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Development of A Measurement Technique for Noneuilibrium Potential Distributions Using Atomic Force Microscopy and Its Application to Solid Battery Analysis

Research Project

Project/Area Number 26870272
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Composite materials/Surface and interface engineering
Nanomaterials chemistry
Research InstitutionNagoya University

Principal Investigator

Motoyama Munekazu  名古屋大学, 工学研究科, 講師 (30705752)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2016: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2015: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2014: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywords原子間力顕微鏡 / 表面電位 / イオン伝導体 / 全固体型リチウム電池 / 相互作用力 / 誘電体 / 静電エネルギー / 分子間力 / 固体電池 / 電位分布
Outline of Final Research Achievements

Calibration lines for the surface potential measurements using amplitude-modulated-atomic-force microscopy (AM-AFM) are made in the first step of this study. An Au-coated-AFM probe oscillating at the resonance frequency is approached toward flat Pt surface. Variations in amplitude and phase of the oscillations are measured to analyze interaction force profiles under bias voltage between probe and Pt sample. The measurement results exhibit expected trends supporting the theory, and the calibration lines show correlation coefficients larger than 0.95. Subsequently, thin Al2O3 and LiPON films are deposited on interdigitated-Pt electrodes to measure surface potential distributions between the electrodes. Eventually, the surface potential linearly changes on the Al2O3 surface. On the other hand, the potential rapidly changes near the electrode on LiPON surface. It is considered that the space charge layer causes non-linear variation in surface potential near the Pt electrodes.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (27 results)

All 2017 2016 2015 2014

All Journal Article (2 results) (of which Peer Reviewed: 1 results,  Acknowledgement Compliant: 1 results) Presentation (24 results) (of which Int'l Joint Research: 6 results,  Invited: 2 results) Book (1 results)

  • [Journal Article] Modeling the Nucleation and Growth of Li at Metal Current Collector/LiPON Interfaces2015

    • Author(s)
      Munekazu Motoyama, Makoto Ejiri, and Yasutoshi Iriyama
    • Journal Title

      Journal of The Electrochemical Society

      Volume: 162 Issue: 13 Pages: A7067-A7071

    • DOI

      10.1149/2.0051513jes

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] 不燃性ガラス電解質上で起こるリチウム析出溶解反応2014

    • Author(s)
      本山宗主,入山恭寿
    • Journal Title

      化学工業

      Volume: 65 Pages: 33-39

    • Related Report
      2014 Research-status Report
    • Acknowledgement Compliant
  • [Presentation] 酸化物系無機固体電解質上におけるLi金属の析出溶解反応2017

    • Author(s)
      本山宗主,米元文洋,木村俊雄,入山恭寿
    • Organizer
      電気化学会第84回大会
    • Place of Presentation
      首都大学東京 南大沢キャンパス(東京都八王子市)
    • Year and Date
      2017-03-25
    • Related Report
      2016 Annual Research Report
  • [Presentation] n-Situ Scanning Electron Microscope Observations of Electrochemical Li Deposition and Dissolution at LiPON/Pt, Au Interfaces2017

    • Author(s)
      M. Motoyama, T. Kimura, M. Ejiri, and Y. Iriyama
    • Organizer
      IBA2017
    • Place of Presentation
      奈良春日野国際フォーラム(奈良県奈良市)
    • Year and Date
      2017-03-05
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 酸化物系ガラス電解質/金属集電体界面におけるLi析出溶解反応のin-situ SEM観察2017

    • Author(s)
      本山宗主
    • Organizer
      日本金属学会東海支部・日本鉄鋼協会東海支部学術討論会
    • Place of Presentation
      名古屋大学(愛知県名古屋市)
    • Year and Date
      2017-01-31
    • Related Report
      2016 Annual Research Report
  • [Presentation] Au, Pt集電体/LiPON界面におけるLi析出溶解反応のin-situ SEM観察2016

    • Author(s)
      本山宗主,木村俊雄,鈴木慎太郎,入山恭寿
    • Organizer
      第57回電池討論会
    • Place of Presentation
      幕張メッセ(千葉県千葉市)
    • Year and Date
      2016-11-29
    • Related Report
      2016 Annual Research Report
  • [Presentation] 振幅変調型AFMを用いたLi+伝導性固体電解質薄膜の比誘電率測定2016

