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Cooperative functions emerged by hybridization of layered silicates with spherical particles

Research Project

Project/Area Number 26810121
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Inorganic industrial materials
Research InstitutionShinshu University

Principal Investigator

OKADA Tomohiko  信州大学, 学術研究院工学系, 准教授 (30386552)

Project Period (FY) 2014-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2015: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2014: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywords層状ケイ酸塩 / 不均一核生成 / 吸着 / 単分散球状シリカ / 表面修飾 / 分離
Outline of Final Research Achievements

Hybridization of layered silicate fine crystals (mainly smectite like layered silicates) has been investigated to explore synergic functions. Direct crystallization of the smectite-like layered silicates was employed onto various silica substrates (spheres, fibers, hollow microcapsules, and so on). Successful deposition of the crystals with homogeneous and thinner layers was verified to maintain the morphology of the original silica substrates. These hybridized materials have been applied to (1) filtration with adsorption of cationic organic contaminants, (2) building units of colloidal crystals, (3) controlled release materials for a cosmetic using, (4) HPLC column packing materials for chiral discrimination with a saving amount of eluent, and (5) magnetically collectable adsorbent/catalyst supports.

Report

(3 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • Research Products

    (23 results)

All 2016 2015 2014 Other

All Journal Article (9 results) (of which Peer Reviewed: 9 results,  Acknowledgement Compliant: 7 results) Presentation (12 results) (of which Int'l Joint Research: 8 results,  Invited: 3 results) Remarks (1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] An Inorganic Anionic Polymer Filter Disc: Direct Crystallization of a Layered Silicate Nanosheet on a Glass Fiber Filter2016

    • Author(s)
      Okada, T., Shimizu, K., Yamakami, T.
    • Journal Title

      RSC Adv.

      Volume: 6 Issue: 31 Pages: 26130-26136

    • DOI

      10.1039/c5ra25626g

    • NAID

      120007100492

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Application of Hectorite-Coated Silica Gel Particles as a Packing Material for Chromatographic Resolution2016

    • Author(s)
      Okada, T., Kumasaki, A., Shimizu, K., Yamagishi, A., Sato, H.
    • Journal Title

      J. Chromatogr. Sci.,

      Volume: in press Issue: 7 Pages: 1238-1243

    • DOI

      10.1093/chromsci/bmw058

    • NAID

      120007100491

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Water-Floatable Organosilica Particles for TiO2 Photocatalysis2016

    • Author(s)
      Maki, Y.; Ide, Y.; Okada, T.
    • Journal Title

      Chem. Eng. J.

      Volume: 299 Pages: 367-372

    • DOI

      10.1016/j.cej.2016.04.059

    • NAID

      120007100490

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Organoclays in water causes expansion that facilitates caffeine adsorption2015

    • Author(s)
      Tomohiko Okada, Junpei Oguchi, Kenichiro Yamamoto, Takashi Shiono, Masahiko Fujita, Taku Iiyama
    • Journal Title

      Langmuir

      Volume: 31 Issue: 1 Pages: 180-187

    • DOI

      10.1021/la503708t

    • Related Report
      2015 Annual Research Report 2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Concentration of 2-Phenylphenol by Organoclays from Aqueous Sucrose Solution.2015

    • Author(s)
      Seki, Y., Ide, Y., Okada, T., Ogawa, M.,
    • Journal Title

      Appl. Clay Sci.

      Volume: 109-110 Pages: 64-67

    • DOI

      10.1016/j.clay.2014.12.021

    • NAID

      120007100497

    • Related Report
      2015 Annual Research Report 2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Crystal architectures of a layered silicate on monodisperse spherical silica particles cause the topochemical expansion of the core-shell particles2015

    • Author(s)
      Okada, T.; Suzuki, A.; Yoshido, S.; Minamisawa, H. M.
    • Journal Title

      Microporous Mesoporous Mater.

      Volume: 215 Pages: 168-174

    • DOI

      10.1016/j.micromeso.2015.05.018

    • NAID

      120007101475

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Crystal growth of a hectorite-like layered silicate on monodisperse spherical silica particles with different diameters2015

    • Author(s)
      Okada, T., Suzuki, A.
    • Journal Title

      Clay Sci.

      Volume: 19 Pages: 45-51

    • NAID

      110009985138

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] In situ crystallization of Al-containing silicate nanosheets on monodisperse amorphous silica microspheres2015

    • Author(s)
      Okada, T., Sueyoshi, M., Minamisawa, H. M.
    • Journal Title

      Langmuir

      Volume: 31 Issue: 51 Pages: 13842-13849

    • DOI

      10.1021/acs.langmuir.5b03874

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Preparation of Porous Thin-film Polymethylsiloxane Microparticles in a W/O Emulsion System2015

    • Author(s)
      Mishima, S., Okada, T., Sakai, T., Kiyono, R., Haeiwa, T.
    • Journal Title

      Polym. J.

