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Study of intercalation mechanism and state of sodium into nanopores in carbon materials

Research Project

Project/Area Number 26870385
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Nanomaterials chemistry
Inorganic industrial materials
Research InstitutionOkayama University

Principal Investigator

GOTOH KAZUMA  岡山大学, 自然科学研究科, 准教授 (20385975)

Research Collaborator KOMABA Shinichi  東京理科大学, 理学部, 教授
SHIMIZU Tadashi  物質材料研究機構, 強磁場ステーション長
YUMURA Tadashi  京都工芸繊維大学, 材料化学系, 准教授
Lerner Michael M.  オレゴン州立大学, 化学科, 教授
Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2016: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2015: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2014: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywords固体NMR / 炭素材料 / ハードカーボン / ナトリウムイオン電池 / リチウムイオン電池 / 黒鉛層間化合物 / ナトリウムクラスター / 分子ダイナミクス / ナノ細孔
Outline of Final Research Achievements

The state of sodium and the structure of adsorption sites in carbon electrode of sodium ion battery were studied using solid state nuclear magnetic resonance. Our new model of sodium storage can explain why many sodium ions are doped into non-graphitizable carbon produced by heat treatment over 1600 degree C. The dynamic behavior of organic molecules co-intercalated with sodium in graphite was also revealed.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (47 results)

All 2017 2016 2015 2014 Other

All Int'l Joint Research (2 results) Journal Article (9 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 9 results,  Open Access: 1 results,  Acknowledgement Compliant: 2 results) Presentation (34 results) (of which Int'l Joint Research: 4 results,  Invited: 9 results) Book (2 results)

  • [Int'l Joint Research] Oregon State University(米国)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] King Mongkut's Institute of Technology(タイ)

    • Related Report
      2016 Annual Research Report
  • [Journal Article] Enhanced Li-Ion Accessibility in MXene Titanium Carbide by Steric Chloride Termination2017

    • Author(s)
      Satoshi Kajiyama, Lucie Szabova, Hiroki Iinuma, Akira Sugahara, Kazuma Gotoh, Keitaro Sodeyama, Yoshitaka Tateyama, Masashi Okubo, Atsuo Yamada
    • Journal Title

      Advanced Energy Materials

      Volume: - Issue: 9 Pages: 1601873-1601873

    • DOI

      10.1002/aenm.201601873

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Show stabilizataion of Si-Li alloys formed during charge and discharge of a Si-C mixed electrode studied by in situ solid-state 7Li nuclear magnetic resonance spectroscopy2017

    • Author(s)
      Juichi Arai, Kazuma Gotoh, Ryo Sayama and Kazuyuki Takeda
    • Journal Title

      J. Electrochem. Soc.

      Volume: 164 Issue: 1 Pages: A6334-A6340

    • DOI

      10.1149/2.0541701jes

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Combination of Solid State NMR and DFT Calculation to Elucidate the State of sodium and lithium in Hard Carbon Electrodes2016

    • Author(s)
      Morita, R.; Gotoh, K.; Fukunishi, M.; Kubota, K.; Komaba, S.; Nishimura, N.; Yumura, T.; Deguchi, K.; Ohki, S.; Shimizu, T.; Ishida, H
    • Journal Title

      Journal Material Chemistry A

      Volume: 4 Issue: 34 Pages: 13183-13193

    • DOI

      10.1039/c6ta04273b

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Structure and Dynamic Behavior of Na-Diglyme Complex in the Graphite Anode of Sodium Ion2016

    • Author(s)
      K. Gotoh, H. Maruyama, T. Miyatou, M. Mizuno, K. Urita, H. Ishida
    • Journal Title

      J. Phys. Chem. C

      Volume: 120 Issue: 49 Pages: 28152-28156

    • DOI

      10.1021/acs.jpcc.6b10962

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Surface and interlayer base-characters in lepidocrocite titanate: The adsorption and intercalation of fatty acid2016