    • Author(s)
      木村健二,本山宗主,入山恭寿
    • Organizer
      2016年電気化学会北海道支部・東海支部合同シンポジウム「インテリジェント電気化学の新潮流」
    • Place of Presentation
      北海道大学(北海道札幌市)
    • Year and Date
      2016-11-23
    • Related Report
      2016 Annual Research Report
  • [Presentation] In-Situ Scanning Electron Microscope Observations of Electrochemical Li Deposition and Dissolution at LiPON/Pt, Au Interfaces2016

    • Author(s)
      M. Motoyama, T. Kimura, M. Ejiri, and Y. Iriyama
    • Organizer
      PRiME2016
    • Place of Presentation
      Honolulu, HI
    • Year and Date
      2016-10-02
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 振幅変調型AFMを用いたLi+伝導性固体電解質薄膜の比誘電率測定2016

    • Author(s)
      木村健二,本山宗主,入山恭寿
    • Organizer
      第77回応用物理学会秋季学術講演会
    • Place of Presentation
      朱鷺メッセ(新潟県新潟市)
    • Year and Date
      2016-09-13
    • Related Report
      2016 Annual Research Report
  • [Presentation] Modelling the Nucleation and Growth of Li at Metal Current Collector/LiPON Interfaces2016

    • Author(s)
      M. Motoyama, M. Ejiri, and Y. Iriyama
    • Organizer
      18th International Meeting on Lithium Batteries: IMLB 2016
    • Place of Presentation
      Chicago, IL
    • Year and Date
      2016-06-19
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 複合固体電解質/Pt, Au界面で起こるリチウム析出溶解反応のin-situ SEM 観察2016

    • Author(s)
      本山宗主,木村俊雄,江尻誠,入山恭寿
    • Organizer
      第18回化学電池材料研究会ミーティング
    • Place of Presentation
      日本化学会会館7階ホール(東京都千代田区神田駿河台1-5)
    • Year and Date
      2016-06-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] 複合固体電解質/Pt, Au界面で起こるリチウム析出溶解反応のin-situ SEM 観察2016

    • Author(s)
      本山宗主,木村俊雄,入山恭寿
    • Organizer
      電気化学会第83回大会
    • Place of Presentation
      大阪大学吹田キャンパス
    • Year and Date
      2016-03-30
    • Related Report
      2015 Research-status Report
  • [Presentation] 振幅変調型AFMを用いた単一ナノ粒子の比誘電率測定2016

    • Author(s)
      木村健二,本山宗主,入山恭寿
    • Organizer
      第63回応用物理学会春季学術講演会
    • Place of Presentation
      東京工業大学
    • Year and Date
      2016-03-21
    • Related Report
      2015 Research-status Report
  • [Presentation] 集電体/LiPON 界面における Li 析出溶解反応の in-situ FE-SEM 観察2015

    • Author(s)
      本山宗主,木村俊雄,入山恭寿
    • Organizer
      第56回電池討論会
    • Place of Presentation
      愛知県名古屋市ウィンクあいち
    • Year and Date
      2015-11-12
    • Related Report
      2015 Research-status Report
  • [Presentation] In-situ observations of electrochemical Li growth and dissolution on a LiPON electrolyte by high resolution scanning electron microscopy2015

    • Author(s)
      Munekazu Motoyama, Toshio Toshio, and Yasutoshi Iriyama
    • Organizer
      228th ECS Meeting
    • Place of Presentation
      アメリカ合衆国アリゾナ州フェニックス
    • Year and Date
      2015-10-13
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] In-situ SEM observations of Li plating/stripping reactions through Li-Pt alloying on a LiPON electrolyte2015

    • Author(s)
      Toshio Kimura, Munekazu Motoyama, and Yasutoshi Iriyama
    • Organizer
      The 66th Annual Meeting of the ISE
    • Place of Presentation
      台湾, 台北
    • Year and Date
      2015-10-05
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] リン酸リチウムオキシナイトライドガラス/金属界面におけるリチウムの核生成・成長過程のその場電子顕微鏡観察2015

