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Elucidation of mechanism of fast ionic conduction in complex hydrides and functional deployments as multivalent ionic conductors and ionic liquids

Research Project

Project/Area Number 26820311
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Structural/Functional materials
Research InstitutionTohoku University

Principal Investigator

Matsuo Motoaki  東北大学, 金属材料研究所, 講師 (20509038)

Research Collaborator UNEMOTO Atsushi  東北大学, 原子分子材料科学高等研究機構, 講師 (10551525)
IKESHOJI Tamio  東北大学, 金属材料研究所, 客員研究員
TAKAMURA Hitoshi  東北大学, 大学院工学研究科, 教授 (30250715)
ORIMO Shin-ichi  東北大学, 原子分子材料科学高等研究機構, 教授 (40284129)
Udovic Terrence J.  米国国立標準技術研究所, 中性子研究所, 研究員
Skripov Alexander V.  ロシア科学アカデミー, 金属物理学研究所, 研究員
Project Period (FY) 2014-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2015: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2014: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywords水素化物 / ナトリウムイオン伝導 / 錯体水素化物 / リチウムイオン伝導 / 固体電解質
Outline of Final Research Achievements

Sodium ion rechargeable batteries have recently attracted considerable interest as one of post lithium ion rechargeable batteries because of sodium's low cost and natural abundance. To this end, it is very important to develop sodium fast ionic conductors which can be used as solid electrolytes for the sodium ion rechargeable batteries. In this study, we have succeeded in synthesizing new solid-state hydrides such as Na2B10H10, Na2B12H12, NaCB9H10 and NaCB11H12 with fast ionic conductivities.

Report

(3 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • Research Products

    (36 results)

All 2016 2015 2014 Other

All Int'l Joint Research (2 results) Journal Article (11 results) (of which Int'l Joint Research: 4 results,  Peer Reviewed: 10 results,  Acknowledgement Compliant: 9 results,  Open Access: 4 results) Presentation (19 results) (of which Int'l Joint Research: 3 results,  Invited: 5 results) Remarks (2 results) Patent(Industrial Property Rights) (2 results)

  • [Int'l Joint Research] アメリカ国立標準技術研究所/サンディア国立研究所(米国)

    • Related Report
      2015 Annual Research Report
  • [Int'l Joint Research] ロシア科学アカデミー(ロシア連邦)

    • Related Report
      2015 Annual Research Report
  • [Journal Article] Liquid-like ionic conduction in solid lithium and sodium monocarba-closo-decaborates near or at room temperature2016

    • Author(s)
      Wan Si Tang, Motoaki Matsuo, Hui Wu, Vitalie Stavila, Wei Zhou, Albert A. Talin, Alexei V. Soloninin, Roman V. Skoryunov, Olga A. Babanova, Alexander V. Skripov, Atsushi Unemoto, Shin-ichi Orimo, Terrence. J. Udovic
    • Journal Title

      Advanced Energy Materaterials

      Volume: 6 Issue: 8

    • DOI

      10.1002/aenm.201502237

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Stabilizing lithium and sodium fast-ion conduction in solid polyhedral-borate salts at device-relevant temperatures2016

    • Author(s)
      Wan Si Tang, Motoaki Matsuo, Hui Wu, Vitalie Stavila, Atsushi Unemoto, Shin-ichi Orimo, Terrence. J. Udovic
    • Journal Title

      Energy Storage Materials

      Volume: 4 Pages: 79-83

    • DOI

      10.1016/j.ensm.2016.03.004

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] 1.新規イオン伝導体群としての錯体水素化物 —材料探索と全固体電池への実装—2016

    • Author(s)
      松尾元彰, 宇根本篤, 折茂慎一
    • Journal Title

      Electrochemistry

      Volume: 84 Issue: 1 Pages: 26-30

    • DOI

      10.5796/electrochemistry.84.26

    • NAID

      130005118463

    • ISSN
      1344-3542, 2186-2451
    • Related Report
      2015 Annual Research Report
    • Acknowledgement Compliant
  • [Journal Article] Atomic motion in the complex hydride Li3(NH2)2I: 7Li and 1H nuclear magnetic resonance studies2015

    • Author(s)
      A.V. Skripov, R.V. Skoryunov, A.V. Soloninin, O.A. Babanova, M. Matsuo, S. Orimo
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 119 Issue: 24 Pages: 13459-13464

    • DOI

      10.1021/acs.jpcc.5b03183

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Unparalleled lithium and sodium superionic conduction in solid electrolytes with large monovalent cage-like anions2015

