Reversible control of spin and charge via electrochemical operation based on single-molecule magnet.
| Project/Area Number |
26888017
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| Research Category |
Grant-in-Aid for Research Activity Start-up
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| Allocation Type | Single-year Grants |
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| Research Field |
Inorganic chemistry
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| Research Institution | Fukuoka University |
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Principal Investigator |
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| Project Period (FY) |
2014-08-29 – 2016-03-31
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| Project Status |
Completed (Fiscal Year 2015)
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| Budget Amount *help |
¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Fiscal Year 2015: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2014: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
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| Keywords | 単分子磁石 / 単一分子素子 / 磁性変換 / 多段階酸化還元 / 電気化学 / 酸化還元活性配位子 / 外場応答性 / 多重物性 / 分子磁性 / 単一次元鎖磁石 |
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| Outline of Final Research Achievements |
The chloranilate is one of anilate derivatives, which shows the multi-step redox property. Thus, both dinuclear dysprosium(III) and mononuclear cobalt (II) complexes with the chloranilate as the bridged were synthesized. Both complexes can reversibly control spin and/or electronic state by the electrochemical procedure, which is confirmed by the cyclic voltammetry measurement.
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Report
(3 results)
Research Products
(9 results)
