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Synthesis and functions of heteropolycyclic compounds having long straight-chain alkyl groups

Research Project

Project/Area Number 61550628
Research Category

Grant-in-Aid for General Scientific Research (C)

Allocation TypeSingle-year Grants
Research Field Synthetic chemistry
Research InstitutionSaitama University

Principal Investigator

HISAO NISHI  Faculty of Engineering, Saitama University,Professor, 工学部, 教授 (80008804)

Co-Investigator(Kenkyū-buntansha) KIYOSHI KITAHARA  Faculty of Engineering, Saitama University,Assistant, 工学部, 助手 (90107376)
Project Period (FY) 1986 – 1987
Project Status Completed (Fiscal Year 1987)
Budget Amount *help
¥2,200,000 (Direct Cost: ¥2,200,000)
Fiscal Year 1987: ¥700,000 (Direct Cost: ¥700,000)
Fiscal Year 1986: ¥1,500,000 (Direct Cost: ¥1,500,000)
KeywordsLong straight-chain alkyl group / Organic thin film / 有機顔料
Research Abstract

Carbazole dioxazinos [4] and [5] having long straight-chain alkyl groups were synthesized. Demethanolation and dehydrogenation of [3] gave a linear structure [4] and an angular structure [5], respectively. Introduction of the long straight-chain alkyl groups to carbazole dioxazine results in lowering their melting and decomposition points and a little bathochromic shift was observed in visible spectra. Absorption and elimination of acid gas on the evaporated films of carbazole dioxazines were investigated. Furthermore, Langmuir-Blodgett films of these compounds were prepared.

Report

(2 results)
  • 1987 Final Research Report Summary
  • 1986 Annual Research Report
  • Research Products

    (8 results)

All Other

All Publications (8 results)

  • [Publications] 西久夫: 日本化学会誌. (1988)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1987 Final Research Report Summary
  • [Publications] 西久夫: 日本化学会誌. 911-915 (1987)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1987 Final Research Report Summary
  • [Publications] 西久夫: 日化第55秋季年会講演予稿集. II. 412 (1987)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1987 Final Research Report Summary
  • [Publications] Hisao NISHI: "Synthesis and the Structure of Carbazole Dioxazines having Long Straight-Chain Alkyl Groups" Nippon Kagaku Kaishi. 6. (1988)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1987 Final Research Report Summary
  • [Publications] Hisao HISHI: "Synthesis of Carbazole Dioxazines having Long Straight-Chain Alkyl Groups (1)" 55th National Meeting of the Chemical Society of Japan. II. 412 (1987)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1987 Final Research Report Summary
  • [Publications] 西久夫: 日本化学会誌. 5月号. (1987)

    • Related Report
      1986 Annual Research Report
  • [Publications] 西久夫: 日本化学会誌.

    • Related Report
      1986 Annual Research Report
  • [Publications] 中原弘雄: 日本化学会第53秋季年会講演予稿集. 【II】. 877-(3W26) (1986)

    • Related Report
      1986 Annual Research Report

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Published: 1987-03-31   Modified: 2016-04-21  

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