    • Author(s)
      W.S. Tang, A. Unemoto, W. Zhou, V. Stavila, M. Matsuo, H. Wu, S. Orimo, T.J. Udovic
    • Journal Title

      Energy and Environmental Science

      Volume: 8 Issue: 12 Pages: 3637-3645

    • DOI

      10.1039/c5ee02941d

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Effect of lithium ion conduction on hydrogen desorption of LiNH2-LiH solid composite2015

    • Author(s)
      Tengfei Zhang, Shigehito Isobe, Motoaki Matsuo, Shin-ichi Orimo, Yongming Wang, Somei Ohnuki
    • Journal Title

      ACS Catalysis

      Volume: 5 Issue: 3 Pages: 1552-1555

    • DOI

      10.1021/cs501782y

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Complex transition metal hydrides incorporating ionic hydrogen: Thermal decomposition pathway of Na2Mg2FeH8 and Na2Mg2RuH82015

    • Author(s)
      T.D. Humphries, M. Matsuo, G. Li, S, Orimo
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 17 Issue: 12 Pages: 8276-8282

    • DOI

      10.1039/c5cp00258c

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Sodium superionic conduction in Na2B12H122014

    • Author(s)
      T.J. Udovic, M. Matsuo, A.Unemoto, N. Verdal, V. Stavila, A.V. Skripov, J.J. Rush, H. Takamura, S. Orimo
    • Journal Title

      Chemical Communications

      Volume: 50 Issue: 28 Pages: 3750-3752

    • DOI

      10.1039/c3cc49805k

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Exceptional superionic conductivity in disordered sodium decahydro-closo-decaborate2014

    • Author(s)
      T.J. Udovic, M. Matsuo, W.S. Tang, H. Wu, N. Verdal, A.V. Soloninin, R.V. Skoryunov, O.A. Babanova, A.V. Skripov, J.J. Rush, A. Unemoto, H. Takamura, S. Orimo
    • Journal Title

      Advanced Materials

      Volume: 26 Issue: 45 Pages: 7622-7626

    • DOI

      10.1002/adma.201403157

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Nuclear magnetic resonance study of atomic motion in the mixed borohydride - amide Na2(BH4)(NH2)2014

    • Author(s)
      A.V. Soloninin, O.A. Babanova, E.Y. Medvedev, A.V. Skripov, M. Matsuo, S. Orimo
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 118 Issue: 27 Pages: 14805-14812

    • DOI

      10.1021/jp503451d

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Development of bulk-type all-solid-state lithium-sulfur battery using LiBH4 electrolyte2014

    • Author(s)
      A. Unemoto, S. Yasaku, G. Nogami, M. Tazawa, M. Taniguchi, M. Matsuo, T. Ikeshoji, S. Orimo
    • Journal Title

      Applied Physics Letters

      Volume: 105 Issue: 8 Pages: 083901-083901

    • DOI

      10.1063/1.4893666

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Presentation] Development of complex hydrides for fast ionic conduction2016

    • Author(s)
      Motoaki Matsuo, Atsushi Unemoto, Terrence. J. Udovic, Alexander V. Skripov, Tamio Ikeshoji, Biswajit Paik, Shin-ichi Orimo
    • Organizer
      10th International Symposium Hydrogen & Energy
    • Place of Presentation
      ラフォーレ蔵王リゾート&スパ(宮城県刈田郡)
    • Year and Date
      2016-02-21
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Complex hydride electrodes for high-energy density all-solid-state lithium-sulfur battery2016

    • Author(s)
      Atsushi Unemoto, Motoaki Matsuo, Tamio Ikeshoji, S.Orimo
    • Organizer
      10th International Symposium Hydrogen & Energy
    • Place of Presentation
      ラフォーレ蔵王リゾート&スパ(宮城県刈田郡)
    • Year and Date
      2016-02-21
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] How cations move in boron-hydride electrolytes: First-principals molecular dynamics2016

    • Author(s)
      Tamio Ikeshoji, Atsushi Unemoto, S. Takagi, Motoaki Matsuo, Shin-ichi Orimo
    • Organizer
      10th International Symposium Hydrogen & Energy
    • Place of Presentation
      ラフォーレ蔵王リゾート&スパ(宮城県刈田郡)
    • Year and Date
      2016-02-21
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] closo型錯イオン[BnHn]2-を有する錯体水素化物での高速イオン伝導2015

