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Fabrication and characterization of the core-shell type Pd/Mg nanoparticles for the hydrogen storage application

Research Project

Project/Area Number 26889034
Research Category

Grant-in-Aid for Research Activity Start-up

Allocation TypeSingle-year Grants
Research Field Structural/Functional materials
Research InstitutionNagoya University

Principal Investigator

Ogawa Satoshi  名古屋大学, 工学(系)研究科(研究院), 助教 (70739101)

Project Period (FY) 2014-08-29 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2015: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2014: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Keywordsコアシェル型ナノ粒子 / 水素吸蔵材料 / マグネシウム / パラジウム / XPS / NEXAFS / ナノ材料 / 表面・界面物性 / 水素 / X線
Outline of Final Research Achievements

We have attempted the fabrication of the core-shell type nanoparticle composed of Mg core and Pd shell (Pd/Mg NPs) for the hydrogen storage application. The gas evaporation method using He gas was adopted to fabricate the Pd/Mg NPs. The evaporated Mg atoms were condensed into the Mg NPs in the He gas atmosphere. After that, the surface of the Mg NPs was decorated with Pd. As a result, unfortunately, we have not been able to establish the covering the Mg NPs with Pd shell. The Pd atoms have formed the Pd NPs on the surface of the Mg NPs.
We have investigated the hydrogen storage property of this composite material of the Mg and Pd NPs. The almost 90% of the Mg atoms in this material have been hydrogenated at the room temperature. The analyses of the chemical state using X-ray have revealed that the interfacial Mg-Pd alloy is formed between Mg and Pd nanoparticles.

Report

(3 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Annual Research Report
  • Research Products

    (9 results)

All 2016 2015 2014

All Journal Article (2 results) (of which Peer Reviewed: 2 results,  Acknowledgement Compliant: 2 results) Presentation (7 results) (of which Int'l Joint Research: 2 results)

  • [Journal Article] Hydrogen Storage of Pd/Mg composite nanoparticles fabricated by gas evaporation method2016

    • Author(s)
      Satoshi Ogawa, Hiroyuki Suzuki, Chie Tsukada, Tomoko Yoshida, Shinya Yagi
    • Journal Title

      e-Journal of Surface Science and Nanotechnology

      Volume: 未定

    • NAID

      130005151355

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Hydrogen storage of binary nanoparticles composed of Mg and Pd2015

    • Author(s)
      Satoshi Ogawa, Taishi Fujimoto, Tsuyoshi Mizutani, Masahiro Ogawa, Naoki Uchiyama, Kazuo Kato, Toshiaki Ohta, Tomoko Yoshida and Shinya Yagi
    • Journal Title

      International Journal of Hydrogen Energy

      Volume: -

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] XAFS分析によるPd薄膜のPC等温線の取得の試み2016

    • Author(s)
      小川 智史, 小川 雅裕, 塚田千恵, 太田 俊明, 八木 伸也
    • Organizer
      第29回日本放射光学会年会・放射光科学合同シンポジウム
    • Place of Presentation
      東京大学柏の葉キャンパス駅前サテライト、オークビレッジ柏の葉
    • Year and Date
      2016-01-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] Nanoparticles for Hydrogen Storage Application : Pd, Ni and Mg Nanoparticles2015

    • Author(s)
      Satoshi Ogawa, Hiroyuki Suzuki, Chie Tsukada, Tomoko Yoshida and Shinya Yagi
    • Organizer
      International Symposium on EcoTopia Science ’15 (ISETS ‘15)
    • Place of Presentation
      Nagoya University, Nagoya, Aichi, Japan
    • Year and Date
      2015-11-27
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Spectroscopic characterization of Pd/Mg nanoparticles during hydrogen absorption2015

    • Author(s)
      Satoshi Ogawa, Chie Tsukada, Masahiro Ogawa, Toshiaki Ohta, Tomoko Yoshida, Shinya Yagi
    • Organizer
      10th International Symposium on Atomic Level Characterizations for New Materials and Devices ’15 (ALC ‘15)
    • Place of Presentation
      Kunibiki Messe, Matsue, Shimane, Japan
    • Year and Date
      2015-10-25
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 調光薄膜材料の局所構造に関するXAFS分析2015

    • Author(s)
      小川智史,原田和美,金井友美,塚田千恵,小川雅裕,太田俊明,内山直樹,八木伸也
    • Organizer
      第18回XAFS討論会
    • Place of Presentation
      高エネルギー加速器研究機構・小林ホール
    • Year and Date
      2015-07-29
    • Related Report
      2015 Annual Research Report
  • [Presentation] Pd/Mg-Ni薄膜材料のXAFS分析2015

    • Author(s)
      小川 智史, 原田和美, 金井友美, 塚田千恵, 小川 雅裕, 太田 俊明, 内山直樹, 八木 伸也
    • Organizer
      平成27年度立命館大学SRセンター研究成果報告会
    • Place of Presentation
      立命館大学 びわこ・くさつキャンパス
    • Year and Date
      2015-06-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] Hydrogen Storage Property of the Pd nanoparticle with clean surfaces studied by QCM2014

    • Author(s)
      Satoshi Ogawa, Taishi Fujimoto, Naoki Uchiyama, Tomomi Kanai, Chie Tsukada, Tomoko Yoshida, Shinya Yagi
    • Organizer
      The 7th International Symposium on Surface Science (ISSS-7)
    • Place of Presentation
      Shimane Prefectural Convention Center, Kunibiki Messe, Matsue, Shimane, Japan
    • Year and Date
      2014-11-02 – 2014-11-06
    • Related Report
      2014 Annual Research Report
  • [Presentation] Mg-Pd二元ナノ粒子材料の水素吸蔵による 化学状態変化のNEXAFS分析2014

    • Author(s)
      小川智史,藤本大志,小川雅裕,塚田千恵,太田俊明,吉田朋子,八木伸也
    • Organizer
      第17回XAFS討論会
    • Place of Presentation
      徳島大学総合科学部
    • Year and Date
      2014-09-01 – 2014-09-03
    • Related Report
      2014 Annual Research Report

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Published: 2014-09-09   Modified: 2017-05-10  

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