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Development of Heteroepitaxial Diamond Wafers by Controlled Buffer Layers

Research Project

Project/Area Number 26820110
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Electronic materials/Electric materials
Research InstitutionTokyo Institute of Technology

Principal Investigator

Iwasaki Takayuki  東京工業大学, 工学院, 助教 (80454031)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2016: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2015: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2014: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Keywordsダイヤモンド / ヘテロエピタキシャル成長 / 核形成法 / 核形成モニタリング
Outline of Final Research Achievements

Nucleation and selection technologies of epitaxial diamonds were developed toward fabricating large-area hetero-diamond wafers. The diamond nucleation was performed using a molecular source and bias-enhancement methods. It was revealed that impurities between diamond and a buffer layer caused the formation of non-epitaxial diamonds. The impurities can be suppressed by a high amount of atomic hydrogen generated in a high power density plasma, leading to improvement of the orientation of (100) diamonds. On a (111) face, epitaxial diamonds were obtained with a combination of short-time bias treatment and oxygen addition. Finally, highly-oriented diamond films were achieved on both the (100) and (111) crystal faces.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (29 results)

All 2017 2016 2015 2014 Other

All Int'l Joint Research (2 results) Journal Article (5 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 5 results,  Acknowledgement Compliant: 3 results,  Open Access: 2 results) Presentation (22 results) (of which Int'l Joint Research: 10 results,  Invited: 2 results)

  • [Int'l Joint Research] 南フロリダ大学(米国)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] 南フロリダ大学(米国)

    • Related Report
      2015 Research-status Report
  • [Journal Article] Influence of High-Power-Density Plasma on Heteroepitaxial Diamond Nucleation on 3C-SiC Surface2017

    • Author(s)
      Junya Yaita, Meralys Natal, Stephen E. Saddow, Mutsuko Hatano, Takayuki Iwasaki*
    • Journal Title

      Applied Physics Express

      Volume: 10 Issue: 4 Pages: 045502-045502

    • DOI

      10.7567/apex.10.045502

    • NAID

      210000135821

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Highly oriented diamond (111) films synthesized by pulse bias-enhanced nucleation and epitaxial grain selection on a 3C-SiC-Si (111) substrate2017

    • Author(s)
      T. Suto, J. Yaita, T. Iwasaki, M. Hatano
    • Journal Title

      Appl. Phys. Lett.

      Volume: 110 Issue: 6 Pages: 062102-062102

    • DOI

      10.1063/1.4975630

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] High-Temperature Bipolar-Mode Operation of Normally-Off Diamond JFETIEEE Journal of the Electron Devices Society2017

    • Author(s)
      T. Iwasaki, H. Kato, T. Makino, M. Ogura, D. Takeuchi, S. Yamasaki, M. Hatano
    • Journal Title

      IEEE Journal of the Electron Devices Society

      Volume: 5 Issue: 1 Pages: 95-99

    • DOI

      10.1109/jeds.2016.2624301

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Normally-Off Diamond Junction Field-Effect Transistors With Submicrometer Channel2016

    • Author(s)
      Taisuke Suwa, Takayuki Iwasaki, Kazuki Sato, Hiromitsu Kato, Toshiharu Makino, Masahiko Ogura, Daisuke Takeuchi, Satoshi Yamasaki, Mutsuko Hatano
    • Journal Title

      IEEE ELECTRON DEVICE LETTERS

      Volume: 37 Issue: 2 Pages: 209-211

    • DOI

      10.1109/led.2015.2513074

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] hotoelectrochemical CO2 reduction on 3C-SiC photoanode in aqueous solution2015

    • Author(s)
      J. Yaita, T. Iwasaki, M. Natal, M. Hatano
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 54 Issue: 4S Pages: 04DH13-04DH13

    • DOI

      10.7567/jjap.54.04dh13

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 高酸素濃度成長を用いたSi(111)上高配向ダイヤ膜の合成2017

    • Author(s)
      須藤建瑠、桑原新之介、矢板潤也、岩崎孝之、波多野睦子
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川
    • Year and Date
      2017-03-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] High-Quality Heteroepitaxial Diamond Films Grown on 3C-SiC/Si Substrates2017

