| Project/Area Number |
62430017
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| Research Category |
Grant-in-Aid for General Scientific Research (A)
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| Allocation Type | Single-year Grants |
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| Research Field |
工業物理化学
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| Research Institution | The University of Tokyo |
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Principal Investigator |
KITAZAWA Koichi (1988) Faculty of Engineering, The University of Tokyo, 工学部, 教授 (90011189)
笛木 和雄 (1987) 東京大学, 工学部, 教授 (80010750)
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| Co-Investigator(Kenkyū-buntansha) |
MAKOTO Misono Faculty of Engineering, The University of Tokyo, 工学部, 教授 (20011059)
合志 陽一 東京大学, 工学部, 教授 (90111468)
北沢 宏一 東京大学, 工学部, 教授 (90011189)
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| Project Period (FY) |
1987 – 1988
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| Project Status |
Completed (Fiscal Year 1988)
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| Budget Amount *help |
¥39,200,000 (Direct Cost: ¥39,200,000)
Fiscal Year 1988: ¥2,600,000 (Direct Cost: ¥2,600,000)
Fiscal Year 1987: ¥36,600,000 (Direct Cost: ¥36,600,000)
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| Keywords | Superconductivity / Oxygen Vacancy / Valence control / Perovskite / Catalytic combution / XPS / STM / 薄膜触媒 / ペロブスカイト型複合酸化物 / ESCA / 異常原子価 / 薄膜 / 酸化物超伝導体 |
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| Research Abstract |
[1] Valence control and analysis of perovskite-type oxides. The relationship between the oxygen vacancy, oxidation state and the superconductivity has been quantitatively investigated. The highest Tc of 38 K was obtained for (La_<1-x>Sr_x)_2CuO_4 when the oxidation number of Cu was 2,16. The much greater influenece of B-site substitution than A-site substitution with paramagnetic ion, demonstrated that the supreconductivity is revealed along CuO plane.
[2] Active ceramic catalysts for catalytic combution. By the valence control with A site substitution and by the dispersion of active component on a ZrO_2 support, a highly active catalyst for catalytic combution was obtained. The structure and mechanism have been examined by XPS, IR and EDX measurements.
[3] STM. A versatile and compact STM was constructed and the energy gap was measured for a single crystal of Bi_2Sr_2CaCuOy.
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