    • Author(s)
      松尾元彰, 神保貴行, 宇根本篤, 高村仁, Terrence. J. Udovic, Biswajit Paik, 折茂慎一
    • Organizer
      日本金属学会2015年秋期大会
    • Place of Presentation
      九州大学(福岡県福岡市)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] 錯体水素化物固体電解質LiBH4からの水素脱離による全固体TiS2/Li電池の安定動作化2015

    • Author(s)
      宇根本篤, 池庄司民夫, 矢作駿, 松尾元彰, Vitalie Stavila, Terrence. J. Udovic, 折茂慎一
    • Organizer
      日本金属学会2015年秋期大会
    • Place of Presentation
      九州大学(福岡県福岡市)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] Effect of lithium ion conduction on hydrogen desorption of LiNH2-LiH solid composite2015

    • Author(s)
      張騰飛, 磯部繁人, 松尾元彰, 折茂慎一, 王永明, 橋本直幸, 大貫惣明
    • Organizer
      日本金属学会2015年秋期大会
    • Place of Presentation
      九州大学(福岡県福岡市)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] Hydro-closo-borates Na2BnHn (n=10, 12)でのナトリウム高速イオン伝導2015

    • Author(s)
      松尾 元彰, Terrence J. Udovic, 神保 貴行, 宇根本 篤, 高村 仁, 折茂 慎一
    • Organizer
      日本金属学会2015年春期大会
    • Place of Presentation
      東京大学(東京都目黒区)
    • Year and Date
      2015-03-18 – 2015-03-20
    • Related Report
      2014 Research-status Report
  • [Presentation] LiBH4-LiCl系固体電解質を用いた高容量型バルク全固体Li/S電池の開発2015

    • Author(s)
      吉田 浩二, 宇根本 篤, 矢作 駿, 松尾 元彰, 池庄司 民夫, 折茂 慎一
    • Organizer
      日本金属学会2015年春期大会
    • Place of Presentation
      東京大学(東京都目黒区)
    • Year and Date
      2015-03-18 – 2015-03-20
    • Related Report
      2014 Research-status Report
  • [Presentation] LiBH4-LiI系固体電解質を用いた高電位型バルク全固体Li/LiCoO2電池の開発2015

    • Author(s)
      宇根本 篤, 野上 玄器, 田沢 勝, 谷口 貢, 松尾 元彰, 池庄司 民夫, 折茂 慎一
    • Organizer
      日本金属学会2015年春期大会
    • Place of Presentation
      東京大学(東京都目黒区)
    • Year and Date
      2015-03-18 – 2015-03-20
    • Related Report
      2014 Research-status Report
  • [Presentation] エネルギー機能性材料としての錯体水素化物の開発2015

    • Author(s)
      松尾 元彰
    • Organizer
      JAEA放射光科学シンポジウム2015
    • Place of Presentation
      大型放射光施設SPring-8(兵庫県佐用郡)
    • Year and Date
      2015-03-16 – 2015-03-17
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Complex hydrides for all-solid-state energy devices2014

    • Author(s)
      Atsushi Unemoto , Motoaki Matsuo, Tamio Ikeshoji, Shin-ichi Orimo
    • Organizer
      Second Ineternational Conference of Young Researchers on Advanced Materials (IUMRS-ICYRAM 2014)
    • Place of Presentation
      Haikou (China)
    • Year and Date
      2014-10-24 – 2014-10-29
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Complex hydrides for all-solid-state rechargeable battery electrolytes2014

    • Author(s)
      Atsushi Unemoto , Motoaki Matsuo, Tamio Ikeshoji, Shin-ichi Orimo
    • Organizer
      Eleventh International Conference on Flow Dynamics (ICFD2014)
    • Place of Presentation
      仙台国際会議場(宮城県仙台市)
    • Year and Date
      2014-10-08 – 2014-10-10
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] ナトリウム高速イオン伝導体としてのホウ素系錯体水素化物の開発2014

    • Author(s)
      神保 貴行, 松尾 元彰, Terrence J. Udovic, 宇根本 篤, 高村 仁, 折茂 慎一
    • Organizer
      日本金属学会2014年秋期大会
    • Place of Presentation
      名古屋大学(愛知県名古屋市)
    • Year and Date
      2014-09-24 – 2014-09-26
    • Related Report
      2014 Research-status Report
  • [Presentation] 錯体水素化物固体電解質を用いた高エネルギー密度型バルク全固体リチウムー硫黄電池の開発2014

