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Study for magnetic field effects on phase formation of Mn-based magnetic materials, and the optimization of the synthesis under magnetic fields

Research Project

Project/Area Number 26820281
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Physical properties of metals/Metal-base materials
Research InstitutionKagoshima University

Principal Investigator

Mitsui Yoshifuru  鹿児島大学, 理工学域理学系, 准教授 (90649782)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2016: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2015: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2014: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Keywords強磁性 / 強磁場 / マンガン / 反応 / 相変態 / マンガン系強磁性体 / 焼結 / 磁場中熱処理 / 反応焼結 / ハード磁性材料
Outline of Final Research Achievements

Magnetic field effects on the reaction and the phase formation of Mn-based ferromagnets were investigated. In this study, the reactive sintering of MnBi, and phase formation of ferromagnetic phase of Mn-Al alloys were focused on. Reactive sintering of MnBi was enhanced by magnetic fields. It was found that magnetic field enhanced the number of formed MnBi phase around Mn grain at the initial stage of the reaction. Furthermore, almost complete uniaxial oriented MnBi bulk samples were obtained by both solid-phase and liquid-phase sintering under high magnetic field.
Phase formation of ferromagnetic Mn-Al alloys was also enhanced by in-field annealing. The field-induced enhancement of the phase formation of ferromagnetic Mn-Al phase was largest for the annealing at 623 K, which was just below Curie temperature of ferromagnetic phase.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (18 results)

All 2017 2016 2015 2014 Other

All Journal Article (5 results) (of which Peer Reviewed: 5 results,  Acknowledgement Compliant: 4 results) Presentation (11 results) (of which Int'l Joint Research: 4 results,  Invited: 1 results) Remarks (1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Annealing temperature and magnetic field effects for ε-τ transformation in Mn-Al alloys2017

    • Author(s)
      R. Kobayashi, Y. Mitsui, R.Y. Umetsu, K. Takahashi, M. Mizuguchi, K. Koyama
    • Journal Title

      IEEE Magn. Lett.

      Volume: 8 Pages: 1400704-1400704

    • DOI

      10.1109/lmag.2016.2617859

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Enhancement of the Phase Formation Rate during In-Field Solid-Phase Reactive Sintering of Mn-Bi2017

    • Author(s)
      D. Miyazaki, Y. Mitsui, R. Y. Umetsu, K. Takahashi, S. Uda, K. Koyama
    • Journal Title

      MATERIALS TRANSACTIONS

      Volume: 58 Issue: 5 Pages: 720-723

    • DOI

      10.2320/matertrans.MBW201609

    • NAID

      130005611923

    • ISSN
      1345-9678, 1347-5320
    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Magnetic field effects on reactive sintering of MnBi2016

    • Author(s)
      Ken-ichi Abematsu, Yoshifuru Mitsui, Atsushi Taira, Daiki Miyazaki, Akio Takaki, Rie Y. Umetsu, Kohki Takahashi, Keiichi Koyama
    • Journal Title

      AIP conference proceedings

      Volume: 1763 Pages: 020010-020010

    • DOI

      10.1063/1.4961343

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Magnetic field effects on liquid-phase reactive sintering of MnBi2016

    • Author(s)
      Yoshifuru Mitsui, Ken-ichi Abematsu, Rie Y. Umetsu, Kohki Takahashi, Keiichi Koyama
    • Journal Title

      Journal of Magnetism and Magnetic Materials

      Volume: 400 Pages: 304-306

    • DOI

      10.1016/j.jmmm.2015.07.114

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Magnetic-field-induced enhancement for synthesizing ferromagnetic MnBi phase by solid-state reaction sintering2014

    • Author(s)
      Y. Mitsui, R. Y. Umetsu, K. Koyama, K. Watanabe
    • Journal Title

      Journal of Alloys and Compounds

      Volume: 615 Pages: 131-134

    • DOI

      10.1016/j.jallcom.2014.06.131

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Presentation] In-magnetic-field annealing for Mn-based alloys2016

    • Author(s)
      Yoshifuru Mitsui, Ryota Kobayashi, Rie Y. Umetsu, Kohki Takahashi, Masaki Mizuguchi, Keiichi Koyama
    • Organizer
      International conference of the Asian Union of Magnetics Society
    • Place of Presentation
      Tainan(Taiwan)
    • Year and Date
      2016-08-01
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Selective crystallization in Mn-based alloys by in-field heat treatment2016

    • Author(s)
      Yoshifuru Mitsui, Ryota Kobayashi, Ken-ichi Abematsu, Rie Y. Umetsu, Kohki Takahashi, Masaki Mizuguchi, Keiichi Koyama
    • Organizer
      7th international workshop on materials analysis and processing in magnetic fields
    • Place of Presentation
      Providence(USA)
    • Year and Date
      2016-06-15
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Mn-Al合金の磁場中熱処理温度と磁気特性2016

