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Solar water splitting using metal sulfide-based photocatalyst and photoelectrode systems

Research Project

Project/Area Number 26820354
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Catalyst/Resource chemical process
Research InstitutionTokyo University of Science

Principal Investigator

Iwase Akihide  東京理科大学, 理学部, 助教 (40632451)

Project Period (FY) 2014-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2015: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2014: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Keywords光触媒 / 人工光合成 / 可視光 / 水分解 / 光電極 / 金属硫化物 / 硫化物 / 還元型酸化グラフェン
Outline of Final Research Achievements

Photocatalytic water splitting is an artificial photosynthetic reaction in which solar energy is converted to chemical energy. Many metal sulfides efficiently produce hydrogen from water under visible light irradiation. However, the metal sulfides was considered to be unfavorable for water splitting, because they are not stable under photoirradiation (photocorrosion). In the present study, we developed water splitting systems utilizing metal sulfide photocatalyst and photoelectordes upon combining with suitable photoatalysts for oxygen evolution.

Report

(3 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • Research Products

    (21 results)

All 2016 2015 2014

All Journal Article (4 results) (of which Peer Reviewed: 4 results,  Acknowledgement Compliant: 4 results) Presentation (17 results) (of which Int'l Joint Research: 3 results,  Invited: 1 results)

  • [Journal Article] Ni-doped AgGaS2 Photocatalyst for H2 Evolution utilizing Wide Visible Light2015

    • Author(s)
      K. Yamato, A. Iwase, A. Kudo
    • Journal Title

      ChemSusChem,

      Volume: 8 Issue: 17 Pages: 2902-2906

    • DOI

      10.1002/cssc.201500540

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Z‐Schematic Water Splitting into H2 and O2 Using Metal Sulfide as a Hydrogen-Evolving Photocatalyst and Reduced Graphene Oxide as a Solid-State Electron Mediator2015

    • Author(s)
      K. Iwashina, A. Iwase, Y. Hau Ng, R. Amal, and A. Kudo
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 137 Issue: 2 Pages: 604-607

    • DOI

      10.1021/ja511615s

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Solar hydrogen evolution using CuGaS2 photocathode improved by incorporating reduced graphene oxide2015

    • Author(s)
      Akihide Iwase, Yun Hau Ng, Rose Amal, Akihiko Kudo
    • Journal Title

      Journal of Materials Chemistry A

      Volume: 3 Issue: 16 Pages: 8566-8570

    • DOI

      10.1039/c5ta01237f

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Utilization of Metal Sulfide Material of (CuGa)1xZn2xS2 Solid Solution with Visible Light Response in Photocatalytic and Photoelectrochemical Solar Water Splitting Systems2015

    • Author(s)
      T. Kato, Y.Hakari, S.Ikeda, Q. Jia, A.Iwae, and A.Kudo
    • Journal Title

      J. Phys. Chem. Lett.

      Volume: 6 Issue: 6 Pages: 1042-1047

    • DOI

      10.1021/acs.jpclett.5b00137

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 金属硫化物水素生成光触媒および還元型酸化グラフェン/BiVO4コンポジットを用いたZスキーム型可視光水分解2016

    • Author(s)
      吉野隼矢・岩瀬顕秀・工藤昭彦
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学(京都,京田辺市)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] 光電気化学的に還元した還元型酸化グラフェンを添加した金属硫化物光電極によるソーラー水素製造2016

    • Author(s)
      本間一光,岩瀬顕秀,池田暁,髙山大鑑, 工藤昭彦
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学(京都,京田辺市)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] 種々の金属硫化物水素生成光触媒および還元型酸化グラフェン/酸素生成光触媒コンポジットを用いたZスキーム型水分解2016

    • Author(s)
      吉野隼矢,岩瀬 顕秀,工藤 昭彦
    • Organizer
      第117回触媒討論会
    • Place of Presentation
      大阪府立大学(大阪,堺市)
    • Year and Date
      2016-03-21
    • Related Report
      2015 Annual Research Report
  • [Presentation] Photocatalytic and photoelectrochemical solar water splitting using reduced graphene oxide-incorporated metal sulfides2015

    • Author(s)
      Akihide Iwase, Katsuya Iwashina, Ikko Honma, Akihiko Kudo
    • Organizer
      PACIFICHEM 2015
    • Place of Presentation
      Honolulu (USA)
    • Year and Date
      2015-12-20
    • Related Report
      2015 Annual Research Report
  • [Presentation] Utilization of metal sulfides for photocatalytic and photoelectrochemical water splitting systems with reduced graphene oxide2015

    • Author(s)
      Akihide Iwase, Katsuya Iwashina, Ikko Honma, S. Yoshino1) and *A. Kudo
    • Organizer
      第25回日本MRS年次大会
    • Place of Presentation
      横浜市開港記念会館(神奈川,横浜市)
    • Year and Date
      2015-12-10
    • Related Report
      2015 Annual Research Report
  • [Presentation] Utilization of metal sulfide photocatalysts in reduced graphene oxide incorporated solar water splitting systems2015