    • Author(s)
      宇根本 篤, 矢作 駿, 野上 玄器, 田沢 勝, 谷口 貢, 松尾 元彰, 池庄司 民夫, 折茂 慎一
    • Organizer
      日本金属学会2014年秋期大会
    • Place of Presentation
      名古屋大学(愛知県名古屋市)
    • Year and Date
      2014-09-24 – 2014-09-26
    • Related Report
      2014 Research-status Report
  • [Presentation] Fast ionic conduction in complex hydrides2014

    • Author(s)
      Motoaki Matsuo, Atsushi Unemoto, Tamio Ikeshoji, Hitoshi Takamura, Terrence J. Udovic, Alexander Skripov, Shin-ichi Orimo
    • Organizer
      The International Meeting on Advanced Material Science for Hydrogen
    • Place of Presentation
      琉球大学(沖縄県中頭郡)
    • Year and Date
      2014-08-25 – 2014-08-27
    • Related Report
      2014 Research-status Report
  • [Presentation] Fast ionic conduction in complex hydrides2014

    • Author(s)
      Motoaki Matsuo, Hiroyuki Oguchi, Atsushi Unemoto, Tamio Ikeshoji, Hitoshi Takamura, Tejs Vegge, Arndt Remhof, Andreas Borgshulte, Andreas Zuttel, Terrence J. Udovic, Alexander Skripov, Shin-ichi Orimo
    • Organizer
      International Symposium on Metal-Hydrogen Systems 2014 (MH2014)
    • Place of Presentation
      Manchester (UK)
    • Year and Date
      2014-07-21 – 2014-07-25
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Effect of lithium ion conduction on hydrogen desorption of LiNH2-LiH solid composite2014

    • Author(s)
      Tengfei Zhang, Shigehito Isobe, Yongming Wang, Naoyuki Hashimoto, Somei Ohnuki, Motoaki Matsuo, Shin-ichi Orimo
    • Organizer
      International Symposium on Metal-Hydrogen Systems 2014 (MH2014)
    • Place of Presentation
      Manchester (UK)
    • Year and Date
      2014-07-21 – 2014-07-25
    • Related Report
      2014 Research-status Report
  • [Presentation] Altering the structural properties of A2B12H12 compounds via cation and anion modifications2014

    • Author(s)
      Wan S. Tang, Terrence J. Udovic, Nina Verdal, John J. Rush, Alexander V. Skripov, Vitalie Stavila, Motoaki Matsuo, Shin-ichi Orimo
    • Organizer
      International Symposium on Metal-Hydrogen Systems 2014 (MH2014)
    • Place of Presentation
      Manchester (UK)
    • Year and Date
      2014-07-21 – 2014-07-25
    • Related Report
      2014 Research-status Report
  • [Presentation] Fast ionic conduction in complex hydrides2014

    • Author(s)
      Motoaki Matsuo
    • Organizer
      EMN East Meeting 2014
    • Place of Presentation
      Bejin (China)
    • Year and Date
      2014-05-12 – 2014-05-15
    • Related Report
      2014 Research-status Report
    • Invited
  • [Remarks] ナトリウムイオン電池 固体電解質の新素材

    • URL

      http://www.hydrogen.imr.tohoku.ac.jp/publication/pdf/20141016.pdf

    • Related Report
      2014 Research-status Report
  • [Remarks] 超イオン伝導現象を発見 安定な錯体水素化物で

    • URL

      http://www.hydrogen.imr.tohoku.ac.jp/publication/pdf/20141031.pdf

    • Related Report
      2014 Research-status Report
  • [Patent(Industrial Property Rights)] 全固体電池用電極層および全固体電池2014

    • Inventor(s)
      野上、廣川、島田、田沢、宇根本、松尾、折茂
    • Industrial Property Rights Holder
      野上、廣川、島田、田沢、宇根本、松尾、折茂
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2014-140903
    • Filing Date
      2014-07-08
    • Related Report
      2014 Research-status Report
  • [Patent(Industrial Property Rights)] イオン伝導体およびその製造方法2014

    • Inventor(s)
      野上 玄器, 谷口 貢, 宇根本 篤, 松尾 元彰, 折茂 慎一
    • Industrial Property Rights Holder
      野上 玄器, 谷口 貢, 宇根本 篤, 松尾 元彰, 折茂 慎一
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2014-258212
    • Filing Date
      2014-12-22
    • Related Report
      2014 Research-status Report

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Published: 2014-04-04   Modified: 2022-01-31  

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