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Synthesis of titania polymorph crystals with controlled structures employing water-soluble titanium complexes and molecular control agents

Research Project

Project/Area Number 26870048
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Inorganic industrial materials
Inorganic materials/Physical properties
Research InstitutionTohoku University

Principal Investigator

Kobayashi Makoto  東北大学, 多元物質科学研究所, 助教 (50613395)

Project Period (FY) 2014-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2015: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2014: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords酸化チタン / 水熱法 / 結晶成長 / 水 / 分子制御 / テーラーメイド合成 / 水熱処理
Outline of Final Research Achievements

In this project, I have attempted hydrothermal synthesis of titania polymorphs with controlled morphologies and development of methodology for the morphological control. On the morphological control using molecular control agents, the effect of functional groups in compounds used as the molecular control agent on the anisotropic growth of rutile-type titania along c-axis was clarified. On the other hand, it was succeeded on synthesis of rutile crystals exposing facets with high energy such as high-index ones under mild conditions. In addition, synthesis of high-index faceted or nanosized brookite-type titania, which was difficult to obtained as the single phase, was attained. These achievements produced novel knowledge for morphological control of crystals.

Report

(3 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • Research Products

    (25 results)

All 2016 2015 2014 Other

All Journal Article (4 results) (of which Peer Reviewed: 4 results,  Acknowledgement Compliant: 3 results,  Open Access: 1 results) Presentation (18 results) (of which Int'l Joint Research: 3 results,  Invited: 8 results) Remarks (3 results)

  • [Journal Article] Self-assembly of Polyethyleneamine-intercalated H2Ti2O5 Nanoparticles into Spherical Agglomerates2016

    • Author(s)
      Makoto Kobayashi, Hideki Kato, Masato Kakihana
    • Journal Title

      Journal of Materials Research

      Volume: 31 Issue: 5 Pages: 564-572

    • DOI

      10.1557/jmr.2016.67

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of titania with controlled structures and its development2016

    • Author(s)
      Makoto Kobayashi
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 掲載確定

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] 酸化チタン多形の水熱結晶成長(Crystal Growth of Titania Polymorphs by Hydrothermal Method)2015

    • Author(s)
      小林亮, 加藤英樹, 垣花眞人
    • Journal Title

      結晶成長学会誌

      Volume: 42 Pages: 283-289

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Design of crystal structures, morphologies, and functionalities of titanium oxide using water-soluble complexes and molecular control agents2015

    • Author(s)
      Makoto Kobayashi, Minoru Osada, Hideki Kato, Masato Kakihana
    • Journal Title

      Polymer Journal

      Volume: 47 Issue: 2 Pages: 78-83

    • DOI

      10.1038/pj.2014.89

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 酸化チタン多形ナノクリスタルの水熱合成2016

    • Author(s)
      小林亮, 加藤英樹, 垣花眞人
    • Organizer
      日本セラミックス協会第29回秋季シンポジウム
    • Place of Presentation
      広島大学(広島県・東広島市)
    • Year and Date
      2016-09-07
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 水溶媒からのチタン系ナノ・ハイブリッドマテリアルの創出2016

    • Author(s)
      小林亮, 加藤英樹, 垣花眞人
    • Organizer
      ナノマテリアル科学の最前線(日本セラミックス協会2016年年会 サテライトプログラム)
    • Place of Presentation
      早稲田大学(東京都・新宿区)
    • Year and Date
      2016-03-14
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 多形・形態を制御した酸化チタンの合成とその展開2016

    • Author(s)
      小林亮
    • Organizer
      日本セラミックス協会2016年年会
    • Place of Presentation
      早稲田大学(東京都・新宿区)
    • Year and Date
      2016-03-14
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Synthesis of ceramics with controlled nano- and micro-structures by aqueous solution methods2016

    • Author(s)
      Makoto Kobayashi, Minsung Kim, Hideki Kato, Masato Kakihana
    • Organizer
      EMN Meeting on Ceramics 2016
    • Place of Presentation
      Kowloon (Hong Kong)
    • Year and Date
      2016-01-25
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Development of pyrazine-2-carboxylate titanium complexes using a water-soluble titanium complex2015

    • Author(s)
      Makoto Kobayashi, Tatsuya Okuhara, Hideki Kato, Sota Sato, Masato Kakihana
    • Organizer
      The 2015 International Chemical Congress of Pacific Basin Societies (Pacifichem 2015)
    • Place of Presentation
      Honolulu (USA)
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 水を溶媒に用いたチタン含有材料の合成と開発2015

    • Author(s)
      小林亮, 加藤英樹, 垣花眞人
    • Organizer
      第8回 新機能無機物質探索研究センター シンポジウム
    • Place of Presentation
      東北大学(宮城県・仙台市)
    • Year and Date
      2015-12-11
    • Related Report
      2015 Annual Research Report
  • [Presentation] Synthesis and Shape Control of Rutile-type Titanium Oxide by Hydrothermal Treatment of a Water-soluble Titanium Complex2015

