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separation and recovery of radioactive Caesium by Metal-Organic Frameworks

Research Project

Project/Area Number 26820409
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Nuclear engineering
Research InstitutionJapan Atomic Energy Agency

Principal Investigator

Nankawa Takuya  国立研究開発法人日本原子力研究開発機構, 原子力科学研究部門 原子力科学研究所 バックエンド技術部, 研究職 (30370448)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2016: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2015: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2014: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywordsセシウム / 吸着材 / 廃棄物処理 / MOF / 配位高分子 / 元素分離 / イオン選択性
Outline of Final Research Achievements

We tested Caesium, Strontium(Sr) and some other alkaline or alkaline earth ion uptake by Metal-Organic-Frameworks(MOF) with the formula of (NH4)[Ln(C2O4) 2 (H2O)] (Ln = Y, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb) to apply it for removing and recovering radioactive elements. According to the results, the selectivity of metal changed with the change of host lanthanide ions in MOFs and (NH4)[Ln(C2O4) 2 (H2O)] has high selectivity to Sr even in sea water. And we also succeeded recovery of these guest ions from the MOF. From these results, we made a new promising adsorbent for removing and recovering radioactive waste from radioactive waste solution.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (3 results)

All 2016 Other

All Int'l Joint Research (1 results) Presentation (1 results) (of which Int'l Joint Research: 1 results) Patent(Industrial Property Rights) (1 results)

  • [Int'l Joint Research] リバプール大学(英国)

    • Related Report
      2015 Research-status Report
  • [Presentation] Separation and recovery of radioactive cesium and strontium by metal-organic-frameworks2016

    • Author(s)
      南川 卓也
    • Organizer
      28th Reimei Workshop on Radioactive Waste Treatment and Remediation
    • Place of Presentation
      日本原子力研究開発機構(茨城、東海)
    • Year and Date
      2016-02-26
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Patent(Industrial Property Rights)] 新規化合物及びその合成方法並びに元素回収剤2016

    • Inventor(s)
      南川卓也D.S, A.K, M.J.R.
    • Industrial Property Rights Holder
      日本原子力研究開発機構
    • Industrial Property Rights Type
      特許
    • Filing Date
      2016-08-19
    • Related Report
      2016 Annual Research Report

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Published: 2014-04-04   Modified: 2022-02-03  

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