| Project/Area Number |
61850143
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| Research Category |
Grant-in-Aid for Developmental Scientific Research
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| Allocation Type | Single-year Grants |
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| Research Field |
無機工業化学
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| Research Institution | Faculty of Science and Engineering, Kinki University |
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Principal Investigator |
TANAKA Masami Professor, Faculty of Science and Engineering, Kinki University, 理工学部, 教授 (70081312)
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| Co-Investigator(Kenkyū-buntansha) |
柏 保介 泉陽硝子工業株式会社, 開発室, 研究員
白金 一浩 岡村製油株式会社, 技術部, 研究員
吉田 元昭 日本板硝子株式会社, 中央研究所, 主席研究員
ITO Seisiro Associate Professor, Faculty of Science and Engineering, Kinki University, 理工学部, 助教授 (40088448)
SHIRAGANE Kzauhiro Researcher, Technical Division, Okamura Oil Mill, Ltd.
KASHIWA Yasusuke Researcher, Development Division, Senyoh Glass Industry Co., Ltd.
YOSHIDA Motoaki Associate Chief Researcher, Central Research Laboratory, Nippon Sheet Glass Co.,
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| Project Period (FY) |
1986 – 1987
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| Project Status |
Completed (Fiscal Year 1987)
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| Budget Amount *help |
¥7,800,000 (Direct Cost: ¥7,800,000)
Fiscal Year 1987: ¥2,000,000 (Direct Cost: ¥2,000,000)
Fiscal Year 1986: ¥5,800,000 (Direct Cost: ¥5,800,000)
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| Keywords | Fine Particle / Fine Powder / Colloidal Particle / Oxide Particle / アルミニウムの白色着色 / 金属酸化物 / コロイド / 湿式粉体合成 |
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| Research Abstract |
Ultrafine particles of alumina combined with anionic surfactants were prepared through the processes including (1) the preparation of the hydrosol of hydrated alumina, (2) the coagulation of hydrosol with the solution of a surfactant, (3) the flashing in an organic solvent of hydrated alumina particles from the coagu- lated hydrosol, and (4) the separation of the solvent from the particles by heating. These particles were dehydrated throught the heat treatment at tempera- tures of 180 to 200゜C under reduced pressure. The alumina particles with surfactants after the above dehydration treatment were estimated to be less than 10nm (average about 5nm) in diameter, and were easily dispersed with trans- parency into a variety of organic solvents and plastics.
Through the research of the hydrosol in the system gydrated titania-hydrated alumina for the improvement in weatherability (stability to ultraviolet radiation) of the fine particles of hydrated titania, a novel technique was found for the white coloring of the anodic oxide film on the aluminum metal surface: The coloring was performed by the electrolytic deposition of the fine particles of hydrated titania into pores of the oxide film, which was subjected to the secondary electrolysis in the hydrated titania sol. Much improvement in weather- ability was achieved by the electrolytic dephosition of the fine particles of hyudrated alumina. instead of hydrated titania, into pores of the anodic oxide film kept in the hydrated alumina sol. The coloring of a high grade in whiteness was meterialized by tghe electrolytic deposition of the fine particles in the system hydrated alumina-hydrated calcia into pores of the oxide film.
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