    • Author(s)
      Sungho Lee, Makoto Kobayashi, Hideki Kato, Masato Kakihana
    • Organizer
      The 32nd Japan-Korea International Seminar on Ceramics
    • Place of Presentation
      ホテルニューオータニ長岡(新潟県・長岡市)
    • Year and Date
      2015-11-18
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 水熱法によるrutile型酸化チタンのc軸異方結晶成長とその機構解明2015

    • Author(s)
      小林亮, 灘浩樹, 加藤英樹, 垣花眞人
    • Organizer
      粉体粉末冶金協会平成27年度秋季大会
    • Place of Presentation
      京都大学(京都府・京都市)
    • Year and Date
      2015-11-11
    • Related Report
      2015 Annual Research Report
  • [Presentation] 水熱法による多様な形態を有する酸化チタン多形の合成2015

    • Author(s)
      小林亮, 加藤英樹, 垣花眞人
    • Organizer
      第2回東北大&GREEN合同シンポジウム
    • Place of Presentation
      東北大学(宮城県・仙台市)
    • Year and Date
      2015-10-30
    • Related Report
      2015 Annual Research Report
  • [Presentation] 水溶性チタン錯体を原料とするソルボサーマル法による酸化チタン結晶成長制御2015

    • Author(s)
      李晟豪,小林亮,加藤英樹,垣花眞人
    • Organizer
      日本セラミックス協会 第28回秋季シンポジウム
    • Place of Presentation
      富山大学(富山県・富山市)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] 原料開発によるセラミックスのナノマクロ構造制御2015

    • Author(s)
      小林亮, 加藤英樹, 垣花眞人
    • Organizer
      研究所若手アンサンブルワークショップ
    • Place of Presentation
      東北大学(宮城県・仙台市)
    • Year and Date
      2015-07-23
    • Related Report
      2015 Annual Research Report
  • [Presentation] 異方成長rutile型酸化チタンの水熱合成とその成長機構2015

    • Author(s)
      李晟豪,小林亮,加藤英樹,垣花眞人
    • Organizer
      日本セラミックス協会2015年年会
    • Place of Presentation
      岡山大学(岡山市)
    • Year and Date
      2015-03-18 – 2015-03-20
    • Related Report
      2014 Research-status Report
  • [Presentation] 水溶性化合物の開発による構造が制御されたセラミックスの合成と高機能化2015

    • Author(s)
      小林亮
    • Organizer
      第3回ケミカルフィールド研究討論会
    • Place of Presentation
      岡山大学(岡山市)
    • Year and Date
      2015-03-18
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Rutile型酸化チタンの結晶成長にヒドロキシ酸が与える影響2014

    • Author(s)
      李晟豪,小林亮,加藤英樹,垣花眞人
    • Organizer
      日本セラミックス協会 東北北海道支部 山形地区セミナー
    • Place of Presentation
      山形大学(山形市)
    • Year and Date
      2014-11-22
    • Related Report
      2014 Research-status Report
  • [Presentation] Hydrothermal Synthesis of Titania and Magnetite Crystals with Unique Morphologies2014

    • Author(s)
      Makoto Kobayashi, Hideki Kato, Masato Kakihana
    • Organizer
      The 2014 Collaborative Conference on Crystal Growth
    • Place of Presentation
      Phuket, Thailand
    • Year and Date
      2014-11-04 – 2014-11-07
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] 分子制御剤による酸化チタンおよび酸化鉄粒子の結晶成長制御および高度機能発現2014

    • Author(s)
      小林亮,佐藤淳貴,長田実,加藤英樹,垣花眞人
    • Organizer
      第63回高分子討論会
    • Place of Presentation
      長崎大学(長崎市)
    • Year and Date
      2014-09-24 – 2014-09-26
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] ヒドロキシカルボン酸によるrutile型酸化チタン結晶の異方成長制御2014

    • Author(s)
      李晟豪,小林亮,加藤英樹,垣花眞人
    • Organizer
      平成26年度化学系学協会東北大会
    • Place of Presentation
      山形大学(山形市)
    • Year and Date
      2014-09-20 – 2014-09-21
    • Related Report
      2014 Research-status Report
  • [Presentation] 形態が制御された酸化チタンおよび酸化鉄結晶の水熱合成2014

    • Author(s)
      小林亮,佐藤淳貴,長田実,加藤英樹,垣花眞人
    • Organizer
      日本セラミックス協会 第27回秋季シンポジウム
    • Place of Presentation
      鹿児島大学(鹿児島市)
    • Year and Date
      2014-09-09 – 2014-09-11
    • Related Report
      2014 Research-status Report
    • Invited
  • [Remarks] 東北大学多元物質科学研究所垣花研究室 ホームページ

    • URL

      http://www.tagen.tohoku.ac.jp/labo/kakihana/

    • Related Report
      2015 Annual Research Report 2014 Research-status Report
  • [Remarks] 東北大学多元物質科学研究所新機能無機物質探索研究センター ウェブサイト

    • URL

      http://www.tagen.tohoku.ac.jp/center/CENIM/index.html

    • Related Report
      2015 Annual Research Report
  • [Remarks] 新機能無機物質探索研究センター ウェブサイト

    • URL

      http://www.tagen.tohoku.ac.jp/center/CENIM/index.html

    • Related Report
      2014 Research-status Report

URL: 

Published: 2014-04-04   Modified: 2017-05-10  

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