    • Author(s)
      Tosapol Maluangnont, Pornanan Arsa, Kanokporn Limsakul, Songsit Juntarachairot, Saithong Sangsan, Kazuma Gotoh and Tawan Sooknoi
    • Journal Title

      J. Solid State Chem.

      Volume: 238 Pages: 175-181

    • DOI

      10.1016/j.jssc.2016.03.030

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Sodium-Ion Intercalation Mechanism in MXene Nanosheets2016

    • Author(s)
      Satoshi Kajiyama, Lucie Szabova, Keitaro Sodeyama, Hiroki Iinuma, Ryohei Morita, Kazuma Gotoh, Yoshitaka Tateyama, Masashi Okubo, and Atsuo Yamada
    • Journal Title

      ACS Nano

      Volume: 10 Issue: 3 Pages: 3334-3341

    • DOI

      10.1021/acsnano.5b06958

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Arrangement and Dynamics of Diamine, Etheric, and Tetraalkylammonium Intercalates within Graphene or Graphite Oxide Galleries by 2H NMR2015

    • Author(s)
      Kazuma Gotoh, Chika Sugimoto, Ryohei Morita, Tatsuya Miyatou, Motohiro Mizuno, Weekit Sirisaksoontorn, Michael M Lerner, and Hiroyuki Ishida
    • Journal Title

      J. Phys. Chem. C

      Volume: 119 Issue: 21 Pages: 11763-11770

    • DOI

      10.1021/acs.jpcc.5b03016

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] In Situ Solid State 7Li NMR Observations of Lithium Metal Deposition during Overcharge in Lithium Ion Batteries2015

    • Author(s)
      Juichi Arai, Yumika Okada, Teruyasu Sugiyama, Misato Izuka, Kazuma Gotoh, and Kazuyuki Takeda
    • Journal Title

      J. Electrochem. Soc.

      Volume: 162 Issue: 6 Pages: A952-A958

    • DOI

      10.1149/2.0411506jes

    • Related Report
      2015 Research-status Report 2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] In situ 7Li nuclear magnetic resonance study of the relaxation effect in practical lithium ion batteries2014

    • Author(s)
      Kazuma Gotoh, Misato Izuka, Juichi Arai, Yumika Okada, Teruyasu Sugiyama, Kazuyuki Takeda, and Hiroyuki Ishida
    • Journal Title

      Carbon

      Volume: 79 Pages: 380-387

    • DOI

      10.1016/j.carbon.2014.07.080

    • NAID

      120005473066

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Presentation] 固体NMRによる酸化グラフェン及び関連物質の研究2016

    • Author(s)
      後藤和馬
    • Organizer
      第7回酸化グラフェン研究会
    • Place of Presentation
      姫路
    • Year and Date
      2016-12-16
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 固体NMRおよびDFT計算による二次電池負極炭素中のリチウムおよびナトリウムの状態分析2016

    • Author(s)
      森田凌平,後藤和馬,福西美香,久保田圭,駒場慎一,西村直人,湯村尚史,出口健三,大木忍,清水禎,石田祐之
    • Organizer
      第55回NMR討論会
    • Place of Presentation
      広島
    • Year and Date
      2016-11-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] 2H NMRによる黒鉛層間エーテル分子の構造および動的挙動の解析2016

    • Author(s)
      後藤和馬,丸山寿史,森田凌平,水野元博,宮東達也,瓜田幸幾,石田祐之
    • Organizer
      第55回NMR討論会
    • Place of Presentation
      広島
    • Year and Date
      2016-11-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] NMRを用いた電気化学系材料の評価2016

    • Author(s)
      後藤和馬
    • Organizer
      電気化学セミナー4
    • Place of Presentation
      東京
    • Year and Date
      2016-11-15
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] ジグライムが挿入された三元系黒鉛層間化合物の固体NMRを用いた解析2016

