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Heteroatom doping into porous carbon monoliths and their electrochemical applications

Research Project

Project/Area Number 26810123
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Inorganic industrial materials
Research InstitutionOsaka University (2015)
Kyoto University (2014)

Principal Investigator

Hasegawa George  大阪大学, 産業科学研究所, 助教 (60726412)

Project Period (FY) 2014-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2015: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2014: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Keywords炭素材料 / ドープ / 多孔性材料 / モノリス電極 / キャパシタ
Outline of Final Research Achievements

Hierarchically porous resorcinol-formaldehyde gels comprising mesoporous nanorod assemblies with two-dimensional hexagonal ordering by combining a supramolecular self-assembly strategy and phase separation in micrometer-scale. The new post-treatment method to introduce heteroatoms (nitrogen, phosphorus, and sulfur) into carbon materials with high doping level has also been developed. In addition, the electrochemical investigation on the undoped and doped carbon monolithic electrodes applied to supercapacitors has provided insights into the effects of heteroatom doping on the electrochemical capacitance. Meanwhile, the hierarchically porous carbon monolith showed good electrochemical sodium storage behavior. It is found that the well-defined mesoporous structure is favorable for improving the rate capability.

Report

(3 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • Research Products

    (16 results)

All 2015 2014 Other

All Journal Article (7 results) (of which Peer Reviewed: 7 results,  Acknowledgement Compliant: 6 results) Presentation (8 results) (of which Int'l Joint Research: 2 results) Remarks (1 results)

  • [Journal Article] High-level doping of nitrogen, phosphorus, and sulfur into activated carbon monoliths and their electrochemical capacitances2015

    • Author(s)
      George Hasegawa, Takeru Deguchi, Kazuyoshi Kanamori, Yoji Kobayashi, Hiroshi Kageyama, Takeshi Abe, Kazuki Nakanishi
    • Journal Title

      Chemistry of Materials

      Volume: 27 Issue: 13 Pages: 4703-4712

    • DOI

      10.1021/acs.chemmater.5b01349

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Hard carbon anodes for Na-ion batteries: toward a practical use2015

    • Author(s)
      George Hasegawa, Kazuyoshi Kanamori, Naokatsu Kannari, Jun-ichi Ozaki, Kazuki Nakanishi, Takeshi Abe
    • Journal Title

      ChemElectroChem

      Volume: 54 Issue: 12 Pages: 1917-1920

    • DOI

      10.1002/celc.201500412

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Hierarchically porous Li4Ti5O12 anode materials for Li- and Na-ion batteries: effects of nano-architectural design and temperature dependence of rate capacity2015

    • Author(s)
      George Hasegawa, Kazuyoshi Kanamori, Tsutomu Kiyomura, Hiroki Kurata, Kazuki Nakanishi, Takeshi Abe
    • Journal Title

      Advanced Energy Materials

      Volume: 5 Issue: 1 Pages: 1400730-1400730

    • DOI

      10.1002/aenm.201400730

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Impact of electrolyte on pseudocapacitance and stability of porous titanium nitride (TiN) monolithic electrode2015

    • Author(s)
      George Hasegawa, Atsushi Kitada, Shota. Kawasaki, Kazuyoshi Kanamori, Kazuki Nakanishi, Yoji Kobayashi, Hiroshi Kageyama, Takeshi Abe
    • Journal Title

      Journal of The Electrochemical Society

      Volume: 162 Issue: 1 Pages: A77-A85

    • DOI

      10.1149/2.0491501jes

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Effects of calcination condition on porous reduced titanium oxides and oxynitrides via preceramic polymer route2015

    • Author(s)
      George Hasegawa, Tatsuya Sato, Kazuyoshi Kanamori, Cheng-Jun Sun, Yang Ren, Yoji Kobayashi, Hiroshi Kageyama, Takeshi Abe, Kazuki Nakanishi
    • Journal Title

      Inorganic Chemistry

      Volume: 54 Issue: 6 Pages: 2802-2808

    • DOI

      10.1021/ic502972v

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Ultralow-Density, Transparent, Superamphiphobic Boehmite Nanofiber Aerogels and Their Alumina Derivatives2015

    • Author(s)
      Gen Hayase, Kazuya Nonomura, George Hasegawa, Kazuyoshi Kanamori, Kazuki Nakanishi
    • Journal Title