    • Author(s)
      三井好古、小林領太、梅津理恵、高橋弘紀、水口将輝、高梨弘毅、小山佳一
    • Organizer
      2016年日本金属学会春期講演大会
    • Place of Presentation
      東京理科大学葛飾キャンパス(東京都葛飾区)
    • Year and Date
      2016-03-23
    • Related Report
      2015 Research-status Report
  • [Presentation] Magnetic-field-induced reaction in Bi-Mn alloys2015

    • Author(s)
      Yoshifuru Mitsui, Atsushi Taira, Daiki Miyazaki, Akio Takaki, Rie Y. Umetsu, Kohki Takahashi Keiichi Koyama
    • Organizer
      2nd international symposium on frontiers in materials science
    • Place of Presentation
      早稲田大学西早稲田キャンパス(東京都新宿区)
    • Year and Date
      2015-11-19
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Magnetic field effects on reaction-sintering of MnBi2015

    • Author(s)
      Y. Mitsui, K. Abematsu, R. Y. Umetsu, K. Takahashi, K. Koyama
    • Organizer
      International conference on magnetism
    • Place of Presentation
      Barcelona, Spain
    • Year and Date
      2015-07-05 – 2015-07-10
    • Related Report
      2014 Research-status Report
  • [Presentation] Magnetic field effects on reaction-sintering of MnBi2015

    • Author(s)
      Yoshifuru Mitsui, Ken-ichi Abematsu, Rie Y. Umetsu, Kohki Takahashi, Keiichi Koyama
    • Organizer
      20th international conference on magnetism
    • Place of Presentation
      Barcelona, Spain
    • Year and Date
      2015-07-05
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] 磁場中反応焼結によって作製したMnBiの磁気特性2014

    • Author(s)
      三井好古、アベ松賢一、梅津理恵、渡辺和雄、小山佳一
    • Organizer
      日本磁気科学会
    • Place of Presentation
      高山市民文化会館、高山市、岐阜
    • Year and Date
      2014-11-13 – 2014-11-14
    • Related Report
      2014 Research-status Report
  • [Presentation] MnBiの磁場中反応焼結に対する熱処理時間の影響2014

    • Author(s)
      三井好古、アベ松賢一、梅津理恵、渡辺和雄、小山佳一
    • Organizer
      日本金属学会
    • Place of Presentation
      名古屋大学、名古屋市、愛知
    • Year and Date
      2014-09-24 – 2014-09-26
    • Related Report
      2014 Research-status Report
  • [Presentation] 強磁性MnBiの強磁場中合成過程2014

    • Author(s)
      三井好古、アベ松賢一、梅津理恵、渡辺和雄、小山佳一
    • Organizer
      応用物理学会
    • Place of Presentation
      北海道大学、札幌市、北海道
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Research-status Report
  • [Presentation] In-field heat treatment effect for Mn-based ferromagnetic materials2014

    • Author(s)
      Y. Mitsui, K. Abematsu, R. Y. Umetsu, K. Watanabe, K. Koyama
    • Organizer
      6th international workshop on materials analysis and processing in magnetic fields
    • Place of Presentation
      サザンビーチホテル&リゾート沖縄(糸満市)及び万国津梁館(名護市)、沖縄
    • Year and Date
      2014-07-08 – 2014-07-11
    • Related Report
      2014 Research-status Report
  • [Presentation] 強磁性MnBiの合成に対する磁場効果2014

    • Author(s)
      三井好古、アベ松賢一、梅津理恵、小山佳一、渡辺和雄
    • Organizer
      日本金属学会九州支部学術講演会
    • Place of Presentation
      崇城大学、熊本市、熊本
    • Year and Date
      2014-06-07
    • Related Report
      2014 Research-status Report
  • [Remarks] 鹿児島大学ニュースリリース ”磁場を利用した新しい磁石合成法を開発”

    • URL

      https://www.kagoshima-u.ac.jp/about/release/newsH26.html#08

    • Related Report
      2014 Research-status Report
  • [Patent(Industrial Property Rights)] Mn-Al永久磁石の製造法及びMn-Al永久磁石2016

    • Inventor(s)
      三井好古、小林領太、小山佳一、梅津理恵、水口将輝
    • Industrial Property Rights Holder
      三井好古、小林領太、小山佳一、梅津理恵、水口将輝
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2016-041157
    • Filing Date
      2016-03-03
    • Related Report
      2015 Research-status Report

URL: 

Published: 2014-04-04   Modified: 2018-03-22  

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