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Systematic Studies on the Mechanisms of Refractory Degradation and Metal Impurification in Metallurgical Smelting

Research Project

Project/Area Number 59430012
Research Category

Grant-in-Aid for General Scientific Research (A)

Allocation TypeSingle-year Grants
Research Field 金属精錬・金属化学
Research InstitutionNagoya University

Principal Investigator

SAKAO Hiroshi  Nagoya University, 工学部, 教授 (30022966)

Co-Investigator(Kenkyū-buntansha) FUJISAWA Toshiharu  Nagoya University, 工学部, 助手 (20115629)
WANIBE Yoshimoto  Nagoya University, 工学部, 助教授 (90023150)
Project Period (FY) 1984 – 1986
Project Status Completed (Fiscal Year 1986)
Budget Amount *help
¥34,500,000 (Direct Cost: ¥34,500,000)
Fiscal Year 1986: ¥1,700,000 (Direct Cost: ¥1,700,000)
Fiscal Year 1985: ¥9,200,000 (Direct Cost: ¥9,200,000)
Fiscal Year 1984: ¥23,600,000 (Direct Cost: ¥23,600,000)
KeywordsRefractories / Slagging reactions / Porosity / Pore size distribution / Permeability / Specific surface / Contact angles / 浸透現象 / 耐火れんが / 気孔代表径 / 複合ワイブル分布 / Krの吸着表面積
Research Abstract

There have been many studies concerning refractory linnings and bricks because of the indispensable materials to pyrometallurgy. Much still remains to be done for the quantitative comparison and the generalization of the results. The present work contains an experiment concerning the infiltration of a molten slag into slagging refractory bricks, porous composites, 4 kinds of measurements for the quantitative characterization of the porous properties, and a phenomeno-logical observation about the wetting behavior of the slag onto refractories.
The observations prove the uselessness of the conventional interpretation. The results induce the origination of a new approach to the quantitative description of the slagging capillarity in consideration of both the reactivity and the viscousness of the slag. The new interpretation has been generalized to the unified expressions applicable even for a connected pore system, so that the satisfactory explaination can be presented to the experimental observations in the practical bricks through the results of the various basic measurements. The conclusion, thus, suggests the possibility for the anticipative estimation of the real complicate phenomenon out of the material natures concerned.

Report

(2 results)
  • 1986 Final Research Report Summary
  • 1985 Annual Research Report
  • Research Products

    (16 results)

All Other

All Publications (16 results)

  • [Publications] 横山誠二: 窯業協会誌. 93. 655-660 (1984)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1986 Final Research Report Summary
  • [Publications] Yoshimoto Wanibe: 5th International Iron and Steel Congress,Pro.6th Process Technology Conference. 6. 911-919 (1986)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1986 Final Research Report Summary
  • [Publications] 横山誠二: 鉄と鋼. 73. 297-304 (1987)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1986 Final Research Report Summary
  • [Publications] 横山誠二: 鉄と鋼. 73. 305-312 (1987)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1986 Final Research Report Summary
  • [Publications] 横山誠二: 鉄と鋼. 73. 484-490 (1987)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1986 Final Research Report Summary
  • [Publications] 鰐部吉基: 鉄と鋼. 73. 491-497 (1987)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1986 Final Research Report Summary
  • [Publications] Seiji Yokoyama: "Measurement of Apparent Porosity, Water Absorption and Densities of Refractory Bricks" Journal of the Ceramic Society of Japan. 93. 655-660 (1985)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1986 Final Research Report Summary
  • [Publications] Yoshimoto Wanibe: "Experimental Study on the Infiltration of Molten Slags in Refractory Capillaries and Bricks" 5th International Iron and Steel Congress, Proc. 6th process Technology Conference. 6. 911-919 (1986)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1986 Final Research Report Summary
  • [Publications] Seiji Yokoyama: "Measurement of Pore Sizes and the Distribution in <Al_2> <O_3> -Si <O_2> Bricks by the Mercury Penetration Method" Tetsu-to-Hagane. 73. 297-304 (1987)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1986 Final Research Report Summary
  • [Publications] Seiji Yokoyama: "Differences in Permeations and Surface Areas of <Al_2> <O_3> -Si <O_2> Bricks by Measuring Methods" Tetsu-to-Hagane. 73. 305-312 (1987)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1986 Final Research Report Summary
  • [Publications] Seiji Yokoyama: "Wetting Behavior of Molten FeO-Si <O_2> Slag to <Al_2> <O_3> -Si <O_2> Refractories" Tetsu-to-Hagane. 73. (1987)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1986 Final Research Report Summary
  • [Publications] Yoshimoto Wanibe: "Infiltration of Molten FeO-Si <O_2> Slag into Pores in <Al_2> <O_3> -Si <O_2> Bricks with the Slagging Reaction" Tetsu-to-Hagane. 73. (1987)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1986 Final Research Report Summary
  • [Publications] 窯業協会誌. 93-10. (1985)

    • Related Report
      1985 Annual Research Report
  • [Publications] 第5回国際鉄鋼会議講演概要. (1986)

    • Related Report
      1985 Annual Research Report
  • [Publications] 同上論文集. (1986)

    • Related Report
      1985 Annual Research Report
  • [Publications] 同上論文集. (1986)鉄と鋼.

    • Related Report
      1985 Annual Research Report

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Published: 1987-03-31   Modified: 2016-04-21  

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