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Development of metal salt coated insert sheet and their application to low temperature precise bonding

Research Project

Project/Area Number 26820124
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Electron device/Electronic equipment
Research InstitutionGunma University

Principal Investigator

KOYAMA Shinji  群馬大学, 大学院理工学府, 准教授 (70414109)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2016: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2015: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2014: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Keywords低温接合 / 電子デバイス / 精密接合 / 固相接合 / 液相拡散接合 / 金属塩生成接合法 / インサート金属 / アルミニウム / チタン / 銅 / ステンレス鋼 / ギ酸 / クエン酸 / 接合
Outline of Final Research Achievements

The application of low-temperature bonding in industrial processes has been explored in an effort to miniaturize electronic equipment. However, low-temperature bonding has been difficult to achieve because of the presence of oxide film. Therefore, an economical method to obtain a high-tensile strength joint at a low temperature and load is required. In previous research showed that surface modification with organic acid decreased the bonding temperature and the deformation in the solid-state bonding of Al and Cu. Therefore, in this investigation, we aimed to obtain a deeper understanding of the effect of surface modification on the performance of a solid-state bonded joint of Al alloy/pure Zn and pure Ti/pure Al. When surface modification is applied, it is clarified that a high-tensile strength joint can be obtained at a low temperature because metallic Zn and Al are exposed as a result of the decomposition of metal salt in the bond interface at a low bonding temperature.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (39 results)

All 2017 2016 2015 2014

All Journal Article (5 results) (of which Peer Reviewed: 4 results,  Acknowledgement Compliant: 4 results) Presentation (32 results) (of which Int'l Joint Research: 4 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] Solid-State Bonding of 5052 Aluminum Alloy/316L Stainless Steel by Using Organic Salt Formation/Decomposition Reaction2016

    • Author(s)
      Hiroki Saito, Shinji Koyama
    • Journal Title

      Materials Science Forum

      Volume: 879 Pages: 2468-2472

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Effect of Interfacial Hardness on Failure Modes of Liquid Phase Diffusion Bonded Sn/Sn with Bi Filler2016

    • Author(s)
      Shinji Koyama, Issei Oya and Ikuo Shohji
    • Journal Title

      Materials Transactions

      Volume: 57 Pages: 810-814

    • NAID

      130005153152

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Direct bonding of SUS304 stainless steel by metal salt generation bonding technique with formic acid2016

    • Author(s)
      Shinji Koyama, Tatsunori Tsuneto
    • Journal Title

      Procedia Materials Science

      Volume: 12 Pages: 95-99

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] 構造材料の精密・低温接合に向けた金属塩被膜付与インサート材の創製2016

    • Author(s)
      小山真司
    • Journal Title

      溶接技術

      Volume: 64 Pages: 96-97

    • Related Report
      2016 Annual Research Report
  • [Journal Article] Cu/Cu direct bonding by metal salt generation bonding technique with organic acid and its persistence of reformed layer2015

    • Author(s)
      Shinji Koyama, Naoki Hagiwara, Ikuo Shohji
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 54 Pages: 0302161-0302164

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] A6061/SUS316Lの固相接合強度に及ぼすギ酸を用いた金属塩生成処理の効果2017

    • Author(s)
      齋藤広輝, 石原重憲, 鶴岡茂樹, 小山真司, 荘司郁夫
    • Organizer
      Mate 2017(Microjoining and Assembly Technology in Electronics)
    • Place of Presentation
      パシフィコ横浜会議センター(神奈川県・横浜市)
    • Year and Date
      2017-01-31
    • Related Report
      2016 Annual Research Report
  • [Presentation] インサート材の金属塩被膜付与条件の最適化と鋳造用Al合金の接合界面への適用2017

    • Author(s)
      西城舜哉, 小山真司, 荘司郁夫
    • Organizer
      Mate 2017(Microjoining and Assembly Technology in Electronics)
    • Place of Presentation
      パシフィコ横浜会議センター(神奈川県・横浜市)
    • Year and Date
      2017-01-31
    • Related Report
      2016 Annual Research Report
  • [Presentation] Liquid Phase Diffusion Bonding of AC2C and ADC12 Aluminum Casting Alloy by using Metal Salt Coated Zn Sheet2016

