A study of surface chemical reaction in atmospheric pressure by means of electronic state imaging
| Project/Area Number |
26870857
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Condensed matter physics I
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| Research Institution | Institute of Physical and Chemical Research |
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Principal Investigator |
Tokushima Takashi 国立研究開発法人理化学研究所, 放射光科学総合研究センター, 技師 (10415242)
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| Project Period (FY) |
2014-04-01 – 2017-03-31
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| Project Status |
Completed (Fiscal Year 2016)
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| Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2015: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2014: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
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| Keywords | 軟X線 / 放射光 / 表面 / 大気圧分光 / 電気化学 / 界面 / イメージング / 軟Ｘ線 |
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| Outline of Final Research Achievements |
A new microscopic method using soft x-rays aiming to observe spatial distribution of electronic state for chemical reaction on the surface and interface under atmospheric pressure was developed. To realize the observation under atmosphere, 100nm-thick film was adopted as a separator window between vacuum and atmosphere. To obtain electronic state information, soft x-ray emission due to irradiation of soft x-rays was analyzed. Using the newly developed experimental setup, electrochemical reaction was studied. While products generated by chemical reaction was successfully observed, intermediate species of the reaction was not observed due to its low concentration. However, experimental results suggest that observation of intermediate species becomes possible by adopting porous material as an electrode.
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Report
(4 results)
Research Products
(6 results)
