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Possibility of quantitative analysis for DLC films by solid-state NMR

Research Project

Project/Area Number 26820037
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Design engineering/Machine functional elements/Tribology
Research InstitutionTokyo Metropolitan Industrial Technology Research Institute

Principal Investigator

Kawaguchi Masahiro  地方独立行政法人東京都立産業技術研究センター, 開発本部開発第二部表面・化学技術グループ, 主任研究員 (40463054)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2016: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2015: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2014: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
KeywordsDLC / 固体NMR / 13C / PBIID
Outline of Final Research Achievements

In order to evaluate sp3 ratio of DLC films quantitatively, powdering process of DLC films and its material and mechanical properties are discussed by using several equipment in this study. 12C-DLC and 13C-DLC films were deposited on silicon wafer and iron sheet under same deposition conditions by PBII&D. From the results of TOF-SIMS, XPS, ERDA, and TEM-EELS measurements, material properties of 13C-DLC were almost same in comparison with that of 12C-DLC. From the results of nanoindentation test, friction test, and MSE test, mechanical properties of 13C-DLC were almost same in comparison with that of 12C-DLC. In addition, the effect of powdering process on change in structure of DLC films could be negligible in case of both 12C- and 13C-DLC films. On the other hands, residual stress of the films were released after the powdering process so that the effect of stress relaxation on each analytical process should discuss more and more as future works.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (8 results)

All 2017 2016 2015

All Presentation (8 results) (of which Int'l Joint Research: 2 results,  Invited: 2 results)

  • [Presentation] 13C-DLC膜の摩擦摩耗評価2017

    • Author(s)
      川口雅弘
    • Organizer
      (一社)日本機械学会
    • Place of Presentation
      東京理科大学
    • Year and Date
      2017-03-17
    • Related Report
      2016 Annual Research Report
  • [Presentation] DLC分析評価の現状と展望2016

    • Author(s)
      川口雅弘
    • Organizer
      平成28年度神奈川県産業技術センターものづくり技術交流会
    • Place of Presentation
      神奈川県産業技術センター
    • Year and Date
      2016-10-27
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] DLCコーティングの評価技術2016

    • Author(s)
      川口雅弘
    • Organizer
      (一社)表面技術協会材料昨日ドライプロセス部会第100回例会
    • Place of Presentation
      東京都立産業技術研究センター青海本部
    • Year and Date
      2016-05-18
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 13C DLC films deposited by PBII&D2015

    • Author(s)
      Masahiro Kawaguchi
    • Organizer
      International Tribology Conference, Tokyo 2015
    • Place of Presentation
      Tokyo Institute of Science
    • Year and Date
      2015-09-16 – 2015-09-20
    • Related Report
      2014 Research-status Report
  • [Presentation] 13C DLC films deposited by PBIID2015

    • Author(s)
      Masahiro Kawaguchi
    • Organizer
      International Tribology Conference
    • Place of Presentation
      Tokyo
    • Year and Date
      2015-09-16
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] MECHANICAL PROPERTIES OF 13C DLC FILMS DEPOSITED BY PBII&D2015

    • Author(s)
      Masahiro Kawaguchi
    • Organizer
      42nd Leed-Lyon Symposium on Tribology
    • Place of Presentation
      Valpré Lyon(仏国)
    • Year and Date
      2015-09-07 – 2015-09-09
    • Related Report
      2014 Research-status Report
  • [Presentation] Mechanical properties of 13C DLC films deposited by PBIID2015

    • Author(s)
      Masahiro Kawaguchi
    • Organizer
      42nd Leeds-Lyon Symposium on Tribology
    • Place of Presentation
      Lyon
    • Year and Date
      2015-09-07
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Deposition of 13C DLC films and its structural analysis2015

    • Author(s)
      Masahiro Kawaguchi
    • Organizer
      ISPlasma2015
    • Place of Presentation
      Nagoya University
    • Year and Date
      2015-03-26 – 2015-03-31
    • Related Report
      2014 Research-status Report

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Published: 2014-04-04   Modified: 2018-03-22  

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