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Development of Core-Shell Structured Zeolite Adsorbents for CO2 separation from wet gas stream

Research Project

Project/Area Number 26820337
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Properties in chemical engineering process/Transfer operation/Unit operation
Research InstitutionGifu University

Principal Investigator

MIYAMOTO Manabu  岐阜大学, 工学部, 助教 (60538180)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2016: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2015: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2014: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Keywordsゼオライト / CO2 / 水蒸気 / Core-Shell / CO2吸着 / 水蒸気吸着 / Core-shell構造化 / 破過曲線 / 吸着
Outline of Final Research Achievements

Aluminosilicates are often used as adsorbents for pressure-swing CO2 separation process. However, the dehumidification is necessary because water adsorbs selectively on aluminosilicates rather than CO2.
Aiming to develop the novel zeolite adsorbents for CO2 separation in wet condition, core-shell structured zeolite which is an aluminosilicate coated with pure silica zeolite was synthesized and its CO2 adsorption property in wet condition was evaluated. The conventional aluminosilicate exhibited significant decrease in CO2 adsorption in the presence of water vapor. In contrast, the decrease in CO2 adsorption was remarkably limited on the core-shell structured zeolite. This clearly indicates the pure silica zeolite coating layer which is highly hydrophobic could inhibit adsorption of water which adsorbs on aluminosilicate strongly rather than CO2. The core-shell structured zeolites is expected to achieve a much high energy efficient CO2 separation process.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (3 results)

All 2017 2015

All Presentation (3 results) (of which Int'l Joint Research: 1 results)

  • [Presentation] Core-shell structured zeolite for CO2 adsorption in wet condition2017

    • Author(s)
      M. Miyamoto, S. Ono, K. Kusukami, Y. Oumi, S. Uemiya
    • Organizer
      7th International FEZA Conference
    • Place of Presentation
      Sofia, Blugaria
    • Year and Date
      2017-07-03
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Core-shell構造化MFI型ゼオライトの水蒸気共存下におけるCO2吸着特性2017

    • Author(s)
      小野俊平、宮本学、近江靖則、上宮成之
    • Organizer
      化学工学会第82年会
    • Place of Presentation
      芝浦工業大学
    • Year and Date
      2017-03-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] 水蒸気共存下におけるMFI型ゼオライトのCO2吸着に対するCore-Shell化の効果2015

    • Author(s)
      楠神幸大、宮本学、近江靖則、上宮成之
    • Organizer
      化学工学会 第47回秋季大会
    • Place of Presentation
      北海道大学(札幌)
    • Year and Date
      2015-09-09
    • Related Report
      2015 Research-status Report

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Published: 2014-04-04   Modified: 2018-03-22  

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