| Project/Area Number |
61470083
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| Research Category |
Grant-in-Aid for General Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
有機工業化学
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| Research Institution | Hokkaido University |
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Principal Investigator |
SANADA Yuzo Faculty of Engineering, Hokkaido University, 工学部, 教授 (50109485)
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| Co-Investigator(Kenkyū-buntansha) |
MORITOMI Hiroshi Faculty 10c. cit, 工学部, 助手 (30133713)
YOKONO Tetsuro Faculty 10c. cit, 工学部, 助手 (50109500)
CHIBA Tadatoshi Faculty 10c. cit, 工学部, 助教授 (70001295)
YOKOYAMA Susumu Faculty of Enbineering, Hokkaido University, 工学部, 助教授 (30001291)
真田 雄三 北海道大学, 工学部金属化学研究施設, 教授 (50109485)
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| Project Period (FY) |
1986 – 1987
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| Project Status |
Completed (Fiscal Year 1987)
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| Budget Amount *help |
¥5,500,000 (Direct Cost: ¥5,500,000)
Fiscal Year 1987: ¥1,200,000 (Direct Cost: ¥1,200,000)
Fiscal Year 1986: ¥4,300,000 (Direct Cost: ¥4,300,000)
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| Keywords | Tar pitch / Carbon microbeads / Characterization / High pressure carbonization / High temperature high pressure NMR / 高温高圧常磁性共鳴 / ピッチ / n-パラフィン |
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| Research Abstract |
The carbon microbeads were found to be produced under very mild conditions at 823k, under nitrogen pressure of 2MPa in the mixture of n-paraffin/coal tar pitch system. The co-carbonization of n-paraffin with pitch under mild pressure and temperature conditions may be viable method for the production mechanism of carbon microbeads.
Details of the formations mechanism of carbon microbeads and anlaysis of its structure have been investigated using high temperature, high pressure 'H-NMR, -ESR, TG and DTA. Carbon microbeads were formed from tar pitch under circumstance of super critical products resulted by thermally crakcking of paraffin. The data obtained by different techniques are in good agreement with each other.
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