| Project/Area Number |
59430009
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| Research Category |
Grant-in-Aid for General Scientific Research (A)
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| Allocation Type | Single-year Grants |
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| Research Field |
無機・錯塩・放射化学
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| Research Institution | Ochanomizu University |
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Principal Investigator |
SONE Kozo Prof.; Ochanomizu Univ. (Dept. of Chem.,Fac.of Sci.), 理学部, 教授 (10021908)
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| Co-Investigator(Kenkyū-buntansha) |
MARUYAMA Yusei Prof.; Inst. for Molecular Science, 分子科学研究所, 教授 (40013479)
KOKO Maeda Prof.;Ochanomizu Univ. (Dept.of Chem.,Fac. of Sci.), 理学部, 教授 (40017190)
FUKUDA Yutaka Associate Prof.; Ocaanomizu Univ. (Dept.of Chem.,Fac.of Sci.), 理学部, 助教授 (30021950)
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| Project Period (FY) |
1984 – 1986
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| Project Status |
Completed (Fiscal Year 1986)
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| Budget Amount *help |
¥34,700,000 (Direct Cost: ¥34,700,000)
Fiscal Year 1986: ¥2,000,000 (Direct Cost: ¥2,000,000)
Fiscal Year 1985: ¥6,400,000 (Direct Cost: ¥6,400,000)
Fiscal Year 1984: ¥26,300,000 (Direct Cost: ¥26,300,000)
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| Keywords | Donor-acceptor interaction / ESR / Chelates / Electron transfer / Thermochromism / Intercalation compound / Charge-transfer complex / 層間化合物 / ドナー / アクセプター / 錯体 / 電荷移動 |
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| Research Abstract |
1. Two series of chromotropic copper( <II> ) chelates, i.e.,[Cu <(daco)_2> ] <X_2> (daco = 1,5-diazacyclooctane) which show peculiar thermochromism in solid state and [Cu( <beta> -diketonate)(diamine)]X which are solvatochromic in organic solvents, were studied by means of spectral and ESR techniques. A number of data on the donor-acceptor interactions in these systems were derived from the ESR measurements.
2. Structural influences on (a) the electron transfer reactions of various biacridinium and biquinolinium salts, which occur under the influence of light or high pressure, and (b) the reactivity of cobalt-mesotetraphenylporphyrin with nucleophilic reagents, were studied using ESR technique. The effects of heat, light and pressure on the homolytic cleavage of C-C bonds were also studied, using bis(benzofuranonyl) and related compounds.
3. Black phosphorus was found to form intercalation compounds with iodine and cesium. Their structures and conductivity characteristics were determined. A number of highly conducting charge-transfer complexes with a new acceptor, AzaTCNQ, were also synthesized and studied. The possibility of proton-electron interactions in certain organic molecules, in which intramolecular proton transfer can occur, was also discussed about.
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