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Basic Research on the Minerals Related to High-Level Radioactive Wastes.

Research Project

Project/Area Number 61430015
Research Category

Grant-in-Aid for General Scientific Research (A)

Allocation TypeSingle-year Grants
Research Field 鉱物学(含岩石・鉱床学)
Research InstitutionUniversity of Tokyo

Principal Investigator

TOKONAMI Masayasu  Univ. of Tokyo, Fac. of Science Professor, 理学部, 教授 (80029850)

Co-Investigator(Kenkyū-buntansha) TOYODA Kazuhiro  Univ. of Tokyo, Fac. of Science Research Assoc., 理学部, 助手 (10207649)
HAGA Nobuhiko  Univ. of Tokyo, Fac. of Science Research Assoc., 理学部, 助手 (60011748)
OZAWA Tohru  Univ. of Tokyo, Fac. of Science Lecturer, 理学部, 講師 (00011651)
HORIUCHI Hiroyuki  Univ. of Tokyo, Fac. of Science Associate Prof., 理学部, 助教授 (80029892)
山中 高光  大阪大学, 教養部, 講師 (30011729)
Project Period (FY) 1986 – 1989
Project Status Completed (Fiscal Year 1989)
Budget Amount *help
¥19,000,000 (Direct Cost: ¥19,000,000)
Fiscal Year 1989: ¥1,000,000 (Direct Cost: ¥1,000,000)
Fiscal Year 1988: ¥2,000,000 (Direct Cost: ¥2,000,000)
Fiscal Year 1987: ¥4,000,000 (Direct Cost: ¥4,000,000)
Fiscal Year 1986: ¥12,000,000 (Direct Cost: ¥12,000,000)
KeywordsRadioactive wastes / Microarea X-ray Diffractometer / Radioactive Minerals / STRIPA Project / Weathering / Microtexture / 稀土類元素 / カ-ボナタイト / 稀土類鉱物
Research Abstract

High-level radioactive wastes unavoidably remain whenever the used nuclear fuels are reprocessed for the next effective use. These wastes must be kept away from human being and animals in safety for a very long period. Thus, the search of the best way of their disposal is an emergency subject for the use of atomic energy. Most of researches on this problem are performed from technological point of view, however, basic researches of wasted substances are not strongly promoted.
In this project, microtextures of minerals which are related to radioactive wastes are mainly investigated because such textures might be observed for the radioactive wastes after a geologically long period. In order to study microtextures, we investigated radioactive minerals or rare-earth minerals which are thought as analogues to show a future's feature for the radioactive wastes. As a result, behaviors of the process of transfer, concentration, substitution of various atoms will be clarified.
Main contents which … More we contributed to these subjects are; (1) Developments of Microarea X-ray Diffractometer : Conventional microarea X-ray diffractometer is only available to take powder diffraction pattern of such a small area as 50mum, and it is difficult to get a crystallographic information from smaller area than that. We could get a crystallographic information from 10mum area by single crystal diffraction technique by making a control of a specially designed X-ray gonioneter combined with a developed soft-ware system. By this technique, it will become possible to identify small minerals and to analyze orientation relationship among minerals. (2) Many of rare-earth minerals which are obtained from alkali-carbonatite complexes of Brazil are studied on mineral assemblage, textures, weathering, element concentration etc. by means of X-ray diffraction, scanning microscopy, photon activation analysis and so on. These results will be available to expect the change of rocks around radioactive wastes. (3) International collaboration with overseas scientists in order to discuss geological environments for disposal of radioactive wastes. Tokonami contributed to potentially useful materials for sealing cracks of rocks. Less

Report

(5 results)
  • 1989 Annual Research Report   Final Research Report Summary
  • 1988 Annual Research Report
  • 1987 Annual Research Report
  • 1986 Annual Research Report
  • Research Products

    (70 results)

All Other

All Publications (70 results)