    • Author(s)
      Shunya Saijo, Shinji Koyama, Ikuo Shohji
    • Organizer
      AMPT2016(国際会議)
    • Place of Presentation
      Kuala Lumpur(Malaysia)
    • Year and Date
      2016-11-08
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] SOLID-STATE DIFFUSION BONDING OF TITANIUM BY USIG METAL SALT COATED ALUMINUM SHEET2016

    • Author(s)
      S. KOYAMA, N.V. PHU
    • Organizer
      7th International Conference, New Methods of Damage and Failure Analysis of Structural Parts(国際会議)
    • Place of Presentation
      横浜国立大学教育文化ホール(神奈川県・横浜市)
    • Year and Date
      2016-11-01
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Optimization of Formate Coating Conditions on Cu Powder and Its Application for Solid-state Bonding of Cu/Cu Interface and Persistence of Reformed Layer2016

    • Author(s)
      Shunya Saijo, Shinji Koyama
    • Organizer
      MS&T16(国際会議)
    • Place of Presentation
      Salt Lake City, Utah(USA)
    • Year and Date
      2016-10-23
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] A5052/SUS316Lの接合強度に及ぼすギ酸塩被膜処理効果とその化学特性評価2016

    • Author(s)
      齋藤広輝, 石原重憲, 鶴岡茂樹, 小山真司, 荘司郁夫
    • Organizer
      日本金属学会2016年秋期講演大会
    • Place of Presentation
      大阪大学豊中キャンパス(大阪府・豊中市)
    • Year and Date
      2016-09-21
    • Related Report
      2016 Annual Research Report
  • [Presentation] ギ酸塩被膜付与Znシートを用いた鋳造用Al合金の液相拡散接合2016

    • Author(s)
      西城舜哉, 小山真司, 荘司郁夫
    • Organizer
      日本金属学会2016年秋期講演大会
    • Place of Presentation
      大阪大学豊中キャンパス(大阪府・豊中市)
    • Year and Date
      2016-09-21
    • Related Report
      2016 Annual Research Report
  • [Presentation] 金属塩被膜を付与したインサート材を用いたAl合金の液相拡散接合2016

    • Author(s)
      西城舜哉, 小山真司, 荘司郁夫
    • Organizer
      溶接学会平成28年度秋季全国大会
    • Place of Presentation
      HOTEL天坊(群馬県・渋川市)
    • Year and Date
      2016-09-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] A5052/SUS316Lの接合強度に及ぼす金属塩生成処理効果とその持続性評価2016

    • Author(s)
      斎藤広輝, 小山真司, 荘司郁夫
    • Organizer
      溶接学会平成28年度秋季全国大会
    • Place of Presentation
      HOTEL天坊(群馬県・渋川市)
    • Year and Date
      2016-09-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] Solid-state Bonding of 5052 Aluminum Alloy/316L Stainless Steel by Using Organic Salt Formation/decomposition Reaction2016

    • Author(s)
      Hiroki Saito, Shinji Koyama
    • Organizer
      THERMEC'2016
    • Place of Presentation
      Graz(Austria)
    • Year and Date
      2016-05-29
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 純Al/SUS304の固相接合強度に及ぼす金属塩生成処理の効果2016

    • Author(s)
      齋藤広輝, 小山真司
    • Organizer
      Mate 2016(Microjoining and Assembly Technology in Electronics)
    • Place of Presentation
      パシフィコ横浜(神奈川県横浜市西区)
    • Year and Date
      2016-02-02
    • Related Report
      2015 Research-status Report
  • [Presentation] SUS304鋼の固相接合強度に及ぼす金属塩被膜処理効果とその持続性2016

    • Author(s)
      常藤達礼, 小山真司, 白鳥智美
    • Organizer
      Mate 2016(Microjoining and Assembly Technology in Electronics)
    • Place of Presentation
      パシフィコ横浜(神奈川県横浜市西区)
    • Year and Date
      2016-02-02
    • Related Report
      2015 Research-status Report
  • [Presentation] 金属塩被膜付与Znシートを用いたA5052合金の低温接合2015

    • Author(s)
      冨川陽平, 小山真司
    • Organizer
      軽金属学会第129回秋期大会
    • Place of Presentation
      日本大学津田沼キャンパス(千葉県習志野市泉町)
    • Year and Date
      2015-11-21
    • Related Report
      2015 Research-status Report
  • [Presentation] Solid-State Bonding of Ni/Ni by Using Metal Salt Generation Bonding Technique2015

