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Verification of the phase transformation induced by thermal vacancies in iron aluminides

Research Project

Project/Area Number 26889072
Research Category

Grant-in-Aid for Research Activity Start-up

Allocation TypeSingle-year Grants
Research Field Physical properties of metals/Metal-base materials
Research InstitutionInstitute of Physical and Chemical Research

Principal Investigator

Niitsu Kodai  国立研究開発法人理化学研究所, 創発物性科学研究センター, 特別研究員 (90733890)

Project Period (FY) 2014-08-29 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2015: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2014: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Keywords金属材料 / 空孔 / 電子線ホログラフィー / 電子顕微鏡 / 点欠陥 / 磁性 / 欠陥
Outline of Final Research Achievements

For Fe-Al alloys quenched from high temperatures that contain high density of thermal vacancies, microstructural observation and visualization of the possible vacancy segregation were examined by using an electron holography microscope. As a result, a curious microstructure was observed for a certain concentration region, the nature of which cannot be explained within the understandings on the existing Fe-Al phase equilibrium. However, possible change of mean inner potential attributed to the microsegregation of vacancy was not detected. This is so far believed to be due to its too small signal (less than the signal-to-noise ratio) to be detected, a knockout effect due to high-voltage electron beam, or an over time decay of vacancy.

Report

(3 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Annual Research Report
  • Research Products

    (26 results)

All 2016 2015 2014

All Journal Article (6 results) (of which Peer Reviewed: 6 results,  Open Access: 3 results,  Acknowledgement Compliant: 3 results) Presentation (19 results) (of which Int'l Joint Research: 5 results,  Invited: 1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Martensitic Transformations and Superelastic Behavior at Low Temperatures in Ti<sub>50&minus;</sub><i><sub>x</sub></i>Ni<sub>40+</sub><i><sub>x</sub></i>Cu<sub>10</sub> Shape Memory Alloys2016

    • Author(s)
      Y. Kimura, X. Xu, K. Niitsu, T. Omori, R. Kainuma
    • Journal Title

      MATERIALS TRANSACTIONS

      Volume: 57 Issue: 3 Pages: 269-277

    • DOI

      10.2320/matertrans.MB201504

    • NAID

      130005127308

    • ISSN
      1345-9678, 1347-5320
    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] New trend in electron holography2016

    • Author(s)
      Toshiaki Tanigaki, Ken Harada, Yasukazu Murakami, Kodai Niitsu, Tetsuya Akashi, Yoshio Takahashi, Akira Sugawara, Daisuke Shindo
    • Journal Title

      Journal of Physics D: Applied Physics

      Volume: 49 Issue: 24 Pages: 244001-244001

    • DOI

      10.1088/0022-3727/49/24/244001

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 天然の界面が示す磁性 ‐電子線ホログラフィーによる解析‐2016

    • Author(s)
      村上恭和、新津甲大、谷垣俊明、朴賢洵、貝沼亮介、進藤大輔
    • Journal Title

      顕微鏡

      Volume: 51

    • NAID

      130007695946

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Composition Dependences of Entropy Change and Transformation Temperatures in Ni-rich Ti-Ni System2015

    • Author(s)
      K. Niitsu, Y. Kimura, X. Xu, R. Kainuma
    • Journal Title

      Shape Memory and Superelasticity

      Volume: 1 Issue: 2 Pages: 124-131

    • DOI

      10.1007/s40830-015-0023-2

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Magnetization Amplified by Structural Disorder within Nanometer-scale Interface Region2014

    • Author(s)
      Y. Murakami et al.
    • Journal Title

      Nature Commun.

      Volume: 5 Issue: 1 Pages: 4133-4133

    • DOI

      10.1038/ncomms5133

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Effect of annealing on stress-induced transformation behaviors at low temperatures in a Ti-51.8 at.% Ni shape memory alloy2014

    • Author(s)
      K. Niitsu, R. Kainuma
    • Journal Title

      PHYS STATUS SOLIDI B

      Volume: 251 Issue: 10 Pages: 2041-2047

    • DOI

      10.1002/pssb.201350418

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] Transitions of Magnetic Domain Structure Mediated by Anti-phase Boundaries in Ni50Mn20In30 Heusler Alloy2016

