| Project/Area Number |
26870593
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Nanomaterials chemistry
Nano/Microsystems
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| Research Institution | Chuo University |
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Principal Investigator |
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| Research Collaborator |
YAMAUCHI Yusuke 法人物質・材料研究機構, 国際ナノアーキテクトニクス研究拠点, 主任研究者 (10455272)
KAJI Kohei 中央大学, 大学院, 学生
AOYAMA Hiroyuki 中央大学, 大学院, 学生
ENDO Michinori 中央大学, 大学院, 学生
Matsuzawa Takuya 中央大学, 大学院, 学生
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| Project Period (FY) |
2014-04-01 – 2017-03-31
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| Project Status |
Completed (Fiscal Year 2016)
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| Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2015: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2014: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
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| Keywords | 不斉触媒 / キラル認識 / キラル識別 / キラリティー / 化学センサ / キラルセンサ / 電気化学 / アミノ酸 / 多孔質材料 / キラル選択性 |
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| Outline of Final Research Achievements |
In this study, asymmetric catalytic activities of porous Pt electrodes baring high-index surfaces for electrochemical reactions of chiral compounds were invesitgated to indicate a guidance for preparation of high-performance asymmetric catalysis, or chiral sensors. For this purpose, enantioselectivity in electrochemical reactions were evaluated by electrochemical methods by changing substrates, target chiral molecules, kinds of metal, preparation process of the porous electrodes, and solution conditions. By these investigations, the capablity of chiral recognition using the porous bare metals was firstly demonstrated. The chiral sensing method using electrochemical methods was applied for a patent.
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