    • Author(s)
      Saito Hiroki, Shinji Koyama
    • Organizer
      MS&T15
    • Place of Presentation
      Greater Columbus Convention Center (Columbus, Ohio, USA)
    • Year and Date
      2015-10-07
    • Related Report
      2015 Research-status Report
  • [Presentation] Solid-State Bonding of Casting Aluminum Alloy by Using Metal Salt Coated Aluminum Sheet2015

    • Author(s)
      Yohei Tomikawa, Shinji Koyama
    • Organizer
      MS&T15
    • Place of Presentation
      Greater Columbus Convention Center (Columbus, Ohio, USA)
    • Year and Date
      2015-10-07
    • Related Report
      2015 Research-status Report
  • [Presentation] ギ酸塩被膜付与Cu粉末を用いたCu/Cu直接固相接合2015

    • Author(s)
      西城舜哉,小山真司
    • Organizer
      日本金属学会 2015年秋期講演大会
    • Place of Presentation
      九州大学伊都キャンパス(福岡県福岡市西区)
    • Year and Date
      2015-09-18
    • Related Report
      2015 Research-status Report
  • [Presentation] ギ酸を用いた金属塩生成・電気アシスト接合法によるAC2C/ADC12の固相接合2015

    • Author(s)
      冨川陽平,小山真司
    • Organizer
      日本金属学会 2015年秋期講演大会
    • Place of Presentation
      九州大学伊都キャンパス(福岡県福岡市西区)
    • Year and Date
      2015-09-18
    • Related Report
      2015 Research-status Report
  • [Presentation] 酢酸を用いた金属塩生成接合法による純Al/SUS304の固相接合2015

    • Author(s)
      齋藤広輝,小山真司
    • Organizer
      日本金属学会 2015年秋期講演大会
    • Place of Presentation
      九州大学伊都キャンパス(福岡県福岡市西区)
    • Year and Date
      2015-09-18
    • Related Report
      2015 Research-status Report
  • [Presentation] SUS304鋼の直接固相接合強度に及ぼす酢酸を用いた金属塩被膜処理効果2015

    • Author(s)
      常藤達礼,小山真司,白鳥智美
    • Organizer
      日本金属学会 2015年秋期講演大会
    • Place of Presentation
      九州大学伊都キャンパス(福岡県福岡市西区)
    • Year and Date
      2015-09-18
    • Related Report
      2015 Research-status Report
  • [Presentation] ギ酸アルミニウムの生成・分解反応を利用した純Al/SUS304ステンレス鋼の固相接合2015

    • Author(s)
      齋藤広輝,小山真司
    • Organizer
      溶接学会平成27年度秋季全国大会
    • Place of Presentation
      北海道科学大学(北海道札幌市手稲区)
    • Year and Date
      2015-09-04
    • Related Report
      2015 Research-status Report
  • [Presentation] SUS304鋼の直接固相接合強度に及ぼすギ酸・クエン酸を用いた金属塩被膜処理効果2015

    • Author(s)
      常藤達礼,小山真司,白鳥智美
    • Organizer
      溶接学会平成27年度秋季全国大会
    • Place of Presentation
      北海道科学大学(北海道札幌市手稲区)
    • Year and Date
      2015-09-03
    • Related Report
      2015 Research-status Report
  • [Presentation] ギ酸を用いた金属塩生成接合法によるAC2C/ADC12の固相接合2015

    • Author(s)
      冨川陽平,小山真司
    • Organizer
      溶接学会平成27年度秋季全国大会
    • Place of Presentation
      北海道科学大学(北海道札幌市手稲区)
    • Year and Date
      2015-09-03
    • Related Report
      2015 Research-status Report
  • [Presentation] ギ酸と酢酸を用いた金属塩生成接合法によるA6061合金の精密固相接合2015

    • Author(s)
      冨川陽平,小山真司
    • Organizer
      シンポジウムMate2015
    • Place of Presentation
      パシフィコ横浜(神奈川県横浜市西区)
    • Year and Date
      2015-02-04
    • Related Report
      2014 Research-status Report
  • [Presentation] クエン酸を用いた金属塩生成接合法によるSUS304ステンレス鋼の固相接合2015

