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Studies on Purification and Separation of Multicomponent Mixtures by Use of Surface-Modified Adsorbents

Research Project

Project/Area Number 61430023
Research Category

Grant-in-Aid for General Scientific Research (A)

Allocation TypeSingle-year Grants
Research Field 化学工学
Research InstitutionMeiji University

Principal Investigator

TAKEUCHI Yasushi  Dept.of Ind.Chem.,Meiji University, 工学部, 教授 (70061827)

Co-Investigator(Kenkyū-buntansha) SUZUKI Takashi  Dept.of Applied Chemistry,Yamanashi University, 工学部, 教授 (60020385)
SUZUKI Yoshitake  Dept.of Ind.Chem.,Meiji University, 工学部, 専任助手 (20163024)
FURUYA Eiji  Dept.of Ind.Chem.,Meiji University, 工学部, 専任講師 (90130830)
CHIHARA Kazuyuki  Dept.of Ind.Chem.,Meiji University, 工学部, 助教授 (80111566)
Project Period (FY) 1986 – 1988
Project Status Completed (Fiscal Year 1988)
Budget Amount *help
¥15,000,000 (Direct Cost: ¥15,000,000)
Fiscal Year 1988: ¥1,000,000 (Direct Cost: ¥1,000,000)
Fiscal Year 1987: ¥3,000,000 (Direct Cost: ¥3,000,000)
Fiscal Year 1986: ¥11,000,000 (Direct Cost: ¥11,000,000)
KeywordsSurface-modified adsorbent / Chemicals-deposited carbon / Odor removal / CVD / Molecular sieving carbon of micropore-control / Resin adsorbent, Ion-substituted Hydroxyapatite / イオン置換ハイドロキシアパタイト / 吸着分離 / イオン置換ハイドロキレアパタイト / 吸親樹脂 / テリハロメタン除去 / イオン交換アパタイト / 吸着速度制御 / 重金属イオン除去 / 添着活性炭 / ハイドロキシアパタイト / 多成分系吸着 / 固定層吸着 / 回分撹拌槽吸着
Research Abstract

Modification of commercially-available adsorbents with respect to their surface characters and/or micropore structures was studied aiming at achievement of better adsorptive separation of trace component as well as bulk separation and further presentation of design methods for such cases. (1) Removal of odoring gases, e.g., hydrogen sulfide, methyl mercaptan and trimethylamine from air was studied by fixed bed of chemicals-deposited carbon to obtain equili-brium and kinetic data. (2) Chemical vapor deposition (CVD) technique was applied to adjust commercial molecular-sieving carbon in its micropore sizes thus achie-ving higher performance in air separation by pressure swing adsorption. (3) Resin adsorbents were treated to show enough capacity for the separation of amino-acids. (4) Hydroxyapatite powder was used to remove divalent heavy metal ions from water and equilibrium and kinetic data were obtained for agitated-tank and fixed-bed treatment. From these results, some design criteria were established.

Report

(4 results)
  • 1988 Annual Research Report   Final Research Report Summary
  • 1987 Annual Research Report
  • 1986 Annual Research Report
  • Research Products

    (32 results)

All Other

All Publications (32 results)

  • [Publications] 三宅通博,長山洋治,後藤敦,鈴木喬: 日本化学会誌. 1988. 635-369 (1988)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1988 Final Research Report Summary
  • [Publications] 谷沢善明,鈴木喬: 電気化学. 56. 864-869 (1988)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1988 Final Research Report Summary
  • [Publications] 竹内雍,新井啓哲,鈴木喬,鈴木義丈: Jouronal of Chem.Eng.Japan. 22. tobeappeared (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1988 Final Research Report Summary
  • [Publications] 鈴木基之,茅原一之: Water Research. 22. 627-633 (1988)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1988 Final Research Report Summary
  • [Publications] 茅原一之,松田秀行,左近淑人,鈴木基之,竹内雍: Carbon.

