Consisting of Alternately Stacking Interstitial Nanospacewithin Binary Silica Colloidal Crystals2016

    • Author(s)
      Yoshiyuki Kuroda, Yosuke Shimbo, Yasuhiro Sakamoto, Hiroaki Wada, Kazuyuki Kuroda
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 55 Issue: 36 Pages: 10702-10706

    • DOI

      10.1002/anie.201605027

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Single-Crystalline Mesoporous Quartz Superlattice2016

    • Author(s)
      T. Matsuno, Y. Kuroda, M. Kitahara, A. Shimojima, H. Wada, K. Kuroda
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 未定 Issue: 20 Pages: 6008-6012

    • DOI

      10.1002/anie.201600675

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Relationship between Aggregated Structures and Dispersibility of Layered Double Hydroxide Nanoparticles ca. 10 nm in Size and Their Application to Ultrafast Removal of Aqueous Anionic Dye2015

    • Author(s)
      Y. Kuroda, Y. Yamaguchi, K. Kuroda, N. Mizuno
    • Journal Title

      Bull. Chem. Soc. Jpn.

      Volume: 88 Issue: 12 Pages: 1765-1772

    • DOI

      10.1246/bcsj.20150271

    • NAID

      130005113814

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Effective Use of Flexible Low-Dimensional Colloidal Particles and Colloidal Crystals for the Control of Hierarchically Porous Materials2015

    • Author(s)
      Y. Kuroda
    • Journal Title

      J. Ceram. Soc. Jpn.

      Volume: 123 Pages: 853-861

    • NAID

      130005096382

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access
  • [Presentation] 層状複水酸化物の三脚型配位子による層間修飾2017

    • Author(s)
      林志桜里, 岡佑弥, 黒田義之, 下嶋敦, 和田宏明, 黒田一幸
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶應義塾大学(神奈川県横浜市)
    • Related Report
      2016 Annual Research Report
  • [Presentation] シリカナノ粒子の集積と結晶化による結晶性メソポーラスシリカの調製と粒径依存性2017

    • Author(s)
      仲谷孝道, 新保洋介, 黒田義之, 下嶋敦, 和田宏明, 黒田一幸
    • Organizer
      日本セラミックス協会2017年年会
    • Place of Presentation
      日本大学(東京都千代田区)
    • Related Report
      2016 Annual Research Report
  • [Presentation] 鋳型のナノ構造変化を利用した酸化物微粒子配列体の調製2017

    • Author(s)
      黒田義之, 武藤至, 下嶋敦, 和田宏明, 黒田一幸
    • Organizer
      日本セラミックス協会2017年年会
    • Place of Presentation
      日本大学(東京都千代田区)
    • Related Report
      2016 Annual Research Report
  • [Presentation] Preparation of Single-Crystalline Mesoporous Quartz Superlattice Using Flux Confined in Nanospace2016

    • Author(s)
      Y. Kuroda, T. Matsuno, M. Kitahara, A. Shimojima, H. Wada, K. Kuroda
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学・京都
    • Year and Date
      2016-03-27
    • Related Report
      2015 Research-status Report
  • [Presentation] Preparation of Layered Double Hydroxide Nanoparticles by Rehydration of Mg–Al Mixed Metal Oxides in Aqueous Solutions of Tripodal Ligands2016

    • Author(s)
      Y. Oka, Y. Kuroda, A. Shimojima, H. Wada, K. Kuroda
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学・京都
    • Year and Date
      2016-03-26
    • Related Report
      2015 Research-status Report
  • [Presentation] 層間が三脚型配位子により修飾されたMg(OH)2の有機溶媒中における合成2016

    • Author(s)
      村松佳祐, 黒田義之, 仲野有紀, 小市竜之, 下嶋敦, 和田宏明, 黒田一幸
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学・京都
    • Year and Date
      2016-03-26
    • Related Report
      2015 Research-status Report
  • [Presentation] Effect of Organic Solvents on the Synthesis of Magnesium Hydroxide Modified with Tripodal Ligands2016

    • Author(s)
      Keisuke Muramatsu, Yoshiyuki Kuroda, Yuki Nakano, Tatsuyuki Koichi, Atsushi Shimojima, Hiroaki Wada, Kazuyuki Kuroda
    • Organizer
      FIT-ME Symposium
    • Place of Presentation
      福岡工業大学(福岡県福岡市)
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] One-Pot Synthesis of Magnesium Hydroxide Nanosheets Modified with Tripodal Ligands2016

    • Author(s)
      Yoshiyuki Kuroda, Tatsuyuki Koichi, Yuki Saito, Atsushi Shimojima, Hiroaki Wada, Kazuya Yamaguhi, Noritaka Mizuno, Kazuyuki Kuroda
    • Organizer
      FIT-ME Symposium
    • Place of Presentation
      福岡工業大学(福岡県福岡市)
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 三脚型及び二脚型配位子により層間修飾された水酸化マグネシウムの直接合成2016