    • Author(s)
      Kodai Niitsu, Toshiaki Tanigaki, Xu Xiao, Yasukazu Murakami, Daisuke Shindo and Ryosuke Kainuma
    • Organizer
      The 5th international conference on ferromagnetic shape memory alloys (ICFSMA'16)
    • Place of Presentation
      Sendai, Japan
    • Year and Date
      2016-09-05
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Stress-induced martensitic transformation and phase equilibria at cryogenic temperatures in Ni-rich TiNi alloys2016

    • Author(s)
      Kodai Niitsu, Yuta Kimura, Xiao Xu, Toshihiro Omori, Ryosuke Kainuma
    • Organizer
      9th pacific rim international conference on advanced materials and processing (PRICM9)
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      2016-08-01
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Development of Pulse Magnetization System on Aberration Corrected 1.2-MV Cold Field-Emission Transmission Electron Microscope2016

    • Author(s)
      T. Tanigaki, T. Akashi, A. Sugawara, K. Niitsu, X. Yu, Y. Tomioka, D. Shindo, Y. Tokura, H. Shinada
    • Organizer
      Microscopy & Microanalysis 2016 Meeting
    • Place of Presentation
      Columbus, Ohio
    • Year and Date
      2016-07-24
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 1.2 MVホログラフィー電子顕微鏡用パルス磁場印加装置2016

    • Author(s)
      谷垣俊明,明石哲也,菅原昭,新津甲大,于秀珍,富岡泰秀,進藤大輔,十倉好紀,品田博之
    • Organizer
      日本顕微鏡学会第72回学術講演会
    • Place of Presentation
      仙台国際センター(宮城県青葉区)
    • Year and Date
      2016-06-14
    • Related Report
      2015 Annual Research Report
  • [Presentation] 電子線ホログラフィーによる形態を制御した絶縁体の帯電現象と2次電子挙動の観察2016

    • Author(s)
      進藤大輔,築田直也,真柄英之,佐藤隆文,赤瀬善太郎,新津甲大
    • Organizer
      日本顕微鏡学会第72回学術講演会
    • Place of Presentation
      仙台国際センター(宮城県青葉区)
    • Year and Date
      2016-06-14
    • Related Report
      2015 Annual Research Report
  • [Presentation] 非整数のトポロジカル数を持つ電子らせん波の検討2016

    • Author(s)
      原田研,新津甲大,嶌田惠子,進藤大輔
    • Organizer
      日本顕微鏡学会第72回学術講演会
    • Place of Presentation
      仙台国際センター(宮城県青葉区)
    • Year and Date
      2016-06-14
    • Related Report
      2015 Annual Research Report
  • [Presentation] Ni基ホイスラー合金中の逆位相界面における微量偏析と原子配列規則度の原子分解能評価2016

    • Author(s)
      新津甲大,水口知大,許皛,長迫実,大沼郁雄,谷垣俊明,村上恭和,進藤大輔,貝沼亮介
    • Organizer
      日本顕微鏡学会第72回学術講演会
    • Place of Presentation
      仙台国際センター(宮城県青葉区)
    • Year and Date
      2016-06-14
    • Related Report
      2015 Annual Research Report
  • [Presentation] コンタミネーションプリントの直接観察2016

    • Author(s)
      嶌田惠子,新津甲大,勝田禎治,大野輝昭,原田研,進藤大輔
    • Organizer
      日本顕微鏡学会第72回学術講演会
    • Place of Presentation
      仙台国際センター(宮城県青葉区)
    • Year and Date
      2016-06-14
    • Related Report
      2015 Annual Research Report
  • [Presentation] Ti50.0-xNi40.0+xCu10.0合金の低温域における超弾性挙動2016

    • Author(s)
      木村雄太、新津甲大、許皛、大森俊洋、貝沼亮介
    • Organizer
      日本金属学会第158回大会
    • Place of Presentation
      東京理科大学(東京都葛飾区)
    • Year and Date
      2016-03-23
    • Related Report
      2015 Annual Research Report
  • [Presentation] 電子線ホログラフィーによるナノ結晶軟磁性材料の定量的磁場解析の検討2016