      Volume: 47 Issue: 6 Pages: 449-455

    • DOI

      10.1038/pj.2015.16

    • NAID

      120007100495

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Presentation] Organoclays in water cause interlayer expansion that facilitates caffeine adsorption2015

    • Author(s)
      Tomohiko Okada
    • Organizer
      2015 International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      アメリカ ホノルル
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Crystal growth of a layered silicate on amorphous silica fibers.2015

    • Author(s)
      Kei Shimizu, Tomohiko Okada
    • Organizer
      2015 International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      アメリカ ホノルル
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] The in situ crystallization of an Al-containing layered silicate on monodisperse spherical colloidal silica particles.2015

    • Author(s)
      Mai Sueyoshi, Tomohiko Okada
    • Organizer
      2015 International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      アメリカ ホノルル
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Fabrication and photocatalysis of organosilica-titanium oxide hybrid particles.2015

    • Author(s)
      Yusuke Maki, Yusuke Ide, Tomohiko Okada
    • Organizer
      2015 International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      アメリカ ホノルル
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Hierarchical Design of Layered Silicates for Molecular Recognition2015

    • Author(s)
      Tomohiko Okada
    • Organizer
      2nd International Joint Workshop of STAR Project (Korean-French joint research)
    • Place of Presentation
      韓国 原州
    • Year and Date
      2015-10-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Silica-based functional core-shell microspheres2015

    • Author(s)
      Tomohiko Okada
    • Organizer
      The 5th International Conference on Sciences and Social Sciences 2015
    • Place of Presentation
      タイ バンコク
    • Year and Date
      2015-09-14
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Organoclays in water cause interlayer expansion that facilitates caffeine adsorption.2015

    • Author(s)
      Tomohiko Okada, Junpei Oguchi, Ken-ichiro Yamamoto, Takashi Shiono, Masahiko Fujita, Taku Iiyama
    • Organizer
      Euroclay 2015
    • Place of Presentation
      イギリス エジンバラ
    • Year and Date
      2015-07-05
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Intercalation into fine crystallites of a layered silicate on monodisperse spherical colloidal silica particles2015

    • Author(s)
      Tomohiko Okada, Asuka Suzuki
    • Organizer
      Euroclay 2015
    • Place of Presentation
      イギリス エジンバラ
    • Year and Date
      2015-07-05
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ヘクトライト-シリカコアシェル粒子のHPLCカラム充填剤への応用2015

    • Author(s)
      岡田友彦・熊崎愛作・清水慶・中山駿佑・北澤孝史・佐藤久子・山岸晧彦
    • Organizer
      第95春季年会 日本化学会
    • Place of Presentation
      日大船橋
    • Year and Date
      2015-03-25 – 2015-03-28
    • Related Report
      2014 Research-status Report
  • [Presentation] サポナイト様層状ケイ酸塩と複合化した球状シリカ微粒子の吸着特性2015

    • Author(s)
      末吉舞・岡田友彦・三島彰司
    • Organizer
      第95春季年会 日本化学会
    • Place of Presentation
      日大船橋
    • Year and Date
      2015-03-25 – 2015-03-28
    • Related Report
      2014 Research-status Report
  • [Presentation] Cation exchangeable core-shell micro-spherical particles based on silica and silicates2014

    • Author(s)
      Okada, T.
    • Organizer
      International Joint Workshop of STAR Project
    • Place of Presentation
      Wonju Korea
    • Year and Date
      2014-10-16 – 2014-10-18
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] 繊維状シリカ表面におけるヘクトライト様層状ケイ酸塩の結晶成長2014

    • Author(s)
      清水慶・鈴木飛鳥・岡田友彦・三島彰司
    • Organizer
      第58回粘土科学討論会
    • Place of Presentation
      福島市AOZ
    • Year and Date
      2014-09-24 – 2014-09-26
    • Related Report
      2014 Research-status Report
  • [Remarks] 信州大学工学部 吸着・触媒化学研究室

    • URL

      http://www.shinshu-u.ac.jp/faculty/engineering/chair/chem009/

    • Related Report
      2015 Annual Research Report 2014 Research-status Report
  • [Patent(Industrial Property Rights)] カラム充填剤及び高速液体クロマトグラフィー装置2014

    • Inventor(s)
      岡田友彦,他5名
    • Industrial Property Rights Holder
      信州大学、東邦大学、愛媛大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2014-180909
    • Filing Date
      2014-09-05
    • Related Report
      2014 Research-status Report

URL: 

Published: 2014-04-04   Modified: 2017-05-10  

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