    • Author(s)
      J. Yaita, T. Iwasaki, M. Natal, S. E. Saddow, M. Hatano
    • Organizer
      Hasselt Diamond Workshop 2017
    • Place of Presentation
      Hasselt, Belgium
    • Year and Date
      2017-03-08
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Scaling Laws for the Dislocation Reduction in Heteroepitaxial Diamond Films on 3C-SiC/Si Substrates2016

    • Author(s)
      J. Yaita, T. Iwasaki, M. Natal, S. E. Saddow, M. Hatano
    • Organizer
      The Fifth International Education Forum on Environment and Energy Science
    • Place of Presentation
      San Diego, USA
    • Year and Date
      2016-12-15
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Heteroepitaxial growth of highly-oriented diamond films on 3C-SiC / Si (111) substrates by pulse bias enhanced nucleation2016

    • Author(s)
      T. Suto, J. Yaita, T. Iwasaki, M. Hatano
    • Organizer
      2016 MRS Fall Meeting & Exhibit
    • Place of Presentation
      Boston, USA
    • Year and Date
      2016-11-27
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] パルスバイアス核形成および選択的エッチング効果を用いた3C-SiC/Si上への(111)高配向ダイヤモンドの合成2016

    • Author(s)
      須藤建瑠、矢板潤也、岩崎孝之、波多野睦子
    • Organizer
      第30回ダイヤモンドシンポジウム
    • Place of Presentation
      東京
    • Year and Date
      2016-11-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] 3C-SiC(111)/Si(111)上への高配向ダイヤモンドのヘテロエピタキシャル成長2016

    • Author(s)
      須藤建瑠、矢板潤也、岩崎孝之、波多野睦子
    • Organizer
      第77回応用物理学会秋季学術講演会
    • Place of Presentation
      新潟
    • Year and Date
      2016-09-13
    • Related Report
      2016 Annual Research Report
  • [Presentation] 高密度プラズマを用いた3C-SiC/Si上のダイヤモンドヘテロエピタキシャル成長及び欠陥評価2016

    • Author(s)
      矢板潤也、岩崎孝之、Meralys Reyes-Natal、Stephen E. Saddow、波多野睦子
    • Organizer
      第77回応用物理学会秋季学術講演会
    • Place of Presentation
      新潟
    • Year and Date
      2016-09-13
    • Related Report
      2016 Annual Research Report
  • [Presentation] 高密度プラズマによる3C-SiC/Si上のダイヤモンド核配向性の向上2016

    • Author(s)
      矢板潤也, 岩崎孝之, Meralys Natal, Steven E. Saddow, 波多野睦子
    • Organizer
      第63回応用物理学会春季学術講演会
    • Place of Presentation
      東京
    • Year and Date
      2016-03-19
    • Related Report
      2015 Research-status Report
  • [Presentation] パルスバイアス核形成法を用いた3C-SiC(111)/Si(111)上への高配向ダイヤモンドの合成2016

    • Author(s)
      須藤建瑠、矢板潤也、岩崎孝之、波多野睦子
    • Organizer
      第63回応用物理学会春季学術講演会
    • Place of Presentation
      東京
    • Year and Date
      2016-03-19
    • Related Report
      2015 Research-status Report
  • [Presentation] 縦型ダイヤモンドJFETの作製2016

    • Author(s)
      諏訪泰介, 岩崎孝之, 加藤宙光, 牧野俊晴,小倉政彦,竹内大輔,山崎聡,波多野睦子
    • Organizer
      第63回応用物理学会春季学術講演会
    • Place of Presentation
      東京
    • Year and Date
      2016-03-19
    • Related Report
      2015 Research-status Report
  • [Presentation] Diamond Electronics2016

    • Author(s)
      T. Iwasaki
    • Organizer
      The 1st International Symposium of Applied Physics & Single-nano Excellent-Core in JAIST
    • Place of Presentation
      JAIST
    • Year and Date
      2016-03-02
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Improving of Heteroepitaxial Diamond Crystalline for Diamond Power Device Applications2015

    • Author(s)
      J. Yaita, T. Iwasaki, M. Natal, S. E. Saddow, M. Hatano
    • Organizer
      The Fourth International Education Forum on Environment and Energy Science
    • Place of Presentation
      Hawaii
    • Year and Date
      2015-12-06
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Effect of high plasma density on heteroepitaxial diamond nucleation on 3C-SiC/Si substrates2015