    • Author(s)
      Akihide Iwase, Katsuya Iwashina, Akihiko Kudo
    • Organizer
      EMN Meeting on Photocatalysis 2015
    • Place of Presentation
      Las Vegas (USA)
    • Year and Date
      2015-11-23
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] ハロゲンで処理したCuおよびAgを含む硫化物光触媒の光電気化学特性2015

    • Author(s)
      岩瀬顕秀,工藤 昭彦
    • Organizer
      第116回触媒討論会
    • Place of Presentation
      三重大学(三重,津市)
    • Year and Date
      2015-09-17
    • Related Report
      2015 Annual Research Report
  • [Presentation] 還元型酸化グラフェンを用いた硫化物光触媒および光電極によるソーラー水分解2015

    • Author(s)
      岩瀬顕秀,本間一光,岩品克哉,工藤昭彦
    • Organizer
      2015年光化学討論会
    • Place of Presentation
      大阪市立大学(大阪,大阪市)
    • Year and Date
      2015-09-11
    • Related Report
      2015 Annual Research Report
  • [Presentation] 還元型酸化グラフェンを添加したCu2ZnGeS4光電極を 用いたソーラー水素生成2015

    • Author(s)
      本間一光,岩瀬顕秀,池田暁,工藤 昭彦
    • Organizer
      2015年光化学討論会
    • Place of Presentation
      大阪市立大学(大阪,大阪市)
    • Year and Date
      2015-09-11
    • Related Report
      2015 Annual Research Report
  • [Presentation] Akihide Iwase, Akihiko Kudo2015

    • Author(s)
      Photoelectrochemical Water Splitting using Improved p-Type semiconductor Photoelectrode by Incorporating Reduced Graphene Oxide
    • Organizer
      First International Symposium on Recent Progress of Energy and Environmental Photocatalysis
    • Place of Presentation
      Tokyo University of Science (Chiba, Noda-shi)
    • Year and Date
      2015-09-03
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Z-Scheme Photocatalyst for Water Splitting Using Metal Sulfides, TiO2, and Reduced Graphene Oxide of a Solid-State Electron Mediator2015

    • Author(s)
      Shunya Yoshino, Akihide Iwase, Akihiko Kudo
    • Organizer
      First International Symposium on Recent Progress of Energy and Environmental Photocatalysis2015
    • Place of Presentation
      Tokyo University of Science (Chiba, Noda-shi)
    • Year and Date
      2015-09-03
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 還元型酸化グラフェンを用いた金属硫化物光触媒系による水分解2015

    • Author(s)
      岩瀬顕秀,本間一光,岩品克哉,工藤昭彦
    • Organizer
      第34回光がかかわる触媒化学シンポジウム
    • Place of Presentation
      東京工業大学(東京,目黒区)
    • Year and Date
      2015-06-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] 還元型酸化グラフェンを添加した種々の金属硫化物光カソードを用いたソーラー水素製造2015

    • Author(s)
      本間 一光,岩瀬 顕秀,山本 智貴,池田 暁,加賀 洋史,工藤 昭彦
    • Organizer
      日本化学会第95春期年会
    • Place of Presentation
      千葉
    • Year and Date
      2015-03-26
    • Related Report
      2014 Research-status Report
  • [Presentation] 金属硫化物光触媒および光電極を用いた水分解および二酸 化炭素還元2015

    • Author(s)
      岩瀬 顕秀,池田 暁,山本 智貴,加藤 孝明,岩品 克哉,高山 大鑑,工藤 昭彦
    • Organizer
      第115回触媒討論会
    • Place of Presentation
      東京
    • Year and Date
      2015-03-24
    • Related Report
      2014 Research-status Report
  • [Presentation] Improved Photoelectrochemical Performance of p-Type semiconductor Photoelectrode by Incorporating Reduced Graphene Oxide2014

    • Author(s)
      Akihide Iwase, Akihiko Kudo
    • Organizer
      2014 International Conference on Artificial Photosynthesis
    • Place of Presentation
      兵庫
    • Year and Date
      2014-11-26
    • Related Report
      2014 Research-status Report
  • [Presentation] 金属硫化物水素生成光触媒および還元型酸化グラフェン 電子伝達体を用いたZスキーム型水分解反応2014

    • Author(s)
      岩品 克哉,岩瀬 顕秀,工藤 昭彦
    • Organizer
      第114回触媒討論会
    • Place of Presentation
      広島
    • Year and Date
      2014-09-27
    • Related Report
      2014 Research-status Report
  • [Presentation] 層状物質の添加により高性能化された硫化物光カソードを用いたソーラー水素製造2014

    • Author(s)
      岩瀬 顕秀,本間 一光,池田 暁,岩品 克哉,工藤 昭彦
    • Organizer
      第114回触媒討論会
    • Place of Presentation
      広島
    • Year and Date
      2014-09-25
    • Related Report
      2014 Research-status Report

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Published: 2014-04-04   Modified: 2017-05-10  

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