  • [Publications] 床次正安: "精密X線回折" 表面科学. 7. 45-51 (1986)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] 床次正安: "鉱物学" 表面科学. 7. 117-120 (1986)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] 吉朝朗: "Structure of Sr_4 Fe_6 O_<13>,a new perovskite-derivative in the Sr-Fe-O system" Material Research Bulletin. 21. 175-181 (1986)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] 遠藤将一: "High temperature X-ray study of single crystal stishovite synthesized with Li_2 WO_4 as flux" Phys.and Chem.Minerals. 13. 146-151 (1986)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] Arthur J.Schultz: "Time-of-flight single-crystal neutron and X-ray diffraction study of K_<0.26> WO_3" Acta Crystallogr.C42. 641-644 (1986)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] W.Coons: "State-of-the-art report on potentially useful materials for sealing nuclear waste repositories." SKB Technical Report. 87-12. 1-164 (1987)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] 澤田晴朗: "The crystal structure of senandorite(andorite VI):PbAgSb_3S_6" Zeit.Kristallogr.180. 141-150 (1987)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] 杉山和正: "Structure and crystal chemistry of a dense polymorph of tricalcium phosphate Ca_3(PO_4)_2:A host to accomodate large lithophile elements in the earth's mantle." Phys.Chem.Minerals. 15. 125-130 (1987)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] 福田功一郎: "Dependence of exsolution textures in synthetic augite on its composition and cooling rate." Mineralogical Journal. 13. 376-389 (1987)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] 相川信之: "Crystal structure and cation distribution of“cleavable"olivines." Mineralogical Journal. 13. 271-279 (1987)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] 堀内弘之: "MgSiO_3(perovskite-type):Single-crystal X-ray diffraction study." Amer.Mineral.72. 357-360 (1987)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] 寿山竜之: "Structural refinements of ZrO_2 and HfO_2 treated at 600℃・6GPa." 窯業協会誌. 95. 567-568 (1987)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] 吉朝朗: "Anharmonic thermal vibrations in wurtzite-type Ag I." Acta Crystallogr.B43. 434-440 (1987)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] 葉金花: "Structure study on the single crystal of Cu-Al-Ni γ_1 martensite phase." Photon Factory Activity Report. 7. 198 (1987)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] G.Artioli: "A single crystal diffraction study of the natural zeorite cowlesite." Photon Factory Activity Report. 7. 316 (1987)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] 丸茂文幸: "Diffractometer for Synchrotron radiation structural studies of high temperature melts" Review of Scientific Instruments. 60. 2421-2424 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] 小澤徹: "X-ray diffraction study of some sulfosalts in the Riester-Minami mineral collection." In“Riester-Minami mineral collection"issued from Univ.Musium of Univ.TOKYO. 1-272 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] 豊田和弘: "機器光量子放射化分析法による標準岩石試料及びカ-ボナタイト風化土壌試料の分析" 核理研研究報告. 22. 117-122 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] 葉金花: "Structure of V_2Sn_2Ga" Acta Crystallogr.C.(印刷中).

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] 葉金花: "Structure of Ta_5SnGa_2" Acta Crystallogr.C.(印刷中).

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] 堀内弘之: "Crystal structures of mantle minerals and their implications for phase transition at high pressures" In“Dynamic Processes of Material Transport and Transformation in the Earth's Interior"(F.Marumo Ed.)(印刷中).

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] 豊田和弘: "Rare earth elements zoning in fish teeth from deep-sea sediments." Nature(投稿中).

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] 芳賀信彦: "A high temperature neutron diffraction study of the anharmonicity and structural instability below the orth-proto phase transition in enstatite,Mg_2Si_2O_6 and a latiice dynamicnl model." Acta Crystallogr.(投稿予定).

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] TOKONAMI,M.: "Precise X-ray Diffraction" Hyomen Kagaku. 7. 45-51 (1986)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] TOKONAMI,M.: "Mineralogy" Hyomen Kagaku 7 117-120 1986.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] YOSHIASA,A.: "Structure of Sr_4Fe_6O_<13>, a new perovskite-derivative in the Sr-Fe-O system." Mat. Res. Bull. 21 175-181 1986.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] ENDO,S.: "High temperature X-ray study of single crystal stishovite synthesized with Li_2WO_4 as flux." Phys.Chem.Minerals 13 146-151 1986.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] SCHULTZ,A.J.: "Time-of-flight single-crystal neutron and X-ray diffraction study of K_<0.26>WO_3." Acta Crystallogr. C42 641-644 1986.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] COONS,W.: "State-of-the-art report on potentially useful materials for sealing nuclear waste repositories." SKB Technical Rep. 87-12 1-164 1987.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] SAWADA,H.: "The crystal structure of senandorite(andorite VI):PbAgSb_3S_6." Zeit.Kristallogr. 180 141-150 1987.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] SUGIYAMA,K.: "Structure and crystal chemistry of a dense polymorph of tricalcium phosphate Ca_3(PO_4)_2:A host to accommodate large lithophile elements in the earth's mantle." Phys.Chem.Minerals 15 125-130 1987.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] FUKUDA,K.: "Dependence of exsolution textures in synthetic augite on its composition and cooling rate." Mineral. Journal 13 376-389 1987.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] AIKAWA,N.: "Crystal structure and cation distribution of "cleavable" olivines." Mineral. Journal 13 271-279 1987.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] HORIUCHI,H.: "MgSiO_3(perovskite-type);Single-crystal X-ray diffraction Study." Amer. Mineral. 72 357-360 1987.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] SUYAMA,R.: "Structural refinements of ZrO_2 and HfO_2 treated at 600C・6GPa." Yogyo-Kyokai-Shi 95 567-568 1987.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] YOSHIASA,A.: "Anharmonic thermal vibrations in wurtzite-type Agl." Acta Crystallogr. B43 434-440 1987.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] YE,J.: "Structure study on the single crystal of Cu-Al-Ni gamma_1' martensite phase." Photon Fac. Act. Rep. 7 198 1987.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] ARTIOLI,G.: "A single crystal diffraction study of the natural zeolite cowlesite." Photon Fac. Act. Rep. 7 316 1987.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] MARUMO,F.: "Diffractometer for synchrotron radiation structural studies of high temperature melts." Rev. Sci. Instr. 60 2421-2424 1989.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] OZAWA,T.: "X-ray diffraction study of some sulfosalts in the Riester-Minami mineral collection." Issued from Univ. Museum of Univ. Tokyo, 1-272 1989.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] TOYODA,K.: "Analysis of standard rocks and weathered carbonatites by a photon activation method." Kakuriken Rep. 22 117-122 1989.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] YE,J.: "Structure of V_2Sn_2Ga." Acta Crystallogr. C.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] YE,J.: "Structure of Ta_5SnGa_2." Acta Crystallogr. C.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] HORIUCHI,H.: "Crystal structure of mantle minerals and their implications for phase transition at high pressures." "Dynamic Processes of Material Transport and Transformation in the Earth's Interior".

