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Development of active electrode catalysts with interactions between intermetallic compound-metal oxide-carbon

Research Project

Project/Area Number 26870093
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Energy engineering
Reaction engineering/Process system
Research InstitutionGunma University

Principal Investigator

Ishitobi Hirokazu  群馬大学, 大学院理工学府, 助教 (00708406)

Project Period (FY) 2014-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2016: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2015: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2014: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Keywords直接エタノール燃料電池 / 電極触媒 / 金属間化合物 / カーボン担体 / 複合触媒 / 触媒活性 / カーボンナノファイバー / 濃度拡散 / 相互作用
Outline of Final Research Achievements

In this study, developments of composite catalysts with the interaction between intermetallic compound-metal oxide-carbon. The composite catalyst, PtPb (intermetallic compound) supported on titanium oxide embedded carbon nanofiber (TECNF), was prepared. Ethanol electrooxidation activity for PtPb/TECNF, Pt/TECNF, Pt/C (commercial catalyst) was measured. The mass activity at 0.70 V vs. RHE for PtPb/TECNF was almost six times higher than that for Pt/C. The anti-CO property by the interaction for PtPb/TECNF was suggested by CO stripping measurement. The power density of a direct ethanol fuel cell for PtPb/TECNF was higher than that for Pt/C.

Report

(5 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (26 results)

All 2018 2017 2016 2015 2014 Other

All Journal Article (5 results) (of which Peer Reviewed: 5 results,  Acknowledgement Compliant: 4 results) Presentation (20 results) (of which Int'l Joint Research: 2 results,  Invited: 2 results) Remarks (1 results)

  • [Journal Article] Anode catalyst with enhanced ethanol electrooxidation activity by effective interaction between Pt-Sn-SiO 2 for a direct ethanol fuel cell2017

    • Author(s)
      Ishitobi Hirokazu、Ino Yurina、Nakagawa Nobuyoshi
    • Journal Title

      International Journal of Hydrogen Energy

      Volume: 42 Issue: 43 Pages: 26897-26904

    • DOI

      10.1016/j.ijhydene.2017.09.017

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Performances of Cathode Catalyst Layer with Carbon-Alloy Nanofiber in Different Length for Polymer Electrolyte Fuel Cells2016

    • Author(s)
      Hirokazu Ishitobi, Ayaka Ida, Shuhei Anayama, and Nobuyoshi Nakagawa
    • Journal Title

      JOURNAL OF CHEMICAL ENGINEERING OF JAPAN

      Volume: 49 Issue: 12 Pages: 995-1001

    • DOI

      10.1252/jcej.16we068

    • NAID

      130005251313

    • ISSN
      0021-9592, 1881-1299
    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Effect of the Impurities in Bioethanol on Current Density of a Direct Ethanol Fuel Cell2016

    • Author(s)
      Hirokazu Ishitobi, Daiki Naito, Yurina Ino, Masaya Yajima, and Nobuyoshi Nakagawa
    • Journal Title

      Journal of the Japan Institute of Energy

      Volume: 95 Issue: 10 Pages: 909-914

    • DOI

      10.3775/jie.95.909

    • NAID

      130005267677

    • ISSN
      0916-8753, 1882-6121
    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Enhanced Catalytic Activity of Pt for Electrooxidation of Ethanol by using Silica-Carbon Composite as the Catalyst Support2016

    • Author(s)
      Hirokazu Ishitobi, Yurina Ino, and Nobuyoshi Nakagawa
    • Journal Title

      Key Engineering Materials

      Volume: 698 Pages: 47-52

    • DOI

      10.4028/www.scientific.net/kem.698.47

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Enhanced ethanol oxidation activity for a direct fuel cell with silica-carbon composite catalyst support2015

    • Author(s)
      Hirokazu Ishitobi, Yurina Ino, and Nobuyoshi Nakagawa
    • Journal Title

      ECS Transactions

      Volume: 69 Issue: 17 Pages: 825-831

    • DOI

      10.1149/06917.0825ecst

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 直接エタノール燃料電池用のPtRh-セリア-C複合触媒の特性2018