    • Author(s)
      木村健太、赤瀬善太郎、進藤大輔、新津甲大、谷垣俊明、Parmanand Sharma、牧野彰宏
    • Organizer
      日本金属学会第158回大会
    • Place of Presentation
      東京理科大学(東京都葛飾区)
    • Year and Date
      2016-03-23
    • Related Report
      2015 Annual Research Report
  • [Presentation] Ni50Mn20In30ホイスラー合金における逆位相界面を介した磁区構造の幾何学的転移2015

    • Author(s)
      新津甲大, 谷垣俊明, 許皛, 村上恭和, 貝沼亮介, 進藤大輔
    • Organizer
      日本金属学会第157回大会
    • Place of Presentation
      九州大学(福岡県福岡市)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] 形状記憶合金の極低温域における超弾性2015

    • Author(s)
      貝沼亮介、新津甲大、許皛、梅津理恵、大森俊洋
    • Organizer
      日本金属学会第157回大会
    • Place of Presentation
      九州大学(福岡県福岡市)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 規則合金に生じた逆位相境界からの磁束密度測定2015

    • Author(s)
      村上恭和、新津甲大、谷垣俊明、貝沼亮介、朴賢洵、進藤大輔
    • Organizer
      日本金属学会第157回大会
    • Place of Presentation
      九州大学(福岡県福岡市)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] 暗視野電子線ホログラフィーを用いたNd2Fe14B結晶粒の歪分布の評価2015

    • Author(s)
      金子修平、村上恭和、新津甲大、赤瀬善太郎、進藤大輔、谷垣俊明、佐々木泰祐、大久保忠勝、宝野和博
    • Organizer
      日本金属学会第157回大会
    • Place of Presentation
      九州大学(福岡県福岡市)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] TEM STUDIES OF STRUCTURE AND MAGNETISM IN THERMALLY-INDUCED ANTIPHASE BOUNDARY2015

    • Author(s)
      Y. Murakami, K. Niitsu, T. Tanigaki, R. Kainuma, H. S. Park, D. Shindo
    • Organizer
      International Conference on Solid-Solid Phase Transformations in Inorganic Materials (PTM2015)
    • Place of Presentation
      Whistler. BC, Canada
    • Year and Date
      2015-06-28
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Electron holography studies on magnetization and lattice strain in Nd-Fe-B permanent magnets2015

    • Author(s)
      Y. Murakami, T. Sasaki, T. Tanigaki, S. Kaneko, K. Niitsu, Z. Akase, D. Shindo, T. Ohkubo, K. Hono
    • Organizer
      ESICMM-G8 Symposium on Next Generation Permanent Magnets
    • Place of Presentation
      Tsukuba, Japan
    • Year and Date
      2015-06-18
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 逆位相境界で増強される強磁性 (Ferromagnetism developed by antiphase boundaries)2015

    • Author(s)
      村上恭和, 新津甲大, 谷垣俊明, 貝沼亮介, 朴賢洵, 進藤大輔
    • Organizer
      日本顕微鏡学会第71回学術講演会
    • Place of Presentation
      国立京都国際会館(京都市左京区)
    • Year and Date
      2015-05-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] 規則合金に生じた逆位相境界からの磁束密度測定2014

    • Author(s)
      村上恭和、新津甲大 、谷垣俊明、貝沼亮介、朴賢洵、進藤大輔
    • Organizer
      日本金属学会秋期(第155回)大会
    • Place of Presentation
      名古屋大学(名古屋市千種区)
    • Year and Date
      2014-09-24
    • Related Report
      2014 Annual Research Report
  • [Presentation] 電子線ホログラフィー によるVO2薄膜の金属 -絶縁体相転移の観察2014

    • Author(s)
      木下晃一、新津甲大、会沢真二 、村上恭和、進藤大輔 、神吉輝夫 、田中秀和
    • Organizer
      日本金属学会秋期(第155回)大会
    • Place of Presentation
      名古屋大学(名古屋市千種区)
    • Year and Date
      2014-09-24
    • Related Report
      2014 Annual Research Report
  • [Patent(Industrial Property Rights)] バイプリズム装置、および荷電粒子線装置2015

    • Inventor(s)
      原田 研、嶌田惠子、新津甲大
    • Industrial Property Rights Holder
      原田 研、嶌田惠子、新津甲大
    • Industrial Property Rights Type
      特許
    • Filing Date
      2015-12-24
    • Related Report
      2015 Annual Research Report

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Published: 2014-09-09   Modified: 2017-05-10  

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