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Amorphization of the Intermetallic Compounds by Hydrogen Absorption and the Magnetic Properties of the Amorphous Alloys

Research Project

Project/Area Number 61550519
Research Category

Grant-in-Aid for General Scientific Research (C)

Allocation TypeSingle-year Grants
Research Field 金属材料(含表面処理・腐食防食)
Research InstitutionTOHOKU UNIVERSITY

Principal Investigator

AOKI Kiyoshi  Institute for Materials Research, Tohoku University, 金属材料研究所, 助手 (70124542)

Co-Investigator(Kenkyū-buntansha) KIMURA Hisamichi  Institute for Materials Research, Tohoku University, 金属材料研究所, 助手 (00161571)
MASUMOTO Tsuyoshi  Institute for Materials Research, Tohoku University, 金属材料研究所, 教授 (20005854)
Project Period (FY) 1986 – 1987
Project Status Completed (Fiscal Year 1987)
Budget Amount *help
¥1,700,000 (Direct Cost: ¥1,700,000)
Fiscal Year 1987: ¥100,000 (Direct Cost: ¥100,000)
Fiscal Year 1986: ¥1,600,000 (Direct Cost: ¥1,600,000)
KeywordsHydrogen Absorption / Amorphous Alloys / Intermetallic Compound / Laves Phase / 磁気的性質 / 水素化物 / アモルファス / 非晶質 / ラーベス相 / 希土類合金 / 磁性 / 磁化
Research Abstract

Hydrogen-induced amorphization(HIA) has become one of the most attractive methods for producing amorphous alloys without rapid quenching. However, amorphizing alloy systems, the structure, the progress, and the mechanism of HIA are still uncertain. The purposes of the present investigation are to examine the nature of HIA, to obtain a detailed understanding of the progress, and to examine the magnetic properties of the resultant amorphous alloys. By hydrogenation of the Laves phase RM_2 compounds( R = a rare earth metal, M = Fe, Co, Ni), the amorphous RM_2H_2 alloys were synthesized where the decomposition of the compounds into the RH_2 and M(or an intermetallic compound) is suppressed because of low diffusion rates of the metallic atoms. The whole crystalline phase does not transform to the amorphous state at a time, but the amorphous phase nucleates and grows with increasing hydrogen conten. The magnetic properties of the hydrogen induced amorphous alloys are identical to those of the hydrogenated amorphous alloys, suggesting similarity of their structures.

Report

(2 results)
  • 1987 Final Research Report Summary
  • 1986 Annual Research Report
  • Research Products

    (16 results)

All Other

All Publications (16 results)

  • [Publications] K.Aoki;K.Fukamichi;T.Yamamoto and T.Masumoto: Sci.Rep.Res.Inst.Tohoku Univ.,. A-33. 163-172 (1986)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1987 Final Research Report Summary
  • [Publications] K.Aoki;T.Yamamoto and T.Masumoto: Scr.Met.,. 21. 27-31 (1987)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1987 Final Research Report Summary
  • [Publications] K.Chattopadyhay;K.Aoki and T.Masumoto: Scr.Met.,. 21. 365-369 (1987)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1987 Final Research Report Summary
  • [Publications] K.Aoki;T.Yamamoto;Y.Sato;K.Fukamichi and T.Masumoto: Acta Metall.,. 35. 2465-2470 (1987)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1987 Final Research Report Summary
  • [Publications] E.Matusbara;Y.Ohzora;Y.Waseda;K.Aoki;K.Fukamichi and T.Masumoto: Z.Naturforschung. 42a. 582-586 (1987)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1987 Final Research Report Summary
  • [Publications] K.Aoki;M.Nagano;A.Yanagitani and T.Masumoto: J.Appl.Phys.62. 3314-3317 (1987)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1987 Final Research Report Summary
  • [Publications] K.Aoki, T.Yamomoto, K.Fukamichi and T.Masumoto: "Hydrogenation of Amorphous and Crystalline Gd-Co Alloys" Sci.Rep. Res.Inst. Tohoku University. A-33. 163-172 (1986)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1987 Final Research Report Summary
  • [Publications] K.Aoki, T.Yamamoto and T.Masumot: "Hydrogen Induced Amorphization of RNi_2 Laves Compound" Scripta Metallurgica. 21. 27-31 (1987)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1987 Final Research Report Summary
  • [Publications] K.Chattopadyhay, K.Aoki and T.Masumoto: "The Nature of Hydrogen Induced Amorphization of SmNi_2 Laves Compound" Scripta Metallurgica. 21. 365-369 (1987)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1987 Final Research Report Summary
  • [Publications] K.Aoki, T.Yamamoto, Y.Satoh, K.Fukamichi and T.Masumoto: "Amorphization of the CeFe_2 Laves Phase Compound by Hydrogen Absorption" Acta Metallurgica. 35. 2465-2470 (1987)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1987 Final Research Report Summary
  • [Publications] E.Matsubara,Y.Ohzora, Y.Waseda,K.Aoki,K.Fukamichi and T.Masumoto: "X-Ray Diffraction Study of Amorphous CeFe_2H_3 and GdFe_2 Alloys Produced by Hydrogenation" Z.Naturforschung. 42a. 582-586 (1987)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1987 Final Research Report Summary
  • [Publications] 青木清,山本俊哉,深道和明,増本健: Sci.Pep.Res.Inst.Tohoku Univ.A-33. 163-172 (1986)

    • Related Report
      1986 Annual Research Report
  • [Publications] 青木清,山本俊哉,増本健: Scripta Metallurgica. 21(1). 27-31 (1987)

    • Related Report
      1986 Annual Research Report
  • [Publications] K.チャトパディ,青木清,増本健: Scripta Metallurgica. 21(3). (1987)

    • Related Report
      1986 Annual Research Report
  • [Publications] 青木清,山本俊哉,佐藤幸人,深道和明,増本健: Acta Metallurgica.

    • Related Report
      1986 Annual Research Report
  • [Publications] 青木清,永野貢,柳谷彰彦,増本健: J.Appl.Phys.

    • Related Report
      1986 Annual Research Report

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Published: 1987-03-31   Modified: 2016-04-21  

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