    • Author(s)
      村松佳祐, 黒田義之, 小市竜之, 下嶋敦, 和田宏明, 黒田一幸
    • Organizer
      日本セラミックス協会第29回秋季シンポジウム
    • Place of Presentation
      広島大学(広島県東広島市)
    • Related Report
      2016 Annual Research Report
  • [Presentation] Formation of Organically Modified Layered Metal Hydroxides by One Step Reaction of Metal Salts2016

    • Author(s)
      Yoshiyuki Kuroda, Tatsuyuki Koichi, Keisuke Muramatsu, Kazuyuki Kuroda
    • Organizer
      The 6th International Workshop on Layered Materials
    • Place of Presentation
      クンタホラ(チェコ)
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ナノ空間が超格子構造を有するCrB型コロイド結晶の配向膜の作製2016

    • Author(s)
      新保洋介, 黒田義之, 阪本康弘, 下嶋敦, 和田宏明, 黒田一幸
    • Organizer
      第6回CSJ化学フェスタ
    • Place of Presentation
      タワーホール船堀(東京都江戸川区)
    • Related Report
      2016 Annual Research Report
  • [Presentation] Hybrid Brucite-Type Metal Hydroxide Nanosheets Modified with Tripodal Ligands2016

    • Author(s)
      Yoshiyuki Kuroda, Tatsuyuki Koichi, Keisuke Muramatsu, Kazuya Yamaguchi, Noritaka Mizuno, Atsushi Shimojima, Hiroaki Wada, Kazuyuki Kuroda
    • Organizer
      The 3rd Asian Clay Conference
    • Place of Presentation
      広州(中国)
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Efficient Interlayer Modification of Brucite with Tripodal Ligands Using Organic Solvents2016

    • Author(s)
      Keisuke Muramatsu, Yoshiyuki Kuroda, Yuki Nakano, Tatsuyuki Koichi, Atsushi Shimojima, Hiroaki Wada, Kazuyuki Kuroda
    • Organizer
      The 3rd Asian Clay Conference
    • Place of Presentation
      広州(中国)
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Preparation of Mesoporous Mg-Al Mixed Metal Oxides with High Catalytic Activity for Knovenagel Condensation by Using Layered Double Hydroxide Nanoparticles as Precursors2016

    • Author(s)
      Yuya Oka, Yoshiyuki Kuroda, Keigo Kamata, Atsushi Shimojima, Hiroaki Wada, Kazuyuki Kuroda
    • Organizer
      The 3rd Asian Clay Conference
    • Place of Presentation
      広州(中国)
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] シリカナノ粒子の基板上への集積による粒子間空間の配列および配向の制御2016

    • Author(s)
      新保洋介, 黒田義之, 阪本康弘, 下嶋敦, 和田宏明, 黒田一幸
    • Organizer
      第32回ゼオライト研究発表会
    • Place of Presentation
      タワーホール船堀(東京都江戸川区)
    • Related Report
      2016 Annual Research Report
  • [Presentation] 三脚型配位子により修飾された層状金属水酸化物の直接合成2016

    • Author(s)
      黒田義之, 小市竜之, 村松佳祐, 下嶋敦, 和田宏明, 黒田一幸
    • Organizer
      第32回ゼオライト研究発表会
    • Place of Presentation
      タワーホール船堀(東京都江戸川区)
    • Related Report
      2016 Annual Research Report
  • [Presentation] マクロポーラスポリマー薄膜をフレキシブルな鋳型として用いた一次元シリカナノ粒子配列対の形成2016

    • Author(s)
      武藤至, 黒田義之, 下嶋敦, 和田宏明, 黒田一幸
    • Organizer
      第26回日本MRS年次大会
    • Place of Presentation
      横浜開港記念会館(神奈川県横浜市)
    • Related Report
      2016 Annual Research Report
  • [Presentation] シリカナノ粒子の自己集合によるメソポーラス二元ナノ粒子超格子の作製2016

    • Author(s)
      黒田義之, 新保洋介, 阪本康弘, 和田宏明, 黒田一幸
    • Organizer
      第26回日本MRS年次大会
    • Place of Presentation
      横浜開港記念会館(神奈川県横浜市)
    • Related Report
      2016 Annual Research Report
  • [Presentation] 三脚型配位子を用いた層状金属水酸化物の構造・機能制御2016

    • Author(s)
      黒田義之, 山口和也, 水野哲孝, 黒田一幸
    • Organizer
      日本セラミックス協会第29回秋季シンポジウム
    • Place of Presentation
      広島大学(広島県東広島市)
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Structural Control of Layered Double Hydroxide Nanoparticles Using Tripodal Ligands for the Removal of Harmful Anions2016

    • Author(s)
      Yoshiyuki Kuroda, Kazuya Yamaguchi, Noritaka Mizuno, Kazuyuki Kuroda
    • Organizer
      The 3rd Asian Clay Conference
    • Place of Presentation
      広州(中国)
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Synthesis, characterization, and intercalation properties of novel hybrid layered metal hydroxides modified with tris(hydroxymethyl)aminomethane2015

