Development of novel heterogeneous catalysts by hybridizing hyperbranched polymers and carbons

• Project/Area Number: 26870183
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Multi-year Fund
• Research Field: Green/Environmental chemistry; Organic and hybrid materials
• Research Institution: Tokyo Institute of Technology
• Principal Investigator: Nabae Yuta 東京工業大学, 物質理工学院, 助教 (40514881)
• Project Period (FY): 2014-04-01 – 2017-03-31
• Project Status: Completed (Fiscal Year 2016)
• Budget Amount: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000); Fiscal Year 2016: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000); Fiscal Year 2015: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000); Fiscal Year 2014: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
• Keywords: ハイパーブランチ / 触媒 / 炭素 / 元素戦略 / 高分子 / 固体酸 / ハイパーブランチポリマー / ポリエーテルスルホン / ポリエーテルケトン / 分岐構造 / イオン交換樹脂 / スルホン酸 / 部分酸化 / 芳香族高分子 / 高分子固定化触媒

Outline of Final Research Achievements

Aromatic polymers are good at thermal and chemical stability, and have been widely utilized in various field of the industry; however, the application in catalysis had not been well explored. In this study, novel catalyst materials have been successfully developed by immobilizing hyperbranched poly(ether sulfone) and hyperbranched poly(ether ketone) onto carbon materials.