    • Author(s)
      J. Yaita, T. Iwasaki, M. R. Natal, S. E. Saddow, M. Hatano
    • Organizer
      2015 MRS Fall Meeting
    • Place of Presentation
      Boston
    • Year and Date
      2015-11-29
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] ショートパルス電圧核形成促進法による3C-SiC(111)/Si(111)上へのヘテロエピタキシャル成長2015

    • Author(s)
      須藤建瑠、矢板潤也、岩崎孝之、波多野睦子
    • Organizer
      第29回ダイヤモンドシンポジウム
    • Place of Presentation
      東京
    • Year and Date
      2015-11-17
    • Related Report
      2015 Research-status Report
  • [Presentation] Heteroepitaxial Growth of Diamond on 3C-SiC/Si Substrates by Antenna-Edge Microwave Plasma CVD2015

    • Author(s)
      T. Suto, J. Yaita, T. Iwasaki, M. Natal, S. E. Saddow, M. Hatano
    • Organizer
      2015 International Conference on Solid State Devices and Materials (SSDM)
    • Place of Presentation
      Sapporo
    • Year and Date
      2015-09-27
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Heteroepitaxial Growth of Diamond on 3C-SiC/Si by Antenna-edge Microwave Plasma CVD2015

    • Author(s)
      T. Suto, J. Yaita, T. Iwasaki, M. Hatano
    • Organizer
      Diamond Quantum Sensing Workshop 2015
    • Place of Presentation
      Takamatsu
    • Year and Date
      2015-08-05
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Improvement of the Nucleation Density and Orientation of Diamond Nuclei on 3C-SiC/Si Substrates by Using High Power Density Plasma2015

    • Author(s)
      J. Yaita, T. Iwasaki, M. Natal, S. E. Saddow, M. Hatano
    • Organizer
      9th International Conference on New Diamond and Nano Carbons (NDNC) 2015
    • Place of Presentation
      Shizuoka
    • Year and Date
      2015-05-24
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Diamond Junction Field-Effect Transistors and Heteroepitaxial Growth Toward Large-Size Wafer2015

    • Author(s)
      T. Iwasaki
    • Organizer
      CMOS Emerging Technologies Research 2015
    • Place of Presentation
      Vancouver
    • Year and Date
      2015-05-20
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Heteroepitaxial Growth of Highly-Oriented Diamond Films on Si(001) Substrates with 3C-SiC(001) Buffer Layers2014

    • Author(s)
      J. Yaita, T. Iwasaki, M. Natal, S. E. Saddow, M. Hatano
    • Organizer
      2014 MRS Fall Meeting
    • Place of Presentation
      Boston, USA
    • Year and Date
      2014-11-30 – 2014-12-05
    • Related Report
      2014 Research-status Report
  • [Presentation] 先端放電型プラズマCVDを用いた3C-SiC/Si上へのダイヤモンドヘテロエピタキシャル成長2014

    • Author(s)
      矢板潤也, 岩崎孝之, Meralys Natal, Steven E. Saddow, 波多野睦子,
    • Organizer
      第28回ダイヤモンドシンポジウム
    • Place of Presentation
      東京
    • Year and Date
      2014-11-19 – 2014-11-21
    • Related Report
      2014 Research-status Report
  • [Presentation] 先端放電型プラズマCVDを用いた3C-SiC(001)/Si(001)ウェハ上への高配向ダイヤモンド薄膜合成2014

    • Author(s)
      矢板潤也, 岩崎孝之, Meralys Natal, Steven E. Saddow, 波多野睦子
    • Organizer
      第75回応用物理学会秋季学術講演会
    • Place of Presentation
      北海道
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Research-status Report
  • [Presentation] Heteroepitaxial Growth of Diamond Films on 3C-SiC(001)/Si substrates by Antenna-Edge Microwave Plasma CVD2014

    • Author(s)
      J. Yaita, T. Iwasaki, M. Natal, S. E. Saddow, M. Hatano
    • Organizer
      SSDM 2014
    • Place of Presentation
      Tsukuba, Japan
    • Year and Date
      2014-09-08 – 2014-09-11
    • Related Report
      2014 Research-status Report

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Published: 2014-04-04   Modified: 2022-02-16  

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