    • Author(s)
      丸山寿史,後藤和馬,水野元博,宮東達也,瓜田幸幾,石田祐之
    • Organizer
      第30回日本吸着学会研究発表会
    • Place of Presentation
      長崎
    • Year and Date
      2016-11-10
    • Related Report
      2016 Annual Research Report
  • [Presentation] ナトリウム電池負極に挿入されたNaイオンの状態研究2016

    • Author(s)
      後藤和馬
    • Organizer
      固体NMR・材料フォーラム
    • Place of Presentation
      金沢
    • Year and Date
      2016-10-20
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] A study of quasi-metallic lithium/sodium cluster in negative electrode materials for secondary battery using solid state NMR and DFT calculation2016

    • Author(s)
      Ryohei Morita, Kazuma Gotoh, Mika Fukunishi, Mouad Dahbi, Kei Kubota, Shinichi Komaba, Naoto Nishimura, Takashi Yumura, Kenzo Deguchi, Shinobu Ohki, Tadashi Shimizu and Hiroyuki Ishida
    • Organizer
      Carbon 2016
    • Place of Presentation
      State College, USA
    • Year and Date
      2016-07-13
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Structure and dynamics of diglyme molecules in graphene layers with sodium ion studied by 2H NMR2016

    • Author(s)
      Kazuma Gotoh, Hisashi Maruyama, Tomoaki Takizawa, Ryohei Morita, Tatsuya Miyatou, Motohiro Mizuno, Koki Urita and Hiroyuki Ishida
    • Organizer
      Carbon 2016
    • Place of Presentation
      State College, USA
    • Year and Date
      2016-07-12
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 炭素材料の固体多核NMRによる分析2016

    • Author(s)
      後藤和馬
    • Organizer
      高分子学会NMR研究会
    • Place of Presentation
      鶴見
    • Year and Date
      2016-05-13
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] リチウムイオン電池の負極表面における電解液の分解の評価2015

    • Author(s)
      佐山瞭,後藤和馬,仁科勇太,石田祐之
    • Organizer
      第5回酸化グラフェンシンポジウム
    • Place of Presentation
      岡山(岡山大)
    • Year and Date
      2015-12-14
    • Related Report
      2015 Research-status Report
  • [Presentation] 高温・低温焼成スクロース由来炭素へのナトリウム吸蔵と固体NMRによる分析2015

    • Author(s)
      森田凌平,後藤和馬,久保田圭,福西美香,駒場慎一,湯村尚史,石田祐之
    • Organizer
      第42回炭素材料学会年会
    • Place of Presentation
      大阪(関西大)
    • Year and Date
      2015-12-02
    • Related Report
      2015 Research-status Report
  • [Presentation] 炭素平面上におけるアルカリ金属原子の安定配置に関する密度汎関数法計算2015

    • Author(s)
      西村直人,湯村尚史,後藤和馬,若杉隆
    • Organizer
      第42回炭素材料学会年会
    • Place of Presentation
      大阪(関西大)
    • Year and Date
      2015-12-02
    • Related Report
      2015 Research-status Report
  • [Presentation] NMRによるリチウムイオン電池、ナトリウムイオン電池材料の分析2015

    • Author(s)
      後藤和馬
    • Organizer
      平成27年度東海化学工業会セミナー
    • Place of Presentation
      名古屋(今池)
    • Year and Date
      2015-11-26
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] 黒鉛層間にアルカリ金属と共挿入された有機分子の運動状態解析2015

    • Author(s)
      後藤和馬,杉本千佳,丸山寿史,瀧澤智昭,宮東達也,水野元博,石田祐之
    • Organizer
      第29回日本吸着学会研究発表会
    • Place of Presentation
      徳島(徳島大)
    • Year and Date
      2015-11-19
    • Related Report
      2015 Research-status Report
  • [Presentation] 炭素・電池材料の固体NMR2015

    • Author(s)
      後藤和馬
    • Organizer
      2015年度日本化学会中国四国支部大会
    • Place of Presentation
      岡山(岡山大)
    • Year and Date
      2015-11-14
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] スクロース由来ハードカーボン中のナトリウムのNMRによる状態分析2015

