Project/Area Number |
60550562
|
Research Category |
Grant-in-Aid for General Scientific Research (C)
|
Allocation Type | Single-year Grants |
Research Field |
工業物理化学
|
Research Institution | Ibaraki University |
Principal Investigator |
OKAZAKI Susumu Ibaraki University, 工学部, 教授 (60007599)
|
Co-Investigator(Kenkyū-buntansha) |
MOMOSE Yoshihiro Ibaraki University, 工学部, 助教授 (10006314)
|
Project Period (FY) |
1985 – 1986
|
Project Status |
Completed (Fiscal Year 1986)
|
Budget Amount *help |
¥1,900,000 (Direct Cost: ¥1,900,000)
Fiscal Year 1986: ¥400,000 (Direct Cost: ¥400,000)
Fiscal Year 1985: ¥1,500,000 (Direct Cost: ¥1,500,000)
|
Keywords | Ceramics / Silica / Fluorination / Plasma / Hydrophobic / Lipophobic / 表面改質 |
Research Abstract |
In order to obtain some information regarding the preparation of fluorinated ceramics, <SiO_2> powder calcinated at high temperatures(1000-1500゜C) was treated with gaseous chlorofluoromethanes or <CF_4> at 450-550゜C in a closed circulation system. In addition, <CF_4> -plasma treatment was applied to the same <SiO_2> sample to perform an intensive surface fluorination. The treatments at 550゜C showed the order of the fluorination activity as following, <CCl_3F> (4.2) > <CCl_2F_2> (2.5) > <CClF_3> (0.3) > <CF_4> (0). (Here, the numbers in parentheses designate F content(%) in the surface layer of the treated <SiO_2> sample.) The F content in the surface layer of the <CCl_3F> -treated <SiO_2> increased linearly from 1.5 to 4.2% with an increase in the treatment temperature. Whereas, <SiF_4> -formation became remarkable at temperatures higher than 600゜C. The surface OH groups completely disappeared and Si-F bond appeared after the <CCl_3F> -treatment at 500゜C. The Cl component was not found for all the flon-treated sample. The adsorptive activities of <SiO_2> for water and hexane decreased with the <CCl_3F> -treatment, suggesting that the <SiO_2> surface became more hydro- and lipo-phobic with the treatment. The <CF_4> -plasma treatment was more effective for the more intensive fluorination of <SiO_2> surface. Thus, an atomic ratio of the treated <SiO_2> attained about 0.75 after the <CF_4> (0.5 Torr)-plasma treatment for 10 min.
|