| Project/Area Number |
26870195
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Polymer/Textile materials
Polymer chemistry
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| Research Institution | Seikei University (2015)
Kyushu University (2014) |
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Principal Investigator |
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| Project Period (FY) |
2014-04-01 – 2016-03-31
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| Project Status |
Completed (Fiscal Year 2015)
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| Budget Amount *help |
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2015: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2014: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
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| Keywords | スクアリン酸アミド / 縮合反応 / 重縮合 / 高分子合成 / スクアリン酸 / 精密重合 |
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| Outline of Final Research Achievements |
The synthesis of the polymers consisting of squaramide as a component of main chain has not been reported. If such polymers can be synthesized, the property is expected to be very interesting. We now report the synthesis of polysquaramide under a variety of conditions. When 1 was polymerized with LiHMDS in dry THF at 40 °C for 99 h, 1 was almost consumed and the molecular weight of the obtained product was higher than 1. We investigated the structure of obtained products (Mn = 670, Mw = 730), but it did not match the expected structure, such as oligomers or cyclic compounds. Accordingly, the condensation reaction between 2 and 3 was carried out as a model reaction to clarify the polymerization behavior. It revealed that the base was reacted with 3 under any conditions. Currently, we are the synthesis of squaramide oligomers by stepwise condensation reaction.
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