    • Author(s)
      森田凌平, 後藤和馬, 久保田圭, 福西美香, 駒場慎一, 出口健三, 大木忍, 清水禎, 石田祐之
    • Organizer
      2015年日本化学会中国四国支部大会
    • Place of Presentation
      岡山(岡山大)
    • Year and Date
      2015-11-14
    • Related Report
      2015 Research-status Report
  • [Presentation] リチウムイオン電池の負極表面における電解液の分解の評価2015

    • Author(s)
      佐山瞭, 後藤和馬, 仁科勇太, 定井麻子, 三根生晋, 石田祐之
    • Organizer
      2015年日本化学会中国四国支部大会
    • Place of Presentation
      岡山(岡山大)
    • Year and Date
      2015-11-14
    • Related Report
      2015 Research-status Report
  • [Presentation] 有機溶媒中での反応を利用した新規黒鉛層間化合物の合成と構造研究2015

    • Author(s)
      丸山寿史, 瀧澤智昭, 後藤和馬, 石田祐之
    • Organizer
      2015年日本化学会中国四国支部大会
    • Place of Presentation
      岡山(岡山大)
    • Year and Date
      2015-11-14
    • Related Report
      2015 Research-status Report
  • [Presentation] in situ Li NMRによるSi含有炭素負極および電解質の精密分析2015

    • Author(s)
      佐山瞭,後藤和馬,新井寿一,中東里英,武田和行,石田祐之
    • Organizer
      第58回固体NMR・材料フォーラム
    • Place of Presentation
      高知(高知大)
    • Year and Date
      2015-10-22
    • Related Report
      2015 Research-status Report
  • [Presentation] リチウムイオン電池の負極表面における電解液の分解の評価2015

    • Author(s)
      佐山瞭,後藤和馬,仁科勇太,定井麻子,三根生晋,石田祐之
    • Organizer
      第53回炭素材料夏季セミナー
    • Place of Presentation
      東京(千葉工大ソラマチキャンパス)
    • Year and Date
      2015-08-10
    • Related Report
      2015 Research-status Report
  • [Presentation] Observations of adsorbed ions or molecules in carbon materials using solid state NMR2015

    • Author(s)
      Kazuma Gotoh
    • Organizer
      5th German-Japanese Joint Symposium on Carbon Materials
    • Place of Presentation
      Freiberg, Germany
    • Year and Date
      2015-07-19
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Analysis of Sodium Ion Stored in Hard Carbon using Solid State Na NMR2015

    • Author(s)
      Kazuma Gotoh
    • Organizer
      Carbon2015
    • Place of Presentation
      Dresden (Germany)
    • Year and Date
      2015-07-14
    • Related Report
      2014 Research-status Report
  • [Presentation] Analysis of sodium ion stored in hard carbon using solid state Na NMR2015

    • Author(s)
      Kazuma Gotoh
    • Organizer
      Carbon 2015
    • Place of Presentation
      Dresden, Germany
    • Year and Date
      2015-07-12
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] 高温熱処理炭素に吸蔵されたナトリウムの固体NMRによる状態分析2015

    • Author(s)
      森田凌平, 後藤和馬, 久保田圭, 福西美香, 駒場慎一, 出口健三, 大木忍, 清水禎, 石田祐之
    • Organizer
      第57回固体NMR・材料フォーラム
    • Place of Presentation
      鶴見(理研)
    • Year and Date
      2015-05-22
    • Related Report
      2015 Research-status Report
  • [Presentation] 黒鉛層間にインターカレートされた重水素化有機分子の2H NMR による運動状態解析2015

    • Author(s)
      杉本千佳,後藤和馬,宮東達也,水野元博,石田祐之
    • Organizer
      第57回固体NMR・材料フォーラム
    • Place of Presentation
      鶴見(理研)
    • Year and Date
      2015-05-22
    • Related Report
      2015 Research-status Report
  • [Presentation] 高温熱処理炭素に吸蔵されたナトリウムの固体NMRによる状態分析2015

