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Development of efficient catalytic systems using supported intermetallic catalysts

Research Project

Project/Area Number 26820350
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Catalyst/Resource chemical process
Research InstitutionHokkaido University (2016)
Tokyo Institute of Technology (2014-2015)

Principal Investigator

Furukawa Shinya  北海道大学, 触媒科学研究所, 准教授 (10634983)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2015: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2014: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords金属間化合物 / 規則性合金 / 高性能触媒 / 選択水素化 / 合金触媒 / アミン酸化 / PROX
Outline of Final Research Achievements

Intermetallic compounds, which have rarely been used as catalyst materials, were used as supported nanoparticles for various molecular transformations. For initially planned reaction systems (PROX, amine oxidation, and hydrogen production from urea), highly active and selective catalysts were developed. We expanded these works to other reactions such as selective hydrogenation of nitroarenes and functionalized alkynes and N-alkylation of amines, resulted in the development of highly efficient catalytic systems much superior to the existing heterogeneous systems.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (13 results)

All 2017 2016 2015 2014

All Journal Article (5 results) (of which Peer Reviewed: 5 results,  Acknowledgement Compliant: 2 results,  Open Access: 1 results) Presentation (8 results) (of which Invited: 4 results)

  • [Journal Article] Selective Activation of Alcohols in the Presence of Reactive Amines over Intermetallic PdZn: Efficient Catalysis for Alcohol-Based N-Alkylation of Various Amines2016

    • Author(s)
      S. Furukawa, R. Suzuki and T. Komatsu
    • Journal Title

      ACS Catal.

      Volume: 6 Issue: 9 Pages: 5946-5953

    • DOI

      10.1021/acscatal.6b01677

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Well-structured Bimetallic Surface Capable of Molecular Recognition for Chemoselective Nitroarene Hydrogenation2016

    • Author(s)
      S. Furukawa, K. Takahashi, T. Komatsu
    • Journal Title

      Chemical Science

      Volume: 印刷中 Issue: 7 Pages: 4476-4484

    • DOI

      10.1039/c6sc00817h

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Unique Reaction Mechanism of Preferential Oxidation of CO over Intermetallic Pt3Co Catalysts: Surface-OH-Mediated Formation of Bicarbonate Intermediate2015

    • Author(s)
      S. Furukawa, K. Ehara, T. Komatsu
    • Journal Title

      Catalysis Science & Technology

      Volume: 6 Issue: 6 Pages: 1642-1650

    • DOI

      10.1039/c5cy01652e

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Mechanistic Study on Aerobic Oxidation of Amine over Intermetallic Pd3Pb: Concerted Promotion Effects by Pb and Support Basicity2015

    • Author(s)
      S. Furukawa, A. Suga and T. Komatsu
    • Journal Title

      ACS Catal.

      Volume: 5 Issue: 2 Pages: 1214-1222

    • DOI

      10.1021/cs501695m

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Highly efficient aerobic oxidation of various amines using Pd3Pb intermetallic compounds as catalysts2014

    • Author(s)
      Shinya Furukawa, Akifusa Suga, Takayuki Komatsu
    • Journal Title

      Chemical Communications

      Volume: 50 Issue: 25 Pages: 3277-3280

    • DOI

      10.1039/c4cc00024b

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Presentation] アルコールによるアミンのN-アルキル化に 有効なPdZnの触媒作用におけるZnの役割2017

    • Author(s)
      古川森也、鈴木遼平、小松隆之
    • Organizer
      第119回触媒討論会
    • Place of Presentation
      首都大学東京 (東京都、八王子市)
    • Related Report
      2016 Annual Research Report
  • [Presentation] 規則性合金を用いた触媒開発とその設計2016

    • Author(s)
      古川森也
    • Organizer
      JXエネルギー(株)中央研究所 若手研究者のための講演会
    • Place of Presentation
      JXエネルギー(株)中央研究所 (神奈川県、横浜市)
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] PdZn触媒上でのアルコールによるアミンのN-アルキル化におけるZnの役割2016

    • Author(s)
      古川森也、鈴木遼平、小松隆之
    • Organizer
      第46回石油・石油化学討論会
    • Place of Presentation
      京都リサーチパーク (京都府、京都市)
    • Related Report
      2016 Annual Research Report
  • [Presentation] 規則性合金を用いた表面反応場の精密設計と高効率触媒系の開拓2015

    • Author(s)
      古川森也
    • Organizer
      東北大学多元物質科学研究所 第8回新機能無機物質探索研究センターシンポジウム
    • Place of Presentation
      東北大学
    • Year and Date
      2015-12-11
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] 規則性合金を用いた表面反応場の精密設計と高効率触媒系の開拓2015

    • Author(s)
      古川森也
    • Organizer
      2015年度触媒学会北海道支部札幌講演会
    • Place of Presentation
      北海道大学
    • Year and Date
      2015-11-20
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] Pt3Co/MgO触媒上でのPROX反応におけるbicarbonate中間体の形成と表面水酸基の関与2015

    • Author(s)
      古川森也・江原健悟・小松隆之
    • Organizer
      第45回石油・石油化学討論会
    • Place of Presentation
      名古屋
    • Year and Date
      2015-11-06
    • Related Report
      2015 Research-status Report
  • [Presentation] 金属間化合物を触媒とした高効率酸化反応系2015

    • Author(s)
      古川森也
    • Organizer
      高難度選択酸化反応研究会ミニシンポジウム
    • Place of Presentation
      東京工業大学
    • Year and Date
      2015-01-30
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Highly Efficient Aerobic Oxidation of Amines to Imines over a Palladium-Lead Intermetallic Compound Catalyst2014

    • Author(s)
      Shinya Furukawa, Akifusa Suga, Takayuki Komatsu
    • Organizer
      The Seventh Tokyo Conference on Advanced Catalytic Science and Technology (TOCAT7)
    • Place of Presentation
      京都
    • Year and Date
      2014-07-05
    • Related Report
      2014 Research-status Report

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Published: 2014-04-04   Modified: 2018-03-22  

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