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Development of intermediate temperature fuel cells with inorganic electrolytes hybridized with inorganic glass matrixes

Research Project

Project/Area Number 26820321
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Structural/Functional materials
Research InstitutionTokyo National College of Technology

Principal Investigator

SHIROISHI Hidenobu  東京工業高等専門学校, 物質工学科, 准教授 (30413751)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2016: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2015: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2014: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Keywords燃料電池 / 中温作動型 / プロトン導電 / 電解質 / 固体電解質 / 電池材料 / 無機固体電解質
Outline of Final Research Achievements

Intermediate temperature fuel cells (ITFCs) operating at 100℃ to 300℃ have various advantages compared with other fuel cells, however there was no good proton conductive solid electrolyte to operate in the intermediate temperature range. Therefore, we developed inorganic electrolytes hybridized with inorganic glass matrixes which is excellent in water resistance and low gas permeability, and aimed to bring ITFCs closer to practical use. As a result, the electrolytes with high water resistance operating in the intermediate temperature range have been developed with ZrO2 - 2P2O5 electrolyte hybridized with ZnO - 2P2O5 glass with a silane treatment. Also, ITFCs were fabricated with the electrolytes, and we have succeeded in generating electricity using various fuels.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (11 results)

All 2017 2016 2015 2014

All Presentation (11 results) (of which Int'l Joint Research: 2 results)

  • [Presentation] 中温作動型燃料電池用固体電解質としてのZrO2-1.6P2O5とその改良(4)2017

    • Author(s)
      小笠原 気八,城石 英伸,齋藤 守弘,田中 優実
    • Organizer
      電気化学会第84回大会
    • Place of Presentation
      東京都八王子市,首都大学東京
    • Year and Date
      2017-03-25
    • Related Report
      2016 Annual Research Report
  • [Presentation] 無機リン酸系ガラスとハイブリッド化したZrO2・1.6P2O5電解質の調製と中温作動プロトン導電型燃料電池の発電性能2016

    • Author(s)
      小笠原気八,城石英伸,齋藤 守弘,田中優実
    • Organizer
      第9回新電極触媒シンポジウム&宿泊セミナー
    • Place of Presentation
      静岡県三島市,東レ総合研修センター
    • Year and Date
      2016-10-21
    • Related Report
      2016 Annual Research Report
  • [Presentation] Proton Conducting ZrO2-1.6P2O5 Electrolyte Hybridized with ZnO-2P2O5 for Intermediate Temperature Fuel Cells2016

    • Author(s)
      Kiya Ogasawara, Hidenobu Shiroishi, Morihiro Saito, Yumi Tanaka
    • Organizer
      Prime 2016
    • Place of Presentation
      Hawaii, USA
    • Year and Date
      2016-10-04
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 中温作動型燃料電池用固体電解質としてのZrO2-1.6P2O5とその改良(3)2016

    • Author(s)
      小笠原 気八,城石 英伸,齋藤 守弘,田中 優実
    • Organizer
      電気化学会第83回大会
    • Place of Presentation
      大阪大学大阪大学吹田キャンパス (大阪府吹田市)
    • Year and Date
      2016-03-29
    • Related Report
      2015 Research-status Report
  • [Presentation] 中温作動プロトン導電型燃料電池用ZrO2-1.6P2O5電解質の改良2015

    • Author(s)
      大屋彼野人,城石 英伸,齋藤 守弘,田中 優実
    • Organizer
      第8回新電極触媒シンポジウム&宿泊セミナー
    • Place of Presentation
      大阪大学大阪大学吹田キャンパス (大阪府吹田市)
    • Year and Date
      2015-10-23
    • Related Report
      2015 Research-status Report
  • [Presentation] Characteristics of an intermediate-temperature fuel cell using proton conductive ZrO2-1.6P2O5-doped ZnO- 2P2O5 hybrid electrolyte2015

    • Author(s)
      Kayato Ooya, Hidenobu Shiroishi, Morihiro Saito, Yumi Tanaka
    • Organizer
      The 66th Annual Meeting of the International Society of Electrochemistry
    • Place of Presentation
      Taipei International Convention Center(Taipei, Taiwan)
    • Year and Date
      2015-10-04
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] 中温作動型燃料電池用固体電解質としてのZrO2-1.6P2O5とその改良2015

    • Author(s)
      小笠原 気八,城石 英伸,齋藤 守弘,田中 優実,大屋 彼野人
    • Organizer
      2015年度電気化学会秋季大会
    • Place of Presentation
      埼玉工業大学(埼玉県深谷市)
    • Year and Date
      2015-09-11
    • Related Report
      2015 Research-status Report
  • [Presentation] 低温焼結型(ZrO2-1.6P2O5)-(ZnO-2P2O5)ハイブリッド電解質のプロトン導電率2015

    • Author(s)
      大屋 彼野人,城石 英伸,齋藤 守弘
    • Organizer
      電気化学会第82回大会
    • Place of Presentation
      横浜国立大学(神奈川県横浜市)
    • Year and Date
      2015-03-15
    • Related Report
      2014 Research-status Report
  • [Presentation] プロトン導電ガラスと複合化したZrO2-1.6P2O5電解質の改良2015

    • Author(s)
      小笠原 気八,大屋 彼野人,城石 英伸,齋藤 守弘
    • Organizer
      電気化学会第82回大会
    • Place of Presentation
      横浜国立大学(神奈川県横浜市)
    • Year and Date
      2015-03-15
    • Related Report
      2014 Research-status Report
  • [Presentation] 中温域プロトン導電型燃料電池用ZrO2-1.6P2O5コンポジットZnO-2P2O5ガラス電解質の特性2014

    • Author(s)
      大屋彼野人,安藤慶介,城石英伸,齋藤守弘
    • Organizer
      日本太陽エネルギー学会・日本風力エネルギー協会合同研究発表会
    • Place of Presentation
      いわき市文化センター(福島県いわき市)
    • Year and Date
      2014-11-13
    • Related Report
      2014 Research-status Report
  • [Presentation] ZrO2-1.6P2O5ハイブリッドZnO-2P2O5ガラス電解質のプロトン導電度の湿度依存性2014

    • Author(s)
      大屋彼野人,城石英伸,齋藤守弘
    • Organizer
      2014年電気化学会秋季大会
    • Place of Presentation
      北海道大学(北海道札幌市)
    • Year and Date
      2014-09-27
    • Related Report
      2014 Research-status Report

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Published: 2014-04-04   Modified: 2018-03-22  

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