KINETIC STUDY ON DEPHOSPHORIZATION REACTION BETWEEN LIME-BASE SLAG AND HIGH CARBON MOLTEN IRON
| Project/Area Number |
59470049
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| Research Category |
Grant-in-Aid for General Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
金属精錬・金属化学
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| Research Institution | NAGOYA UNIVERSITY |
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Principal Investigator |
MORI KAZUMI NAGOYA UNIVERSITY, SCHOOL OF ENGINEERING, PROFESSOR, 工学部, 教授 (10022972)
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| Co-Investigator(Kenkyū-buntansha) |
HIRASAWA MASAHIRO NAGOYA UNIVERSITY, SCHOOL OF ENGINEERING, RESEARCH ASSOCIATE, 工学部, 助手 (90126897)
SANO MASAMICHI NAGOYA UNIVERSITY, SCHOOL OF ENGINEERING, ASSOCIATE PROFESSOR, 工学部, 助教授 (70023174)
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| Project Period (FY) |
1984 – 1986
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| Project Status |
Completed (Fiscal Year 1986)
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| Budget Amount *help |
¥7,900,000 (Direct Cost: ¥7,900,000)
Fiscal Year 1986: ¥1,400,000 (Direct Cost: ¥1,400,000)
Fiscal Year 1985: ¥1,900,000 (Direct Cost: ¥1,900,000)
Fiscal Year 1984: ¥4,600,000 (Direct Cost: ¥4,600,000)
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| Keywords | Hot metal treatment / Activity of slag components / Slag-metal reaction / Dephosphorization reaction / Rephosphorization reaction / Oxygen potential / 物質移動 |
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| Research Abstract |
THE PRESENT STUDY HAS AIMED AT GETTING SCIENTIFIC KNOWLEDGE ON DEPHOSPHORIZATION IN HOT METAL TREATMENT. THE CHARACTERISTIC POINTS IN THIS STUDY ARE: 1)BASE SLAG OF CaO- <Li_2O> - <SiO_2> SYSTEM IS NEWLY USED, AND 2)STIRRING OF THE MELT IS CONTROLLED IN THE EXPERIMENT.
1. KERAMAX ELECTRIC FURNACE IS NEWLY EQUIPPED. WITH USING THIS FURNACE, CONTROL OF TEMPERATURE AND ATMOSPHERE WERE EASILY PERFORMED. 2. MEASUREMENTS WERE MADE ON SILICA ACTIVITY, ACTIVITY OF FeO ADDED AS THE REACTION COMPONENT, AND PHOSPHATE CAPACITY OF THE BASE SLAG. THESE HAVE PROVIDED USEFUL INFORMATION ON FUNDAMENTAL PROPERTIES OF BASE SLAG SYSTEM. 3. STUDIES HAVE BEEN MADE ON THE RATE OF DEPHOSPHORIZATION REACTION OF HIGH CARBON MOLTEN IRON WITH FeO-CONTAINING SLAGS. IT WAS CLEARLY SHOWN THAT DURING THE REACTION A CHANGE FROM DEPHOSPHORIZATION TO REPHOSPHORIZATION OCCURRED. REACTION MECHANISM OF DEPHOSPHORIZATION IS EXAMINED ON THE BASIS OF REACTION MODEL. 4. WITH VARIATION OF THE STARTING PHOSPHORUS CONCENTRATIONS I
… More
N METAL AND SLAG, VARIOUS REACTIONS RANGED FROM DEPHOSPHORIZATION TO REPHOSPHORIZATION WERE PERFORMED. FROM THE DATA IN QUASI-EQUILIBRIUM STATE, VALUES OF OXYGEN POTENTIAL AT THE SLAG-METAL INTERFACE IS OBTAINED. 5. TO OBTAIN USEFUL INFORMATION ON CLARIFYING THE MECHANISM OF DEPHOSPHORIZATION, KINETIC STUDIES HAVE BEEN MADE ON SILICON OXIDATION IN SLAG-METAL SYSTEM. FROM THE STUDY, THE EFFECTS OF STIRRING IN THE METAL AND SLAG PHASES AND CO EVOLUTION AT THE SLAG-METAL INTERFACE ARE CLARIFIED. ON THE BASIS OF A REACTION MODEL, THE OXYGEN POTENTIAL AT THE SLAG-METAL INTERFACE DURING SILICON OXIDATION IS ESTIMATED. THIS WOULD PROVIDE FUNDAMENTAL DATA ON ESTABLISHING THE STRICT DEPHOSPHORIZATION REACTION MODEL. 6. FURTHER STUDIES ARE BEING PLANNED AS NEW RESEARCH PROJECTS ON 1)DEVELOPING STRICT REACTION MODEL WHICH COULD EXPLAIN THEORETICALLY THE RELATIONSHIP BETWEEN VARIOUS REACTIONS OCCURRING BETWEEN SLAG AND METAL AND 2)ELUCIDATING THE EFFECT OF THE BEHAVIOR OF FERRIC OXIDE ON DEPHOSPHORIZATION. Less
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Report
(1 results)
Research Products
(6 results)