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1988 Final Research Report Summary
  • [Publications] 竹内雍,水谷弘孝,池田浩: Journal of Chemical Eng.Japan. 22. (received) (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1988 Final Research Report Summary
  • [Publications] 猪狩俶将 監修竹内雍 他: "新しい消臭剤・工業用脱臭剤の開発と新製品化へのアプローチ「18章添着活性炭による悪臭成分の除去」" 技術情報協会, 480 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1988 Final Research Report Summary
  • [Publications] Ikeda, H.; Y. Takeuchi: "Removal of H_2S, CH_3SH, and (CH_3)_3N from Air by Use of Chemically-treated Activated Carbon" Journal of Chemical Engineering of Japan. 21. 91-97 (1988)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1988 Final Research Report Summary
  • [Publications] Suzuki, M.; K. Chihara: "Heterogeneous Coagulation of Organic Colloid and Powdered Activated Carbon" Water Research. 22. 627-633 (1988)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1988 Final Research Report Summary
  • [Publications] Takeuchi, Y.; H. Arai; Y. Suzuki; T. Suzuki: "Removal of Coexisting Pb^<2+>, Cu^<2+> and Cd^<2+> from Water by the Addition of Hydroxyapatite" Journal of Chemical Engineering of Japan. 22. (1989)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1988 Final Research Report Summary
  • [Publications] Miyake, M; N. Nagayama; A. Goto; T. Suzuki: "Cation-Exchange Characteristics of Synthetic Hydroxyapatites for Zn^<2+>' Cd^<2+> and Hg^<2+> Ions" Nippon Kagaku Kaishi (Journal of the Chemical Society of Japan, Chemistry and Industrial Chemistry). 1988. 635-639 (1988)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1988 Final Research Report Summary
  • [Publications] Takeuchi, Y.; M. Mizutani; H. Ikeda: "Studies on Prevention of Carbon Bed Ignition and Degradation during Adsorption and Desorption Processes of Cyclohexanone in Relation to Solvent Recovery" Journal of Chemical Engineering Japan. 22. (1989)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1988 Final Research Report Summary
  • [Publications] Soc. of Chem. Eng., Japan (ed.); Yasushi Takeuchi et al., (Chapter 12): Kagaku Kogaku Benran (Chemical Engineering Handbook). Maruzen Corp., 1400 (1988)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1988 Final Research Report Summary
  • [Publications] 三宅通博、長山洋治、後藤敦、鈴木喬: 日本化学会誌. 1988. 635-639 (1988)

    • Related Report
      1988 Annual Research Report
  • [Publications] 谷沢善明、鈴木喬: 電気化学. 56ー1988. (864-869)

    • Related Report
      1988 Annual Research Report
  • [Publications] 竹内雍、新井啓哲、鈴木喬、鈴木義丈: Jouronal of Eng Japan. 22. (1989)

    • Related Report
      1988 Annual Research Report
  • [Publications] 鈴木基之、茅原一之: Water Research. 22. 627-633 (1988)

    • Related Report
      1988 Annual Research Report
  • [Publications] 茅原一之、松田秀行、左近淑人、鈴木基之、竹内雍: Carbon.

    • Related Report
      1988 Annual Research Report
  • [Publications] 竹内雍、水谷昌孝、池田浩: Journal of Chemical Eng.Japan. 22. (1989)

    • Related Report
      1988 Annual Research Report
  • [Publications] 猪狩俶将(監修)竹内雍ほか: "新しい消臭剤・工業用脱臭剤の開発と新製品化へのアプローチ18章添着活性炭による悪臭成分の除去" 技術情報協会, 480-( 6ページ) (1989)

    • Related Report
      1988 Annual Research Report
  • [Publications] Takeuchi, Yasuhi; Ikeda, Hiroshi; Asaba, Hidiki: Proc.of the 15th Australasian Chemical Engineering Conference. 1. 28.1-28.8 (1987)

    • Related Report
      1987 Annual Research Report
  • [Publications] Furuya, Eiji; Takeuchi, Yasushi: Proc. of the 1st Korea-Japan Symposium on Separation Process Technology. 467-470 (1987)

    • Related Report
      1987 Annual Research Report
  • [Publications] Ikeda, Hiroshi; Asaba, Hideki; Takeuchi, Yasushi: J. Chem. Eng. Japan. 21. 91-97 (1988)

    • Related Report
      1987 Annual Research Report
  • [Publications] Takeuchi, Yasushi; Suzuki, Takashi; Arai, Hironori: J. Chem. Eng. Japan. 21. 98-100 (1988)

    • Related Report
      1987 Annual Research Report
  • [Publications] 三宅通博,堀井正俊,吉田哲志,鈴木喬: 石膏と石灰(Gypsum & Lime). 209. 16-21 (1987)

    • Related Report
      1987 Annual Research Report
  • [Publications] 化学工学協会(編): "化学工学便覧(改訂5版) 第12章 吸着.イオン交換の項" 丸善株式会社, 1392 (1988)

    • Related Report
      1987 Annual Research Report
  • [Publications] Furuyaf, Eiji; Takeuchi, Yasushi; Noll, K.E.: "IUPAC Symposium on the Characterization of Porous Solids (Studies on Diffusion of Phenols with in a Porous Synthetic Adsorbent)" ELSEVIER SCIENCE PUBLISHERS, (1988)

    • Related Report
      1987 Annual Research Report
  • [Publications] Takeuchi,Yasushi: World Congress 【III】 of Chemical Engineering(Proceedings). 【II】. 882-885 (1986)

    • Related Report
      1986 Annual Research Report
  • [Publications] Furuya,Eiji: World Congress 【III】 of Chemical Engineering(Proceedings). 【II】. 817-820 (1986)

    • Related Report
      1986 Annual Research Report
  • [Publications] 鈴木喬: 石膏と石灰. 204. 314-320 (1986)

    • Related Report
      1986 Annual Research Report
  • [Publications] Takeuchi,Yasushi: Journal of Chem.Eng.of Japan(received). 20. (1987)

    • Related Report
      1986 Annual Research Report
  • [Publications] Takeuchi,Yasushi: Journal of Chem.Eng.of Japan(received). 20. (1987)

    • Related Report
      1986 Annual Research Report

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Published: 1987-03-31   Modified: 2016-04-21  

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