    • Author(s)
      柿沼政貴,石飛宏和,中川紳好
    • Organizer
      第20回化学工学会学生発表会(東京大会)
    • Related Report
      2017 Annual Research Report
  • [Presentation] 金属間化合物-金属酸化物-カーボン複合触媒によるエタノール電極酸化活性の促進2016

    • Author(s)
      石飛宏和,包多多,登丸紘行,中川紳好
    • Organizer
      電気化学会第83回大会
    • Place of Presentation
      大阪大学吹田キャンパス(大阪府吹田市)
    • Year and Date
      2016-03-31
    • Related Report
      2015 Research-status Report
  • [Presentation] 直接エタノール燃料電池のためのSiO2含有CNF触媒担体2016

    • Author(s)
      井野友梨奈,石飛宏和,中川紳好
    • Organizer
      化学工学会第81年会
    • Place of Presentation
      関西大学千里山キャンパス(大阪府吹田市)
    • Year and Date
      2016-03-15
    • Related Report
      2015 Research-status Report
  • [Presentation] A performance advance of the direct ethanol fuel cell by using a silica-carbon composite support2016

    • Author(s)
      Hirokazu Ishitobi, Yurina Ino, and Nobuyoshi Nakagawa
    • Organizer
      International symposium of Innovative Materials for Energy Systems (IMPRES2016)
    • Place of Presentation
      Hotel Villa Diodoro (Taormina, Sicily, Italy)
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] 多孔質ナノファイバーを実装した燃料電池用の電極触媒2016

    • Author(s)
      石飛宏和
    • Organizer
      平成28年度東京工業大学科学技術創成研究院 先導原子力研究所 研究交流・発表会
    • Place of Presentation
      東京工業大学大岡山キャンパス(東京都目黒区)
    • Related Report
      2016 Research-status Report
    • Invited
  • [Presentation] 液供給型電池の電極設計に対する化学工学的アプローチ2016

    • Author(s)
      石飛宏和
    • Organizer
      化学工学会第48回秋季大会
    • Place of Presentation
      徳島大学常三島キャンパス(徳島県徳島市)
    • Related Report
      2016 Research-status Report
  • [Presentation] 金属間化合物PtPbを用いたエタノール酸化活性向上2016

    • Author(s)
      登丸紘行,石飛宏和,中川紳好
    • Organizer
      第23回燃料電池シンポジウム
    • Place of Presentation
      タワーホール船堀(東京都江戸川区)
    • Related Report
      2016 Research-status Report
  • [Presentation] 金属間化合物と複合担体の相互作用による燃料電池におけるエタノール酸化反応の促進2015

    • Author(s)
      石飛宏和,包多多,登丸紘行,中川紳好
    • Organizer
      化学工学会群馬大会2015
    • Place of Presentation
      桐生市市民文化会館(群馬県桐生市)
    • Year and Date
      2015-11-28
    • Related Report
      2015 Research-status Report
  • [Presentation] Enhanced Ethanol Oxidation Activity for a Direct Fuel Cell with Silica-Carbon Composite Catalyst Support2015

    • Author(s)
      Hirokazu Ishitobi, Yurina Ino, and Nobuyoshi Nakagawa
    • Organizer
      The ECS 228th Meeting
    • Place of Presentation
      Phoenix Convention Center (Phoenix, Arizona, United States)
    • Year and Date
      2015-10-14
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] 直接エタノール燃料電池における中間生成物に対する被毒耐性2015

    • Author(s)
      石飛宏和,内藤大樹,井野友梨奈,矢島雅也,中川紳好
    • Organizer
      化学工学会第47回秋季大会
    • Place of Presentation
      北海道大学工学部(北海道札幌市)
    • Year and Date
      2015-09-10
    • Related Report
      2015 Research-status Report
  • [Presentation] 直接エタノール形燃料電池のシリカ含有触媒担体によるCO2選択性2015

    • Author(s)
      井野友梨奈,石飛宏和,中川紳好
    • Organizer
      化学工学会第47回秋季大会
    • Place of Presentation
      北海道大学工学部(北海道札幌市)
    • Year and Date
      2015-09-10
    • Related Report
      2015 Research-status Report
  • [Presentation] 直接燃料電池に用いるバイオエタノールの不純物が出力に与える影響2015