    • Author(s)
      本山宗主,木村俊雄,入山恭寿
    • Organizer
      第26会東海地区光電気化学研究会・2015年東海地区ヤングエレクトロケミスト研究会合同講演会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2015-09-26
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] 複合固体電解質/Pt集電体界面で起こるLi析出溶解反応のin-situ SEM観察2015

    • Author(s)
      木村俊雄,本山宗主,入山恭寿
    • Organizer
      2015年電気化学秋季大会
    • Place of Presentation
      埼玉工業大学
    • Year and Date
      2015-09-12
    • Related Report
      2015 Research-status Report
  • [Presentation] LiPON/Cu集電体界面におけるLi析出溶解反応のモデル化2015

    • Author(s)
      本山宗主,木村俊雄,入山恭寿
    • Organizer
      2015年電気化学秋季大会
    • Place of Presentation
      埼玉工業大学
    • Year and Date
      2015-09-11
    • Related Report
      2015 Research-status Report
  • [Presentation] 集電体/LiPON界面におけるLiの核生成・成長過程のモデル化2015

    • Author(s)
      本山宗主,江尻誠,木村俊雄,入山恭寿
    • Organizer
      第17回化学電池材料研究会ミーティング
    • Place of Presentation
      東京都千代田区 日本化学会会館
    • Year and Date
      2015-06-16
    • Related Report
      2015 Research-status Report
  • [Presentation] In-situ scanning electron microscope observations of lithium nucleation and growth at solid/solid interfaces for all-solid-state-lithium battery2015

    • Author(s)
      Munekazu Motoyama, Makoto Ejiri, and Yasutoshi Iriyama
    • Organizer
      227th ECS Meeting
    • Place of Presentation
      アメリカ合衆国イリノイ州シカゴ
    • Year and Date
      2015-05-25
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] In-Situ Electron Microscope Observations of Electrochemical Li Deposition/Dissolution with a LiPON Electrolyte2015

    • Author(s)
      本山宗主
    • Organizer
      ISPlasma2015/IC-PLANTS2015
    • Place of Presentation
      名古屋大学
    • Year and Date
      2015-03-26 – 2015-03-31
    • Related Report
      2014 Research-status Report
  • [Presentation] In-situ scanning electron microscope observations of strain-confined lithium nucleation at electrode/electrolyte interfaces in all-solid-state-lithium battery2014

    • Author(s)
      本山宗主
    • Organizer
      2014 MRS Fall Meeting & Exhibit
    • Place of Presentation
      マサチューセッツ,米国
    • Year and Date
      2014-11-30 – 2014-12-05
    • Related Report
      2014 Research-status Report
  • [Presentation] In situ scanning electron microscope observations of charge-discharge reactions on Li metal anode in all-solid-state lithium battery2014

    • Author(s)
      江尻誠
    • Organizer
      2014 MRS Fall Meeting & Exhibit
    • Place of Presentation
      マサチューセッツ,米国
    • Year and Date
      2014-11-30 – 2014-12-05
    • Related Report
      2014 Research-status Report
  • [Presentation] リン酸リチウムオキシナイトライドガラス/金属界面におけるリチウムの核生成・成長過程のその場電子顕微鏡観察2014

    • Author(s)
      本山宗主
    • Organizer
      第45回中部化学関係学協会支部連合秋季大会
    • Place of Presentation
      中部大学
    • Year and Date
      2014-11-29 – 2014-11-30
    • Related Report
      2014 Research-status Report
  • [Presentation] 走査型電子顕微鏡を用いた全固体リチウム電池負極のその場観察2014

    • Author(s)
      本山宗主
    • Organizer
      日立材料解析新技術セミナー 2014
    • Place of Presentation
      瀧定名古屋ビル
    • Year and Date
      2014-11-27
    • Related Report
      2014 Research-status Report
    • Invited
  • [Book] 全固体電池のイオン伝導性向上技術と材料、製造プロセスの開発2017

    • Author(s)
      石黒恭生 他106名
    • Total Pages
      475
    • Publisher
      技術情報協会
    • Related Report
      2016 Annual Research Report

URL: 

Published: 2014-04-04   Modified: 2018-03-22  

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