Development of molecular transformation using bichromophoric metal complexes
Project/Area Number |
26893221
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Research Category |
Grant-in-Aid for Research Activity Start-up
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Allocation Type | Single-year Grants |
Research Field |
Chemical pharmacy
|
Research Institution | Gifu Pharmaceutical University |
Principal Investigator |
|
Project Period (FY) |
2014-08-29 – 2016-03-31
|
Project Status |
Completed (Fiscal Year 2015)
|
Budget Amount *help |
¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2015: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2014: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
|
Keywords | 遷移金属触媒 / 光駆動性錯体 / カップリング反応 / 不活性結合の活性化 / 光駆動錯体 / 可視光増感型錯体 / 遷移金属触媒反応 / 有機合成化学 |
Outline of Final Research Achievements |
In this study, we have developed organic reaction especially C-C bond forming reaction using a series of novel visible light sensitizing dinuclear metal complexes. Variety of Ru-Pd dinuclear complexes bearing Ru bipyridyl as a photo sensitizing moiety were synthesized and applied them for the Suzuki-Miyaura coupling reaction. One of the complex show the highest catalytic activity compared to the reported complexes and produced coupling product in high yield under visible light irradiation condition. This result support that this complex works as a converter the photo energy into the chemical energy which we envisioned.
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Report
(3 results)
Research Products
(24 results)