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Research and Development for High Performance Electrode Materials and Lectrode Structures in Molten Carbonate Fuel Cells

Research Project

Project/Area Number 61850145
Research Category

Grant-in-Aid for Developmental Scientific Research

Allocation TypeSingle-year Grants
Research Field 工業物理化学
Research InstitutionTOHOKU UNIVERSITY

Principal Investigator

UCHIDA Isamu  Department of Applied Chemistry, Faculty of Engineering, 工学部, 教授 (50005302)

Co-Investigator(Kenkyū-buntansha) 金子 彰一  東京ガス株式会社, エネルギー変換技術開発プロジェクトチーム, 課長
NISHINA Tatsuo  Department of Applied Chemistry, Faculty of Enginnerinn, 工学部, 助手 (60172673)
ITAYA Kingo  Department of Engineering Science,Faculty of Engineering, 工学部, 助教授 (40125498)
KANEKO Shouichi  Tokyo Gas Company,Energy Conversion Project Group
Project Period (FY) 1986 – 1987
Project Status Completed (Fiscal Year 1987)
Budget Amount *help
¥7,500,000 (Direct Cost: ¥7,500,000)
Fiscal Year 1987: ¥1,900,000 (Direct Cost: ¥1,900,000)
Fiscal Year 1986: ¥5,600,000 (Direct Cost: ¥5,600,000)
KeywordsMolten carbonate fuel cell / Porous gas diffusion electrode / Hydrogen oxidation / Oxygen reduction / Electrocatalysis / 複合電着皮履法 / ラネーニツケル電極 / 溶融塩腐食 / 界面インピーダンス解析 / 酸素電極反応 / 電極触媒 / 電極材料 / 電極構造
Research Abstract

Electrochemical stduies on hydrogen oxidation and oxygen reduction processes on molten Li/K carbonates have been carried out from the view points.of i) Kinetic parameters and reaction mechanism, ii)effects of electrode materials, and iii) design and fabrication of porous gas deffusion structures. Corrosion studies on metals were also conducted in the melt without hydrogen. Emphasis was placed on the development of a new type of porous electrode. Composit electrolytic coating of Raney alloy powder on nickel matrices with large pores was proposed for the fabrication of high perpormance electrode strucutures.

Report

(2 results)
  • 1987 Final Research Report Summary
  • 1986 Annual Research Report
  • Research Products

    (16 results)

All Other

All Publications (16 results)

  • [Publications] UCHIEA,I: Journal Electroanalytical Chemistry. 206. 229-239 (1986)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1987 Final Research Report Summary
  • [Publications] UCHIDA,I: Journal Electroanalytical Chemistry. 206. 241-252 (1986)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1987 Final Research Report Summary
  • [Publications] UCHIDA,I: Journal Electroanalytical Chemistry. 209. 125-133 (1985)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1987 Final Research Report Summary
  • [Publications] 仁科辰夫: 電気化学. 56. (1988)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1987 Final Research Report Summary
  • [Publications] 仁科辰夫: 電気化学. (1988)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1987 Final Research Report Summary
  • [Publications] 内田 勇: 日本化学会誌. (1988)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1987 Final Research Report Summary
  • [Publications] NISHINA.T, MUGIKURA.Y, and ITAYA.K: "Gas Electrode Reactions in Molten Carbonate Media. Part 1. Exchange Current Density of Oxygen Reduction in (Li+K)CO_3 Eutectic at 650゜C" J. Electgroanal< Chem.206. 229-239 (1086)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1987 Final Research Report Summary
  • [Publications] MUGIKURA.Y, NISHINA.T, and ITAYA.K: "Gas Electrode Reactions in Molten Carbonate Media. Part 2. Oxygen Reduction Kinetics on Conductive Oxide Electrodes in (Li<plus-minus>K)CO_3 Eutectic at 650゜ C" J. Electroanal. Chem.206. 241-252 (1986)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1987 Final Research Report Summary
  • [Publications] UCHIDA.I, NISHINA.T, MUGIKURA.Y, and ITAYA.K: "Gas Electrode Reactions in Molten Carbonate Media. Part 3. Temperaure Dependence of Oxygen Reduction Kinetics in (li+K)CO_3 Eutectic" J. Electroanal. Chem.209. 125-133 (1986)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1987 Final Research Report Summary
  • [Publications] NISHINA.T, and UCHIDA.I: "Potential-po^<2-> Diagrams of Soluble Oxygen Species in Molten Alkali Carbonates and Oxygen Reduction Mechanism" Denki-Kagaku. 56. - in press (1988)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1987 Final Research Report Summary
  • [Publications] NISHIAN.T, and UCHIDA.I: "Integration Analysis of Coulostatic Transients and Its Application to the Oxygen Reduction in Molten Carbonate at 750゜C" Denki-gagaku. 56. - in press (1988)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1987 Final Research Report Summary
  • [Publications] UCHIDA,I: Jurnal of Electroanalytical Chemistry. 206. 229-239 (1986)

    • Related Report
      1986 Annual Research Report
  • [Publications] UCHIDA,I: Journal of Electroanalytical Chemistry. 206. 241-252 (1986)

    • Related Report
      1986 Annual Research Report
  • [Publications] UCHIDA,I: Journal of Electroanalytical chemistry. 209. 125-133 (1986)

    • Related Report
      1986 Annual Research Report
  • [Publications] 仁科辰夫: 日本化学会誌.

    • Related Report
      1986 Annual Research Report
  • [Publications] 仁科辰夫: 電気化学.

    • Related Report
      1986 Annual Research Report

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Published: 1987-03-31   Modified: 2016-04-21  

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