Construction of Surface Plasmon Spectrometer for Studies of Adsorption and Organic Films.
Project/Area Number |
61850156
|
Research Category |
Grant-in-Aid for Developmental Scientific Research
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Allocation Type | Single-year Grants |
Research Field |
高分子物性
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Research Institution | Mie University |
Principal Investigator |
AKIRA TAKAHASHI Mie University, Faculty of Engineering, Prof., 工学部, 教授 (70023009)
|
Co-Investigator(Kenkyū-buntansha) |
TADAYA KATO Mie University, Faculty of Engineering, Prof., 工学部, 教授 (80023133)
|
Project Period (FY) |
1986 – 1987
|
Project Status |
Completed (Fiscal Year 1987)
|
Budget Amount *help |
¥4,300,000 (Direct Cost: ¥4,300,000)
Fiscal Year 1987: ¥500,000 (Direct Cost: ¥500,000)
Fiscal Year 1986: ¥3,800,000 (Direct Cost: ¥3,800,000)
|
Keywords | Surface Plasmon / Surface Polarition / Layer Thickness / Adsorption / Polymer Adsorption / 吸着 / 薄膜 / プラズモン / 分光器 |
Research Abstract |
A surface plasmon spectrometer, which is suitable for studies of polymer adsorption as well as layer thickness measurement of deposited layers of organic matters, was designed and constructed. Both the He-Ne laser light source arm and the detector photodiode arm are independently rotatable by stepping motors with the precision of 0.01゜ per pulse. The sensitivity of thickness measurement was <plus-minus> 0.1 nm. To determine the thcikness and the refractive index of layers on a metalic films (e. g. Ag), expressions for reflectivity and surface polariton dispersion equation are solved by curve fitting method, and a computor program was offered. Using the method, adsorption of polyethylene oxide from aqueous solutions onto a silver surface was examined and both adsorbance and adsorbed layer thickness were obtained preciselof
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Report
(2 results)
Research Products
(18 results)