    • Author(s)
      常藤達礼,小山真司
    • Organizer
      シンポジウムMate2015
    • Place of Presentation
      パシフィコ横浜(神奈川県横浜市西区)
    • Year and Date
      2015-02-04
    • Related Report
      2014 Research-status Report
  • [Presentation] 金属塩被膜付与Znシートの創製とA5052アルミニウム合金接合部への適用2015

    • Author(s)
      馬小娟,冨川陽平,秋山主,小山真司
    • Organizer
      シンポジウムMate2015
    • Place of Presentation
      パシフィコ横浜(神奈川県横浜市西区)
    • Year and Date
      2015-02-03
    • Related Report
      2014 Research-status Report
  • [Presentation] 有機酸を用いた金属塩生成接合法によるTi/Alの固相接合条件の最適化2015

    • Author(s)
      秋山主,小山真司
    • Organizer
      シンポジウムMate2015
    • Place of Presentation
      パシフィコ横浜(神奈川県横浜市西区)
    • Year and Date
      2015-02-03
    • Related Report
      2014 Research-status Report
  • [Presentation] Ti/Alのギ酸を用いた金属塩生成接合条件の最適化2014

    • Author(s)
      秋山主,小山真司
    • Organizer
      日本金属学会 2014秋期講演大会
    • Place of Presentation
      名古屋大学東山キャンパス(愛知県名古屋市千種区)
    • Year and Date
      2014-09-26
    • Related Report
      2014 Research-status Report
  • [Presentation] ギ酸を用いた金属塩生成接合法によるA6061合金の固相接合2014

    • Author(s)
      冨川陽平,小山真司
    • Organizer
      日本金属学会 2014秋期講演大会
    • Place of Presentation
      名古屋大学東山キャンパス(愛知県名古屋市千種区)
    • Year and Date
      2014-09-26
    • Related Report
      2014 Research-status Report
  • [Presentation] Direct Bonding of Cu/Cu by metal salt generation bonding technique with formic acid and acetic acid2014

    • Author(s)
      Shinji Koyama, Naoki Hagiwara, Ikuo Shohji
    • Organizer
      6th International Conference, New Methods of Damage and Failure Analysis of Structural Parts
    • Place of Presentation
      Ostrava, Czech Republic
    • Year and Date
      2014-09-08
    • Related Report
      2014 Research-status Report
  • [Presentation] Direct Bonding of Ti/Al by Metal Salt Generation Bonding Technique with Formic Acid2014

    • Author(s)
      Tsukasa Akiyama, Shinji Koyama
    • Organizer
      6th International Conference, New Methods of Damage and Failure Analysis of Structural Parts
    • Place of Presentation
      Ostrava (Czech Republic)
    • Year and Date
      2014-09-08
    • Related Report
      2014 Research-status Report
  • [Presentation] Direct Bonding of A6061 Aluminum Alloy by Metal Salt Generation Bonding Technique with Formic Acid2014

    • Author(s)
      Yohei Tomikawa, Shinji Koyama
    • Organizer
      6th International Conference, New Methods of Damage and Failure Analysis of Structural Parts
    • Place of Presentation
      Ostrava (Czech Republic)
    • Year and Date
      2014-09-08
    • Related Report
      2014 Research-status Report
  • [Presentation] Effect of Surface Modification by Aqueous NaOH Solution on Bond Strength of A5052 Aluminum Alloy/Al and Cu/Al2014

    • Author(s)
      Xiaojuan Ma, Shinji Koyama
    • Organizer
      6th International Conference, New Methods of Damage and Failure Analysis of Structural Parts
    • Place of Presentation
      Ostrava (Czech Republic)
    • Year and Date
      2014-09-08
    • Related Report
      2014 Research-status Report
  • [Patent(Industrial Property Rights)] チタン材の接合方法2015

    • Inventor(s)
      小山 真司
    • Industrial Property Rights Holder
      群馬大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2015-018287
    • Filing Date
      2015-02-02
    • Related Report
      2014 Research-status Report
  • [Patent(Industrial Property Rights)] 金属の接合方法2014

    • Inventor(s)
      小山真司,馬小娟,常藤達礼,秋山主,冨川陽平
    • Industrial Property Rights Holder
      群馬大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2014-264109
    • Filing Date
      2014-12-26
    • Related Report
      2014 Research-status Report

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Published: 2014-04-04   Modified: 2018-03-22  

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