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Molecular Functionalized Electrodes

Research Project

Project/Area Number 59390012
Research Category

Grant-in-Aid for Co-operative Research (A)

Allocation TypeSingle-year Grants
Research Field 広領域
Research InstitutionTokyo Institute of Technology

Principal Investigator

TOKUDA Koichi (1986)  Tokyo Institute of Technology, Associate Professor, 国立大学(その他), 助教授 (40016548)

松田 博明 (1984-1985)  東京工業大学, 教授

Co-Investigator(Kenkyū-buntansha) OYAMA Noboru  Tokyo University of Agriculture and Technology Associate Professor, 工学部, 助教授 (40134845)
FUJIHIRA Masamichi  Tokyo Institute of Technology Professor, 工学部, 教授 (40013536)
NIKI Katsumi  Yokohama National University Professor, 工学部, 教授 (00017899)
SENDA Mitsugi  Kyoto University Professor, 農学部, 教授 (90026419)
MATSUDA Hiroaki  Tokyo University of Agriculture and Technology Part-time Lecturer, 工学部, 非常勤講師 (50016515)
Project Period (FY) 1984 – 1986
Project Status Completed (Fiscal Year 1986)
Budget Amount *help
¥7,100,000 (Direct Cost: ¥7,100,000)
Fiscal Year 1986: ¥400,000 (Direct Cost: ¥400,000)
Fiscal Year 1985: ¥1,800,000 (Direct Cost: ¥1,800,000)
Fiscal Year 1984: ¥4,900,000 (Direct Cost: ¥4,900,000)
Keywordselectrocatalysis / polymer modified electrodes / bioelectrocatalysis / biosensors / redox-electrode reactions of adsorbed species / specular reflection measurement / mediator / 膜
Research Abstract

Researches on molecular functionalized electrodes having specific functionalities have been actively performed with a view to applying these electrodes to electrocatalysis, electroanalysis, selective electro-synthesis, and so on. However, interpretation of basic phenomena at these electrodes are often left untouched because their practical applications are the primary aim of these researches. The present project was undertaken in order to obtain better understandings of the basic problems for molecular functionalized electrodes by the cooperation of rsearchers in various fields, along with the development of these electrodes for practical use. The project members belonged to, at least, one of the following research groups: (1) basic theory, (2) new exploring methods of electrode surfaces, (3) polymer modified electrodes, (4) bioelectrocatalysis, and (5) biosensors, and proceeded to the project and their own work with mutual collaboration and discussion. Some of the results obtained wer … More e presented at the two symposia open to the public on "molecular functionalized electrodes" which were held by this project. The first one was given in Kyoto on November 16, 1985, where four lectures were presented and the second, consisting of eight lectures and a panel discussion, was held in Tokyo on January 30, 1986. Further results are given in the report of the present project. These results include (1) derivation of current-potential equations for surface redox reaction under the effect of interactions of adsorbed species; (2) establishment of applicability of specular reflection measurement to the study of adsorbed layers on glassy carbon electrodes; (3) elucidation of the relation between charge transport within polymer membranes and their structure; (4) elucidations of the role of mediator in glucose oxidase electrode, and that of promoters in the electron transfer reactions of c-type cytochromes at an electrode interface; and (5) development of optical immunosensors and ISFET microbiosensors. Less

Report

(1 results)
  • 1986 Final Research Report Summary
  • Research Products

    (14 results)

All Other

All Publications (14 results)

  • [Publications] M.Aizawa: Anal Lett.17. 555-564 (1984)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1986 Final Research Report Summary
  • [Publications] M.Aizawa: Proc 4th Sensor Symp.197-199 (1984)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1986 Final Research Report Summary
  • [Publications] M.Aizawa: J.Chem.Soc.,Chem.Commun. 1985. 62-63 (1985)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1986 Final Research Report Summary
  • [Publications] Y.Ikariyama: Anal.Chem.57. 496-500 (1985)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1986 Final Research Report Summary
  • [Publications] Y.Ikariyama: Biochem.Biophys.Res.Commun.128. 987-992 (1985)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1986 Final Research Report Summary
  • [Publications] H.Shinohara: J.Chem.Soc,Chem.Commun.1986. 87-88 (1986)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1986 Final Research Report Summary
  • [Publications] 軽部征夫: "バイオセンサー" 共立出版, 116 (1986)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1986 Final Research Report Summary
  • [Publications] 軽部征夫: "ニューバイオテクノロジー エレクトロニクスとの接点" オーム社, 98 (1986)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1986 Final Research Report Summary
  • [Publications] M. Aizawa,: "Photovoltaic Determination of Hydrogen Peroxide with a biophotodiode." Anal. Lett.17. 555-564 (1984)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1986 Final Research Report Summary
  • [Publications] M. Aizawa: "Biophotodiode-Luminexcent Biosensor with Enzyme Membrane and Photodiode." Proc. 4th Sensor Symp.197-199 (1984)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1986 Final Research Report Summary
  • [Publications] M. Aizawa: "Photodoping of Polyacetylene Films." J. Chem. Soc., Chem. Commun.1985. 62-63 (1985)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1986 Final Research Report Summary
  • [Publications] Y. Ikariyama: "Sensitive Bioaffinity Sensor with Metastable Molecular Complex Receptor and Enzyme Amplifier." Anal. Chem.57. 49-500 (1985)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1986 Final Research Report Summary
  • [Publications] Y. Ikariyama: "Electrochemical Luminescence-Based Homogenous Immunassay" Biochem. Biophys Res. Commun.128. 987-992 (1985)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1986 Final Research Report Summary
  • [Publications] Isao Karube: Kyoritsu Shuppan. Biosensors, 196 (1986)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1986 Final Research Report Summary

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Published: 1987-03-31   Modified: 2016-04-21  

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