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] TOYODA,K.: "Rare earth elements zoning in fish teeth from deepsea sediments." Nature.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] HAGA,N.: "A high temperature neutron diffraction study of the anharmonicity and structural instability below the ortho-proto phase transition in enstatite, Mg_2Si_2O_6 and a lattice dynamical model." Acta Cryatallogr. B.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] 堀内弘之: "Crystal structure of Mantle Minerals and Their Implications for Phase Transition At High Pressure" in“Dynamical Process of Material Transport and Transformation in the Earth′s Interior"(予定). 191-217 (1990)

    • Related Report
      1989 Annual Research Report
  • [Publications] 田中雅彦: "微小領域X線回折による鉱物組織の研究" 日本結晶学会講演要旨集. PA18-PA18 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] 豊田和弘: "機器光量子放射化分析法による標準岩石試料及びカ-ボナタイト風化土壌試料の分析" 核理研研究報告. 22. 117-122 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] 小澤徹: "ブラジル南部、カ-ボナタイト地域産の磁鉄鉱の研究" 日本鉱物学会講演要旨集. PA18-PA18 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] 芳賀信彦: "Arax′a(ブラジル)におけるカ-ボナタイトの構成鉱物" 日本鉱物学会講演要旨集. PB17-PB17 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] 豊田和弘: "Rare Earth Elements Zoning in Fish Teeth from Deepーsea Sediments" Nature. (1990)

    • Related Report
      1989 Annual Research Report
  • [Publications] 床次正安: 日本鉱物学会講演要旨集. 101-101 (1988)

    • Related Report
      1988 Annual Research Report
  • [Publications] 堀内弘之: 日本鉱山地質・日本岩石鉱物鉱床・日本鉱物学会連合学会(三鉱学会)講演要旨集. 104-104 (1988)

    • Related Report
      1988 Annual Research Report
  • [Publications] 小澤徹: 日本鉱物学会講演要旨集. 102-102 (1988)

    • Related Report
      1988 Annual Research Report
  • [Publications] 芳賀信彦: 日本鉱山地質・日本岩石鉱物鉱床・日本鉱物学会連合学会(三鉱学会)講演要旨集. 130-130 (1988)

    • Related Report
      1988 Annual Research Report
  • [Publications] 豊田和弘: 日本鉱山地質・日本岩石鉱物鉱床・日本鉱物学会連合学会(三鉱学会)講演要旨集. 44-44 (1988)

    • Related Report
      1988 Annual Research Report
  • [Publications] 田中雅彦: 日本結晶学会講演要旨集. 71-71 (1988)

    • Related Report
      1988 Annual Research Report
  • [Publications] 床次 正安: Acta Crystallographica. A43. C147-C147 (1987)

    • Related Report
      1987 Annual Research Report
  • [Publications] 床次 正安: 表面科学. 7. 45-51 (1986)

    • Related Report
      1987 Annual Research Report
  • [Publications] 床次 正安: 表面科学. 7. 117-120 (1987)

    • Related Report
      1987 Annual Research Report
  • [Publications] 堀内 弘之: Amcrican Minecalogirts. 72. 357-360 (1987)

    • Related Report
      1987 Annual Research Report
  • [Publications] Arthur J. Schultz: Acta Crystallographica. C42. 641-644 (1986)

    • Related Report
      1987 Annual Research Report
  • [Publications] 芳賀 信彦: Acta Chrystallographica. A43. C83-C83 (1987)

    • Related Report
      1987 Annual Research Report
  • [Publications] 床次正安: 表面科学. 7. 45-51 (1986)

    • Related Report
      1986 Annual Research Report
  • [Publications] 床次正安: 表面科学. 7. 117-120 (1986)

    • Related Report
      1986 Annual Research Report
  • [Publications] 堀内弘之: American Mineralogist. (1987)

    • Related Report
      1986 Annual Research Report
  • [Publications] 吉朝朗: Material,Research Bulletin. 21. 175-181 (1986)

    • Related Report
      1986 Annual Research Report
  • [Publications] 山中高光: Pyhs.Chem.Minerals. 13. 156-160 (1986)

    • Related Report
      1986 Annual Research Report
  • [Publications] 山中高光: Phys.Chem.Minerals. 13. 227-232 (1986)

    • Related Report
      1986 Annual Research Report

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Published: 1987-03-31   Modified: 2016-04-21  

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