    • Author(s)
      Y. Kuroda, T. Koichi, Y. Saito, A. Shimojima, H. Wada, K. Yamaguchi, N. Mizuno, K. Kuroda
    • Organizer
      Pacifichem2015
    • Place of Presentation
      Honolulu, USA
    • Year and Date
      2015-12-17
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] 三座配位子を用いた層状複水酸化物ナノ粒子の合成と応用2015

    • Author(s)
      黒田義之, 岡佑弥, 山口和也, 水野哲孝, 黒田一幸
    • Organizer
      第31回ゼオライト研究発表会
    • Place of Presentation
      とりぎん文化会館・鳥取県
    • Year and Date
      2015-11-26
    • Related Report
      2015 Research-status Report
  • [Presentation] ナノサイズ超微細粘土粒子の合成2015

    • Author(s)
      黒田義之
    • Organizer
      地方独立行政法人鳥取県産業技術センター平成27年度ナノ技術活用支援事業第2回技術セミナー
    • Place of Presentation
      BIGSHIP・鳥取県
    • Year and Date
      2015-11-25
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] リスヒドロキシメチルアミノメタンとMg(OH)2からなるハイブリッド層間化合物の合成とその性質2015

    • Author(s)
      小市竜之, 黒田義之, 齋藤友貴, 下嶋敦, 和田宏明, 山口和也, 水野哲孝, 黒田一幸
    • Organizer
      日本セラミックス協会第28回秋季シンポジウム
    • Place of Presentation
      富山大学・富山県
    • Year and Date
      2015-09-18
    • Related Report
      2015 Research-status Report
  • [Presentation] 粒径が精密に制御された層状複水酸化物ナノ粒子を前駆体に用いたメソポーラスMg–Al複酸化物の調製2015

    • Author(s)
      岡佑弥, 黒田義之, 松野敬成, 下嶋敦, 和田宏明, 黒田一幸
    • Organizer
      第59回粘土科学討論会
    • Place of Presentation
      山口大学・山口県
    • Year and Date
      2015-09-03
    • Related Report
      2015 Research-status Report
  • [Presentation] 高分散性層状複水酸化物ナノ粒子による色素の高速除去2015

    • Author(s)
      黒田義之, 山口和也, 黒田一幸, 水野哲孝
    • Organizer
      第59回粘土科学討論会
    • Place of Presentation
      山口大学・山口県
    • Year and Date
      2015-09-03
    • Related Report
      2015 Research-status Report
  • [Presentation] A Novel CrB-Type Binary Colloidal Crystal with an Interstratified Structure2015

    • Author(s)
      Y. Kuroda, Y. Sakamoto, K. Kuroda
    • Organizer
      ZMPC2015
    • Place of Presentation
      札幌コンベンションセンター・北海道
    • Year and Date
      2015-07-01
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Preparation of Mesoporous Mg–Al Metal Oxides with High Surface Area and Large Pore Volume by Using Uniform Layered Double Hydroxide Nanoparticles as Precursors2015

    • Author(s)
      Y. Oka, Y. Kuroda, T. Matsuno, A. Shimojima, H. Wada, K. Kuroda
    • Organizer
      ZMPC2015
    • Place of Presentation
      札幌コンベンションセンター・北海道
    • Year and Date
      2015-07-01
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] コロイド集積体を用いた無機ナノ空間材料の階層構造・形態制御2015

    • Author(s)
      ○黒田義之
    • Organizer
      日本セラミックス協会2015年年会
    • Place of Presentation
      岡山大学
    • Year and Date
      2015-03-18
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] シリカナノ粒子集積体のナノ空間を利用した金のナノ構造・形態制御2014

    • Author(s)
      ○黒田義之、阪本康弘、黒田一幸
    • Organizer
      第30回ゼオライト研究発表会
    • Place of Presentation
      東京
    • Year and Date
      2014-11-26
    • Related Report
      2014 Research-status Report
  • [Presentation] 共沈法による層状複水酸化物の合成における三座配位子の影響2014

    • Author(s)
      ○黒田義之、宮本唯未、日比野光宏、山口和也、水野哲孝
    • Organizer
      第58回粘土科学討論会
    • Place of Presentation
      福島
    • Year and Date
      2014-09-26
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] 三座配位子を用いて合成した層状複水酸化物ナノ粒子のアニオン交換能2014

    • Author(s)
      ○黒田義之、宮本唯未、日比野光宏、山口和也、水野哲孝
    • Organizer
      日本粘土学会第5回若手研究者研究発表会
    • Place of Presentation
      福島
    • Year and Date
      2014-09-24
    • Related Report
      2014 Research-status Report
  • [Presentation] Binary Colloidal Crystals as Flexible Templates for Dimpled Gold Nanoplates with Controlled Surface Patterns2014

    • Author(s)
      ○Yoshiyuki Kuroda, Yasuhiro Sakamoto, Kazuyuki Kuroda
    • Organizer
      International Conference on NanoMaterials for Health, Energy and Environment
    • Place of Presentation
      Mauritius
    • Year and Date
      2014-09-04
    • Related Report
      2014 Research-status Report

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Published: 2014-04-04   Modified: 2018-03-22  

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