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Development of New Complex Catalyst System for the Utilization of Carbon Monoxide

Research Project

Project/Area Number 60470088
Research Category

Grant-in-Aid for General Scientific Research (B)

Allocation TypeSingle-year Grants
Research Field 有機工業化学
Research InstitutionOsaka University

Principal Investigator

MURAI Shinji  Osaka Univ., 工学部, 助教授 (00029050)

Co-Investigator(Kenkyū-buntansha) KAMBE Nobuaki  Osaka Univ., 工学部, 助手 (60144432)
MIYOSHI Noritaka  Osaka Univ., 工学部, 助手 (80157700)
Project Period (FY) 1985 – 1986
Project Status Completed (Fiscal Year 1986)
Budget Amount *help
¥5,500,000 (Direct Cost: ¥5,500,000)
Fiscal Year 1986: ¥1,400,000 (Direct Cost: ¥1,400,000)
Fiscal Year 1985: ¥4,100,000 (Direct Cost: ¥4,100,000)
KeywordsMetal-metal bond / 異元素間結合 / カルボニル化触媒
Research Abstract

The purpose of this project has been to develop the new and efficient catalytic system for the utilization of carbon monoxide that is the one of the most important raw material of the comming industry.
The basic design of the developing new catalyst is based on the possible unique reactivity of metal complexes having a common element and transition metal bond. Such metal-metal bonded complexes has been expected to exibit the enhanced reactivity of the common element toward specific sites in the organic substrates, these forcing the bond formation between the specific sites in the molecule with the transition metal moiety. This new concept has been revealed to be very much successful and various type of novel catalytic reactions that enables incorporation of carbon monoxide has been found.

Report

(1 results)
  • 1986 Final Research Report Summary
  • Research Products

    (8 results)

All Other

All Publications (8 results)

  • [Publications] 村井真二: J.Am.Chem.Soc.108. 7361-7373 (1986)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1986 Final Research Report Summary
  • [Publications] 村井真二: Organometallics. 6. 212-213 (1987)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1986 Final Research Report Summary
  • [Publications] 神戸宣明: Chem.Lett.269-272 (1987)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1986 Final Research Report Summary
  • [Publications] 村井真二: J.Molecular Catalysis.

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1986 Final Research Report Summary
  • [Publications] Murai, Shinji: ""Cobalt Carbonyl Catalyzed Reactions of Lactones with Hydrosilane and Carbon Monoxide. A Novel Synthetic Method for the Introduction of the Siloxymethylidene Group"" J. Am. Chem. Soc.108. 7361-7373 (1986)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1986 Final Research Report Summary
  • [Publications] Murai, Shinji: ""Desilylative Chlorostannation of Silylmethyl-Substituted Cyclopropanes by <SnCl_4> to Give 3-Butenyltrichlorostannanes. An Entry to Homoallylmetal Compounds"" Organometallics. 6. 212-213 (1987)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1986 Final Research Report Summary
  • [Publications] Kambe, Nobuaki: ""Oxidation of Olefins with Benzenetellurinic Anhydride"" Chem. Lett.269-272 (1987)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1986 Final Research Report Summary
  • [Publications] Murai, Shinji: ""Silylcobalt Carbonyl and New Catalytic Reactions"" J. Molecular Catalysis,. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1986 Final Research Report Summary

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Published: 1987-03-31   Modified: 2016-04-21  

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