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Introduction of mesopore-derived strains for an enhancement of the Curie temperature of barium titanate

Research Project

Project/Area Number 26810126
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Inorganic industrial materials
Research InstitutionTokyo University of Science (2015)
National Institute for Materials Science (2014)

Principal Investigator

Norihiro Suzuki  東京理科大学, 研究推進機構総合研究院, 助教 (10595888)

Project Period (FY) 2014-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Fiscal Year 2015: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2014: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywords多孔体 / チタン酸バリウム / キュリー温度 / 歪み / ゾル-ゲル法 / Curie温度 / sol-gel法 / メソ多孔体 / ゾルゲル法
Outline of Final Research Achievements

Porous barium titanate thin film was synthesized by the soft-template method. From the temperature dependence of Raman spectrum, I clarified that ferroelectric tetragonal phase was thermally stabilized by introduced porosity. Owing to this, the Curie temperature (the temperature until which ferroelectricity remains) of porous thin film became much higher than that of a bulk single crystal. In addition, by analyzing the high-magnified transition electron microscope (TEM) image, I confirmed that the porosity introduced an anisotropic compressive strain, which deformed the crystal in order to enhance ferro(piezo)electricity.

Report

(3 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • Research Products

    (7 results)

All 2015 2014

All Journal Article (1 results) (of which Peer Reviewed: 1 results,  Acknowledgement Compliant: 1 results) Presentation (6 results) (of which Invited: 2 results)

  • [Journal Article] Chemical Preparation of Ferroelectric Mesoporous Barium Titanate Thin Films: Drastic Enhancement of Curie Temperature Induced by Mesopore-Derived Strain2014

    • Author(s)
      Norihiro Suzuki, Xiangfen Jiang, Rahul R. Salunkhe, Minoru Osada, Yusuke Yamauchi
    • Journal Title

      Chemistry -An European Journal

      Volume: 20 Issue: 36 Pages: 11283-11286

    • DOI

      10.1002/chem.201403308

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] チタン系(複合)酸化物多孔性薄膜の作製-細孔を活用した高性能デバイスへの試み-2015

    • Author(s)
      鈴木孝宗・山内悠輔
    • Organizer
      日本化学会 第95回春期年会
    • Place of Presentation
      船橋
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Research-status Report
  • [Presentation] 有機鋳型を用いた多孔性チタン酸バリウム薄膜の化学的合成-細孔由来歪みによる強誘電性/圧電特性の向上-2015

    • Author(s)
      鈴木孝宗・長田実・山内悠輔
    • Organizer
      日本セラミックス協会 2015年年会
    • Place of Presentation
      岡山
    • Year and Date
      2015-03-18 – 2015-03-20
    • Related Report
      2014 Research-status Report
  • [Presentation] Synthesis of mesoporous titanium (based) oxide thin films for device applications2015

    • Author(s)
      Norihiro Suzuki, Yusuke Yamauchi
    • Organizer
      MANA International Symposium 2015
    • Place of Presentation
      つくば
    • Year and Date
      2015-03-11 – 2015-03-13
    • Related Report
      2014 Research-status Report
  • [Presentation] Efficient use of nanopores to enhance the ferro(piezo)electricity in barium titanate2015

    • Author(s)
      Norihiro Suzuki
    • Organizer
      Symposium of Applied Research Collabolaration in Asia (SPARCA 2015)
    • Place of Presentation
      台北
    • Year and Date
      2015-02-08 – 2015-02-11
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] 界面活性剤を鋳型とした多孔性ペロブスカイト薄膜の合成-細孔を活用したチタン酸バリウムの強誘電性/圧電性向上-2014

    • Author(s)
      鈴木孝宗・長田実・山内悠輔
    • Organizer
      第30回ゼオライト研究発表会
    • Place of Presentation
      東京
    • Year and Date
      2014-11-26 – 2014-11-27
    • Related Report
      2014 Research-status Report
  • [Presentation] Mesoporous non-siliceous thin films toward highly efficient devices2014

    • Author(s)
      Norihiro Suzuki
    • Organizer
      International Conference on Advanced Materials and Nanotechnology for Sustainable Development (ICAMN-2014)
    • Place of Presentation
      Kathmandu
    • Year and Date
      2014-11-04 – 2014-11-06
    • Related Report
      2014 Research-status Report
    • Invited

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Published: 2014-04-04   Modified: 2017-05-10  

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