Research Products

• [Journal Article] Aerobic oxidation of benzyl alcohol over TEMPO-functionalized polyimide as a heterogeneous catalyst (2017)
  • Author(s): Nabae, Y.*; Mikuni, M.; Takusari, N.; Hayakawa, T. & Kakimoto, M.
  • Journal Title: High Performance Polymers Volume: 印刷中 Issue: 6 Pages: 646-650
  • DOI: 10.1177/0954008317696565
  • Acknowledgement Compliant
• [Journal Article] Modification of Graphene with Hyperbranched Poly(Ether Ketone) for Heterogeneous Catalyst (2015)
  • Author(s): Ying Shi, Yuta Nabae, Teruaki Hayakawa, Masa-aki Kakimoto
  • Journal Title: Journal of Photopolymer Science and Technology Volume: 28 Issue: 2 Pages: 187-190
  • DOI: 10.2494/photopolymer.28.187
  • NAID: 130005093844
  • ISSN: 0914-9244, 1349-6336
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Hyperbranched aromatic poly(ether ketone) functionalized with TEMPO as a heterogeneous catalyst for aerobic oxidation of alcohols (2015)
  • Author(s): Ying Shi, Yuta Nabae, Teruaki Hayakawa, Masa-aki Kakimoto
  • Journal Title: RSC Advances Volume: 5 Issue: 3 Pages: 1923-1928
  • DOI: 10.1039/c4ra12126k
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Sulfonic acid functionalized hyperbranched poly(ether sulfone) as a solid acid catalyst (2014)
  • Author(s): Yuta Nabae, Jie Liang, Xuhui Huang, Teruaki Hayakawa, Masa-aki Kakimoto
  • Journal Title: Green Chemistry Volume: 16 Issue: 7 Pages: 3596-3602
  • DOI: 10.1039/c4gc00188e
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Presentation] Synthesis of hyperbranched aromatic poly(ether ketone) and its application in catalysis material (2017)
  • Author(s): Kenta Yamamoto
  • Organizer: 5th International Conference on Multifunctional, Hybrid and Nanomaterials
  • Place of Presentation: Lisbon, Portugal
  • Year and Date: 2017-03-06
  • Int'l Joint Research
• [Presentation] 芳香族ポリマーの触媒材料への展開 (2016)
  • Author(s): 難波江裕太
  • Organizer: 第２４回ポリイミド・芳香族系高分子会議
  • Place of Presentation: 石川県能美市
  • Year and Date: 2016-12-08
  • Invited
• [Presentation] 芳香族ジカルボン酸無水物モノマーのFriedel-Craftsアシル化自己縮合反応によるカルボキシル化ポリエーテルケトンの一段合成 (2016)
  • Author(s): 山本健太
  • Organizer: 第２４回ポリイミド・芳香族系高分子会議
  • Place of Presentation: 石川県能美市
  • Year and Date: 2016-12-08
• [Presentation] Application of Aromatic Polymers to Heterogeneous Catalysis (2016)
  • Author(s): Yuta Nabae
  • Organizer: Polycondensation 2016
  • Place of Presentation: Moscow, Rusia
  • Year and Date: 2016-09-11
  • Int'l Joint Research / Invited
• [Presentation] Modification of Carbon Surfaces with Hyperbranched Polymer for Developing Novel Catalyst Materials (2016)
  • Author(s): Yuta Nabae
  • Organizer: 251th ACS National Meeting
  • Place of Presentation: アメリカ
  • Year and Date: 2016-03-13
  • Int'l Joint Research
• [Presentation] Synthesis of polyimide nano-particles and application in catalysis (2015)
  • Author(s): Yuta Nabae
  • Organizer: ICSS2015
  • Place of Presentation: タイ
  • Year and Date: 2015-11-06
  • Int'l Joint Research / Invited
• [Presentation] ハイパーブランチポリエーテルスルホンを利用した固体酸触媒の開発 (2015)
  • Author(s): 難波江裕太，梁杰，早川晃鏡，柿本雅明
  • Organizer: 高分子討論会
  • Place of Presentation: 東北大学
  • Year and Date: 2015-09-16
• [Presentation] Hybrids of Hyperbranched Polymers and Carbon as Novel Materials for Catalysis (2015)
  • Author(s): Yuta Nabae
  • Organizer: ICMAT2015
  • Place of Presentation: シンガポール
  • Year and Date: 2015-06-30
  • Int'l Joint Research / Invited
• [Presentation] ハイパーブランチポリエーテルケトンとカーボンのハイブリッド材料による固体触媒反応 (2015)
  • Author(s): 難波江裕太，史穎，早川晃鏡，柿本雅明
  • Organizer: 国際フォトポリマーコンファレンス
  • Place of Presentation: 幕張メッセ
  • Year and Date: 2015-06-24
• [Presentation] カーボンや芳香族ハイパーブランチポリマーを 利用した不均一系触媒 (2015)
  • Author(s): 難波江裕太
  • Organizer: 産総研触媒化学融合研究センター 第18回講演会
  • Place of Presentation: 産業技術総合研究所
  • Year and Date: 2015-04-10
  • Invited
• [Presentation] スルホン化ポリエーテルスルホンを利用した酸触媒反応におけるハイパーブランチ構造の効果 (2015)
  • Author(s): 難波江裕太、梁杰、早川晃鏡、柿本雅明
  • Organizer: 第１１５回触媒討論会
  • Place of Presentation: 成蹊大学
  • Year and Date: 2015-03-24
• [Presentation] Hybrid of hyperbranched polymer and carbon as a novel solid catalyst material (2015)
  • Author(s): Yuta Nabae, Jie Liang, Xuhui Huang, Teruaki Hayakawa, Masa-aki Kakimoto
  • Organizer: Fourth International Conference on Multifunctional, Hybrid and Nanomaterials
  • Place of Presentation: Sitges, Spain
  • Year and Date: 2015-03-09
• [Presentation] カーボンやハイパーブランチポリマーを利用した不均一系触媒 (2015)
  • Author(s): 難波江裕太
  • Organizer: 高難度選択酸化反応研究会シンポジウム
  • Place of Presentation: 東京工業大学
  • Year and Date: 2015-01-30
  • Invited
• [Presentation] ハイパーブランチポリエーテルスルホンを利用した固体酸触媒によるアニソールのアルキル化反応 (2014)
  • Author(s): 冨田眞輝、梁杰、難波江裕太、早川晃鏡、柿本雅明
  • Organizer: 第１１４回触媒討論会
  • Place of Presentation: 広島大学
  • Year and Date: 2014-09-26
• [Presentation] TEMPO末端を有するハイパーブランチポリエーテル ケトンの合成とアルコールの選択的部分酸化反応 (2014)
  • Author(s): 史 穎、 難波江 裕太、早川 晃鏡、柿本 雅明
  • Organizer: 第６３回高分子討論会
  • Place of Presentation: 長崎大学
  • Year and Date: 2014-09-24
• [Presentation] Sulfonic Acid Functionalized Hyperbranched Poly(ether sulfone) Grafted onto Carbon Black as a Solid Acid Catalyst (2014)
  • Author(s): Masaki Tomita, Jie Liang, Yuta Nabae, Teruaki Hayakawa and Masa-aki Kakimoto
  • Organizer: Polycondensation 2014
  • Place of Presentation: Tokyo Institute of Technology
  • Year and Date: 2014-09-08
• [Remarks] 柿本研究室ホームページ
  • URL: http://www.op.titech.ac.jp/lab/kakimoto/index.html
• [Remarks] 東工大 柿本研究室HP
  • URL: http://www.op.titech.ac.jp/lab/kakimoto/index.html
• [Remarks] 柿本研究室 研究内容
  • URL: http://www.op.titech.ac.jp/lab/kakimoto/index.html