    • Author(s)
      石飛宏和,内藤大樹,中川紳好
    • Organizer
      分離技術会年会2015
    • Place of Presentation
      明治大学生田キャンパス(神奈川県川崎市)
    • Year and Date
      2015-05-30
    • Related Report
      2015 Research-status Report
  • [Presentation] シリカ-カーボン系触媒担体を用いる燃料電池におけるエタノール酸化反応2015

    • Author(s)
      石飛宏和,井野友梨奈,中川紳好
    • Organizer
      化学工学会第80年会
    • Place of Presentation
      芝浦工業大学(東京都江東区)
    • Year and Date
      2015-03-21
    • Related Report
      2014 Research-status Report
  • [Presentation] 直接エタノール燃料電池のシリカ含有触媒担体によるCO2選択性の向上2015

    • Author(s)
      井野友梨奈,石飛宏和,中川紳好
    • Organizer
      化学工学会第17回学生発表会
    • Place of Presentation
      八戸高等専門学校(青森県八戸市)
    • Year and Date
      2015-03-07
    • Related Report
      2014 Research-status Report
  • [Presentation] 回転ディスク電極を用いたCNF触媒層の評2014

    • Author(s)
      吉田拓也,石飛宏和,中川紳好
    • Organizer
      化学工学会新潟大会
    • Place of Presentation
      新潟大学五十嵐キャンパス(新潟県新潟市)
    • Year and Date
      2014-11-22
    • Related Report
      2014 Research-status Report
  • [Presentation] 固体高分子型燃料電池のカソードにおけるナノファイバー触媒層の構築による触媒層活性の向上2014

    • Author(s)
      石飛宏和,井田文佳,中川紳好
    • Organizer
      第55回電池討論会
    • Place of Presentation
      京都国際会館(京都府京都市)
    • Year and Date
      2014-11-19
    • Related Report
      2014 Research-status Report
  • [Presentation] An Enhanced Ethanol Electro-oxidation by Silica-carbon Composite Catalyst Support for Fuel Cells2014

    • Author(s)
      Hirokazu Ishitobi, Yurina Ino, and Nobuyoshi Nakagawa
    • Organizer
      The fourth international symposium on element innovation
    • Place of Presentation
      Gunma University, Kiryu, Gunma (Japan)
    • Year and Date
      2014-10-24
    • Related Report
      2014 Research-status Report
  • [Presentation] Analysis of Material and Charge Transfer in the Fiber Catalyst Layer for Polymer Electrode Fuel Cells2014

    • Author(s)
      Hirokazu Ishitobi, Takuya Yoshida, and Nobuyoshi Nakagawa
    • Organizer
      ECS 226th Meeting
    • Place of Presentation
      Cancun (Mexico)
    • Year and Date
      2014-10-07
    • Related Report
      2014 Research-status Report
  • [Presentation] ファイバー状複合触媒を用いた直接エタノール燃料電池における反応速度の解析2014

    • Author(s)
      石飛宏和,矢島雅也,中川紳好
    • Organizer
      化学工学会第46回秋季大会
    • Place of Presentation
      九州大学伊都キャンパス(福岡県福岡市)
    • Year and Date
      2014-09-19
    • Related Report
      2014 Research-status Report
  • [Presentation] Clarification of harmful impurities for direct methanol fuel cells2014

    • Author(s)
      Hirokazu Ishitobi
    • Organizer
      The 8th Kyung Hee - Gunma Joint International Symposium on Green Energy for 21st Century
    • Place of Presentation
      Kiryu city performing arts center, Kiryu (Japan)
    • Year and Date
      2014-08-26
    • Related Report
      2014 Research-status Report
    • Invited
  • [Remarks] 研究者が所属するグループの業績一覧ページ

    • URL

      http://nakagawa-noda.ees.st.gunma-u.ac.jp/nakalab_archive.html

    • Related Report
      2014 Research-status Report

URL: 

Published: 2014-04-04   Modified: 2019-03-29  

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