Syntheses and Properties of Allene・Cumulene Compounds Connecting with Non-benzenoid Aromatics
| Project/Area Number |
61470022
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| Research Category |
Grant-in-Aid for General Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
有機化学一般
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| Research Institution | Utsunomiya University |
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Principal Investigator |
TODA Takashi Utsunomiya University, Faculty of Engineering, 工学部, 教授 (20004278)
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| Co-Investigator(Kenkyū-buntansha) |
YOSHIDA Masaaki Utsunomiya University, Faculty of Engineering, 工学部, 助手 (90114173)
MINABE Masahiro Utsunomiya University, Faculty of Engineering, 工学部, 助教授 (40007993)
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| Project Period (FY) |
1986 – 1988
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| Project Status |
Completed (Fiscal Year 1988)
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| Budget Amount *help |
¥7,000,000 (Direct Cost: ¥7,000,000)
Fiscal Year 1988: ¥400,000 (Direct Cost: ¥400,000)
Fiscal Year 1987: ¥1,000,000 (Direct Cost: ¥1,000,000)
Fiscal Year 1986: ¥5,600,000 (Direct Cost: ¥5,600,000)
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| Keywords | Cycloheptatrienylidene-ethenes / Cyclopentadienylidene-ethenes / Cycloheptatrienylidenecyclopentadienylidene-ethenes / Aminocinnamhydrazides / Styrilformazans / 縮合多環芳香族化合物 / シクロヘプタシクロペンタジエニリデンエテン類 / テトラフェニルシクロペンテニルエテン類 / 環状付加反応 / アセチルアミノピレン類 / ベンゾ〔a〕インデノ〔1、2、3-cd〕アズレン類 / テトラアリールサイクロン誘導体 / シクロヘプタトリエニリデンシクロペンチジエニリデンエチレン誘通体 / アリールフルオニリデン誘導体 / アリールプロパジェン誘導体 / 熱二量化反応 / シクロプロペニリデンエテン類 / シクロペンタジェニリデンエテン類 / シクロヘプタトリエニリデンシクロペンタジェニリデンエテン類 / 【S_2】よりの発光 / ピラゾロン誘導体の生成 |
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| Research Abstract |
The purpose of our project is to synthesize cumulated compounds which possess conjugate system with non-benzenoid aromatics such as cycloheptatrienylidene, cyclopentadienylidene or cyclopropenylidenes, and to investigate chemical and physical properties of those novel conjugate compounds.
For this, arylcycloheptatrienylidene-ethenes were synthesized and it was found that those compounds readily gave three different kinds of dimer which properties were also investigated.
Some cyclopentadienylideneethenes have been reported, but their thermal unstability did not allow detailed studies. We found that substitution of hydrogen atom at the C-1 position by bromine atom makes those system stable and some cyclopentadienylidene-ethenes were obtained. Several physical properties and thermal dimerization reactions of the cyclopentadienylidenes including some arylallene derivatives were investigated. As the results, the dimerization mechanisms are established.
Syntheses of cyclopropenylidene derivatives have not been succeeded yet. Further attempts will be made in feature. Additional research has been done about reactions of diphenylcyclopropenone with hydrazines and multiple reactivities of this system has been explored to give pyrazole derivatives via cinnamhydrazides and also styrilformazan derivatives.
Several pyrene derivatives and benz[a]indeno[1,2,3-cd]azulene derivatives were synthesized and their chemical properties were investigated as new materials for complex formation and for arylallene derivatives' syntheses.
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Report
(4 results)
Research Products
(17 results)