      Chemistry of Materials

      Volume: 27 Issue: 1 Pages: 3-5

    • DOI

      10.1021/cm503993n

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Reduction on reactive pore surfaces as a practical approach to supported metal alloy nanoparticles.2014

    • Author(s)
      Moitra, N.; Kanamori, K.; Ikuhara, Y. H., Gao, X.; Hasegawa, G.; Takeda, K.; Zhu, Y.; Shimada, T.; Nakanishi, K.
    • Journal Title

      Journal of Materials Chemistry A

      Volume: 2 Issue: 31 Pages: 12535-12544

    • DOI

      10.1039/c4ta01767f

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Presentation] Vapor-phase Transport of Heteroatoms into Porous Carbon Monoliths for High-level Doping2015

    • Author(s)
      長谷川丈二、金森主祥、小林洋治、陰山洋、安部武志、中西和樹
    • Organizer
      2015 MRS Fall Meeting
    • Place of Presentation
      Boston (United States)
    • Year and Date
      2015-11-29
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] モノリス型電極を用いたナトリウムイオン電池負極用ハードカーボンの性能評価2015

    • Author(s)
      長谷川丈二、金森主祥、中西和樹、安部武志
    • Organizer
      第56回 電池討論会
    • Place of Presentation
      ウインク愛知(名古屋)
    • Year and Date
      2015-11-11
    • Related Report
      2015 Annual Research Report
  • [Presentation] Studies on Porous Monolithic Carbon Electrodes for Energy Storage2015

    • Author(s)
      長谷川丈二、金森主祥、中西和樹、安部武志
    • Organizer
      The XVIII edition of the International Sol-Gel Conference
    • Place of Presentation
      メルパルク京都(京都)
    • Year and Date
      2015-09-06
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 窒素含有チタン系有機-無機ハイブリッド多孔体の結晶化挙動2015

    • Author(s)
      長谷川丈二、小林洋治、陰山洋、安部武志、金森主祥、中西和樹
    • Organizer
      日本セラミックス協会2015年年会
    • Place of Presentation
      岡山 (岡山県)
    • Year and Date
      2015-03-20
    • Related Report
      2014 Research-status Report
  • [Presentation] Synthesis and Electrochemical Application of Porous Si/C Nanocomposites from Poly(silsesqioxane) Networks2015

    • Author(s)
      長谷川丈二、楊肖、金森主祥、中西和樹、野平俊之、安部武志
    • Organizer
      Fourth International Conference on Multifunctional, Hybrid and Nanomaterials
    • Place of Presentation
      シッチェス(スペイン)
    • Year and Date
      2015-03-10
    • Related Report
      2014 Research-status Report
  • [Presentation] 多孔性カーボンモノリスへのヘテロ原子の導入2014

    • Author(s)
      長谷川丈二、金森主祥、中西和樹、小林洋治、陰山洋、安部武志
    • Organizer
      第41回炭素材料学会年会
    • Place of Presentation
      大野城(福岡県)
    • Year and Date
      2014-12-10
    • Related Report
      2014 Research-status Report
  • [Presentation] Nano-structured Porous Li4Ti5O12 as a High-Performance Anode for Li-ion and Na-ion Batteries2014

    • Author(s)
      長谷川丈二、金森主祥、清村勤、倉田博樹、中西和樹、安部武志
    • Organizer
      International Society of Electrochemistry 65th Annual Meeting
    • Place of Presentation
      ローザンヌ(スイス)
    • Year and Date
      2014-09-02
    • Related Report
      2014 Research-status Report
  • [Presentation] 階層的多孔構造を有するチタン酸リチウムの作製と二次電池電極への応用2014

    • Author(s)
      長谷川丈二、金森主祥、清村勤、倉田博樹、中西和樹、安部武志
    • Organizer
      第12回ゾル-ゲル討論会
    • Place of Presentation
      つくば(茨城県)
    • Year and Date
      2014-08-07
    • Related Report
      2014 Research-status Report
  • [Remarks] 京都大学大学院 理学研究科 化学専攻 無機物質化学研究室

    • URL

      http://kuchem.kyoto-u.ac.jp/mukibutsu/

    • Related Report
      2014 Research-status Report

URL: 

Published: 2014-04-04   Modified: 2017-05-10  

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