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Structure and electronic state of thin organic films grown on metals

Research Project

Project/Area Number 60470009
Research Category

Grant-in-Aid for General Scientific Research (B)

Allocation TypeSingle-year Grants
Research Field 物理化学一般
Research InstitutionKyoto University

Principal Investigator

UYEDA Natsu  Prof. Institute for Chemical Research,Kyoto university., 化学研究所, 教授 (20027014)

Co-Investigator(Kenkyū-buntansha) FUJIYOSHI Y.  Res.Ass. Inst.Chem.Res.,Kyoto Univ., 化学研究所, 助手 (80142298)
ISHIZUKA K.  Res.Ass. Inst.Chem.Res.,Kyoto Univ., 化学研究所, 助手 (40135596)
KOBAYASHI T.  Assoc.Prof. Inst.Chem.Res.,Kyoto Univ., 化学研究所, 助教授 (50027059)
Project Period (FY) 1985 – 1986
Project Status Completed (Fiscal Year 1986)
Budget Amount *help
¥7,000,000 (Direct Cost: ¥7,000,000)
Fiscal Year 1986: ¥400,000 (Direct Cost: ¥400,000)
Fiscal Year 1985: ¥6,600,000 (Direct Cost: ¥6,600,000)
KeywordsOrganic thin film / LB-film / Structure / Epitaxial growth / Electron microscopy / Graphite intercalation compound / EELS / プラズモンロス
Research Abstract

Very thin films of various kinds of metal phthalocyanines and T.C.N.Q.,which have some functions such as high conductivity or switching phenomena, were made on noble metal films of gold,silver and copper and investigated crystallographically to reveal the interaction at their interfaces. According to a combination of metal and organic films they were classified into the following three groupes.
(1)Very strong interaction acts at the interface. In some cases, charge transfer occurred and ionized metal diffused into the organic films.
(2)Fairly strong interaction acts at only the early state of the film growth and it controlled the orientation of molecules or atoms on the interface. Accordingly the film grew epitaxially and a definite axial relations were observed between the films. (3)No strong interaction has been observed . Each film grew independently.
Organic films made by Langmuir-Blodgett method have also been studied by electron microscopy. Dark field images revealed that the LB-films of some fatty acids as well a soluble metal phthalocyanine,(t-Buthyl) <_4CuPc> , were porous and nonuniform in structures. Two dimensional structure of graphite intercalated compounds have been analyzed by electron microscopy and electron energy loss spectroscopy(EELS).
The intercalants of acetic acid with chromium trioxide and benzene with pottasium were observed in staging in high resolution electron micrographs.

Report

(1 results)
  • 1986 Final Research Report Summary
  • Research Products

    (11 results)

All Other

All Publications (11 results)

  • [Publications] N.Uyeda: Molecular Crystal and Liquid Crystal.25. 103-112 (1985)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1986 Final Research Report Summary
  • [Publications] K.Yase: Bulletin of the Institute for Chemical Research,Kyoto University. 63. 383-392 (1985)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1986 Final Research Report Summary
  • [Publications] N.Uyeda: Dyes and Pigment. 6. 115-125 (1985)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1986 Final Research Report Summary
  • [Publications] H.Kasano: Bulletin of the Instaitute for Chemical Research,Kyoto University. 63. 216-226 (1985)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1986 Final Research Report Summary
  • [Publications] T.Kobayashi: Journal of the Physical Chemistry. 90. 2231-2236 (1986)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1986 Final Research Report Summary
  • [Publications] H.Kurata: Synthetic Metals. (1987)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1986 Final Research Report Summary
  • [Publications] N.Uyeda: "Direct molecularimaging of low dimensional solid by high resolution electron microscopy." Molecular Crystals and Liquid Crystals.25. 103-112 (1985)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1986 Final Research Report Summary
  • [Publications] K.Yase: "Direct observation of disorders of molecular stacking in Pt-phthalocyanine epitaxial films." Bull.Inst.Chem.Res.,Kyoto Univ.63. 383-392 (1985)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1986 Final Research Report Summary
  • [Publications] N.Uyeda: "Direct imaging of organic molecules in crystal by high resolution electron microscopy at atomic resolution." Dyes and Pigment. 6. 115-134 (1985)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1986 Final Research Report Summary
  • [Publications] H.Kasano: "An application of EELS to the study of residual aluminum in Raney nickel catalyst." Bull.Inst.Chem.Res.,Kyoto Univ.63. 216-226 (1985)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1986 Final Research Report Summary
  • [Publications] T.Kobayashi: "Structure and growth mechanism of <CrO_3> <CH_3> COOH intercalated graphite." J.Phys.Chem.90. 2231-2236 (1986)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1986 Final Research Report Summary

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Published: 1987-03-31   Modified: 2016-04-21  

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