    • Author(s)
      森田凌平, 後藤和馬, 久保田圭, 福西美香, 駒場慎一, 出口健三, 大木忍, 清水禎, 石田祐之
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      船橋(日本大学)
    • Year and Date
      2015-03-26
    • Related Report
      2014 Research-status Report
  • [Presentation] 層状化合物MXene Ti3C2のナトリウムイオン電極特性2015

    • Author(s)
      梶山智司,飯沼広基,森田凌平,後藤和馬,大久保將史,山田淳夫
    • Organizer
      電気化学会第82回大会
    • Place of Presentation
      横浜(横浜国立大)
    • Year and Date
      2015-03-17
    • Related Report
      2014 Research-status Report
  • [Presentation] P2型Na2/3MnO2の結晶多形と非化学量論性2015

    • Author(s)
      田原禎之,久保田圭,熊倉真一,後藤和馬,駒場慎一
    • Organizer
      電気化学会第82回大会
    • Place of Presentation
      横浜(横浜国立大)
    • Year and Date
      2015-03-16
    • Related Report
      2014 Research-status Report
  • [Presentation] 磁気共鳴法でみる二次電池負極用炭素材料の内部構造2015

    • Author(s)
      後藤和馬
    • Organizer
      大阪電気通信大学エレクトロニクス基礎研究所ワークショップ
    • Place of Presentation
      寝屋川(大阪電通大)
    • Year and Date
      2015-02-13
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Li storage and Na storage in carbon materials analyzed by solid state NMR2014

    • Author(s)
      Kazuma Gotoh
    • Organizer
      第41回炭素材料学会年会
    • Place of Presentation
      福岡(大野城まどかぴあ)
    • Year and Date
      2014-12-10
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] 三元系黒鉛層間化合物の2H NMRによる状態分析2014

    • Author(s)
      杉本千佳, 後藤和馬, 宮東達也, 水野元博, 石田祐之
    • Organizer
      第41回炭素材料学会年会
    • Place of Presentation
      福岡(大野城まどかぴあ)
    • Year and Date
      2014-12-08
    • Related Report
      2014 Research-status Report
  • [Presentation] in situ Li NMRを用いたリチウムイオン実電池の負極内リチウムの観察2014

    • Author(s)
      後藤和馬, 伊塚美里, 杉山照泰, 中東理恵, 新井寿一, 武田和行, 石田祐之
    • Organizer
      第55回電池討論会
    • Place of Presentation
      京都(京都国際会館)
    • Year and Date
      2014-11-21
    • Related Report
      2014 Research-status Report
  • [Presentation] In situ Li NMR によるリチウムイオン電池の過充電状態の解析2014

    • Author(s)
      伊塚美里,後藤和馬,杉山照泰,中東里英,新井寿一,武田和行,石田祐之
    • Organizer
      第53回NMR討論会
    • Place of Presentation
      大阪(大阪大学)
    • Year and Date
      2014-11-06
    • Related Report
      2014 Research-status Report
  • [Presentation] 炭素とナノスペースの化学2014

    • Author(s)
      後藤和馬
    • Organizer
      岡山工学振興会第58回ほっと交流会
    • Place of Presentation
      岡山(岡山工学振興会)
    • Year and Date
      2014-05-22
    • Related Report
      2014 Research-status Report
    • Invited
  • [Book] 『NMR分光法』(阿久津秀雄,嶋田一夫,鈴木榮一郎,西村善文編)第6章 “物質科学への展開”2016

    • Author(s)
      後藤和馬
    • Publisher
      講談社サイエンティフィック
    • Related Report
      2015 Research-status Report
  • [Book] 『ナトリウムイオン2次電池の開発と最新技術』 (岡田重人,駒場慎一,山田淳夫編) 第5章第2編 “NMRによる2次電池の計測”2015

    • Author(s)
      後藤和馬
    • Publisher
      技術教育出版社
    • Related Report
      2015 Research-status Report

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Published: 2014-04-04   Modified: 2022-02-16  

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