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Research on Production of Single Crystals of Compounds having higher Melting Points.

Research Project

Project/Area Number 62550488
Research Category

Grant-in-Aid for General Scientific Research (C)

Allocation TypeSingle-year Grants
Research Field 金属精錬・金属化学
Research InstitutionOsaka University

Principal Investigator

HARA Shigeta  Osaka University, Faculty of Engineerings. Lecturer, 工学部, 講師 (90029116)

Project Period (FY) 1987 – 1988
Project Status Completed (Fiscal Year 1988)
Budget Amount *help
¥2,000,000 (Direct Cost: ¥2,000,000)
Fiscal Year 1988: ¥300,000 (Direct Cost: ¥300,000)
Fiscal Year 1987: ¥1,700,000 (Direct Cost: ¥1,700,000)
KeywordsDensity / Surface tension / LiF / NaF / KF / MgF_2 / CaF_2 / SrF_2 / BaF_2 / GdF_3 / NdF_3 / LaF_3 / Al_2O_3 / Ti_2O_3 / LiNbO_3 / LiTaO_3 / CaO・ Al_2O_3 / BaO / Pt-Rh alloy / Molybdenum / melt / 最大泡圧法 / 融体 / 超高温 / Fe_2O_3 / Fe_2O_3-CaO / 超高温炉 / モリブデン / 高周波誘導加熱炉 / アルミナ / 気相酸素分圧ガス浄化
Research Abstract

This work has been carried out to develop basic technologies and informations for production of single crystals having higher melting point, finacially suportedby 2-years grant-in-aid for scientific research. Especially, research projects are focussed to examine reactions between the melt and container materials, and also to measure the physicochemical properties as the surface tension and the density. Samples used in this work are LiF, NaF, KF, MgF_2, CaF_2, SrF_2, BaF_2, GaF_3, NdF_3, LaF_3 as fluorides, Al_2O_3, Ti_2O_3 as single component oxides, and LuNbO_3, LiTaO_3, CaO・Al_2O_3 and BaO ・ Ti_2O_3 as binary oxides. If melting point of a compound is below 1873K, container materials used were mainly platium and plainum-rhodium alloy, which showed to be stable to the melts. However, if the melting point is above 1873K, molybdenum was used as the container. In the case, it was observed that small amount of molybdenum dissolved into LiTaO_3, and BaO ・ Ti_2O_3 melts, even if the melts were kept under an atmosphere having lower oxygen potential. The other oxide melts can be kept stablely under the atmosphere. Two types of furnaces were used to measure the surface tensions and densities. One is a molybdenum winding furnace and another is a induction heating furnace. The Archimedean method was used for measurements of the densities, and the maximum bubble pressure method was used for measurements of the densities and surface tensions of melts having higher melting points. From the measurenents, physico-chemical properties were analyzed and discussed.
From the results, technology for choise of container materials and also for measurements of densities and surface tensions of the melts were established to produce single crystals of the compounds having higher melting points up to 2400K.

Report

(3 results)
  • 1988 Annual Research Report   Final Research Report Summary
  • 1987 Annual Research Report
  • Research Products

    (12 results)

All Other

All Publications (12 results)

  • [Publications] 原茂太,萩野和巳: 鉄と鋼. 75. 439-445 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1988 Final Research Report Summary
  • [Publications] S.Hara,;K.Irie,;D.R.Gaskell,;K.Ogino.: Trans.JIM. 29. 977-989 (1988)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1988 Final Research Report Summary
  • [Publications] S.Hara,;K.Irie,;D.R.Gaskell,;K.Ogino.: Trans.JIM. 29. 990-1002 (1988)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1988 Final Research Report Summary
  • [Publications] 原茂太,萩野和巳: 日本金属学会誌. 52. 1098-1102 (1988)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1988 Final Research Report Summary
  • [Publications] Shigeta Hara; Kazumi Ogino: "Density and Surface Tension of Melts in the CaF_2-CaO-SiO_2 System." Tetsu-to-Hagane. 75. 439-445 (1989)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1988 Final Research Report Summary
  • [Publications] S.Hara;K.Irie;D.R.Gaskell;K.Ogino: "Densities of Melts in the FeO-Fe_2O_3-CaO and FeO-Fe_2O_3- 2CaO・SiO_2 Systems." Trans.JIM.29. 977-989 (1988)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1988 Final Research Report Summary
  • [Publications] S.Hara;K.Irie;D.R.Gaskell;K.Ogino: "Densities of Melts in the FeO-Fe_2O_3-BaO System." Trans.JIM.29. 990-1002 (1988)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1988 Final Research Report Summary
  • [Publications] Shigeta Hara; Kazumi Ogino: "Density and Surface Tension of Melts in the CaF_2-MO(M:Mg,Ca,Ba) Systems." Nipon Kinzoku Gakkai-Shi. 52. 1098-1102 (1988)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1988 Final Research Report Summary
  • [Publications] 原茂太,荻野和巳: 鉄と鋼. 57. 439-445 (1989)

    • Related Report
      1988 Annual Research Report
  • [Publications] S.Hara;K.Irie;D.R.Gaskell;K.Ogino: Trans.JIM. 29. 977-989 (1988)

    • Related Report
      1988 Annual Research Report
  • [Publications] S.Hara;K.Irie;D.R.Gaskell;K.Ogino: Trans.JIM. 29. 990-1002 (1988)

    • Related Report
      1988 Annual Research Report
  • [Publications] 原茂太、荻野和巳: 日本金属学会誌. 52. 1089-1102 (1988)

    • Related Report
      1988 Annual Research Report

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Published: 1987-04-01   Modified: 2016-04-21  

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