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Preparation and Functinalization of cyclophanes as Model Compounds

Research Project

Project/Area Number 62550637
Research Category

Grant-in-Aid for General Scientific Research (C)

Allocation TypeSingle-year Grants
Research Field Synthetic chemistry
Research InstitutionKyushu University

Principal Investigator

TASHIRO Masashi  Institute of Advanced Material Stucy, Kyushu University, Professor, 機能物質科学研究所, 教授 (40038576)

Co-Investigator(Kenkyū-buntansha) TSUGE Akihiko  Institute of Advanced Material Study, Kyushu University, Assistant, 機能物質科学研究所, 助手 (80179986)
TAKAHASHI Kazufumi  Institute of Advanced Material Study, Kyushu University, Assistant, 機能物質科学研究所, 助手 (40179479)
Project Period (FY) 1987 – 1988
Project Status Completed (Fiscal Year 1988)
Budget Amount *help
¥2,000,000 (Direct Cost: ¥2,000,000)
Fiscal Year 1988: ¥500,000 (Direct Cost: ¥500,000)
Fiscal Year 1987: ¥1,500,000 (Direct Cost: ¥1,500,000)
KeywordsOrganic Synthesis / Selective Synthesis / Protective Group / Partial Redcution / Metacyclophanes / 電荷移動錯体 / 分子内電荷移動錯体 / 〔n.m.l〕メタシクロファン / オルトシクロファン / 包接機能 / 可逆的光開環-閉環反応
Research Abstract

Many [2.2]-, [2.2.2.2]- [2.1.2.1]-Metacyclophanes, which having various functional groups, were prepared from monosubstituted benzenes such as toluene and anisole by using terr-butyl group as a positional protective function. Also metacyclophanequinones were prepared by partial reduction of the corresponding metacyclophanequinones or oxidation of the corresponding hydroxy-metacyclophanes in order to obtain CT-complexes like quinhydrones. Unfortunatcly, such complexes could not formed in any cases.
However, it was first found that the metacyclophanes have very differennt reactivities for various electro-philic reagents from usual aromatic compounds.

Report

(3 results)
  • 1988 Annual Research Report   Final Research Report Summary
  • 1987 Annual Research Report
  • Research Products

    (23 results)

All Other

All Publications (23 results)

  • [Publications] 又賀駿太郎: Journal of Organic Chemistry. 52. 2653-2656 (1987)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1988 Final Research Report Summary
  • [Publications] 田代昌士: Journal of Organic Chemistry. 52. 3196-3199 (1987)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1988 Final Research Report Summary
  • [Publications] 村上慎一: Chemistry Letters. 5-8 (1988)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1988 Final Research Report Summary
  • [Publications] 田代昌士: 九州大学総合理工学研究科報告. 10. 175-179 (1988)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1988 Final Research Report Summary
  • [Publications] 村上慎一: 染料と薬品. 33. 4-14 (1988)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1988 Final Research Report Summary
  • [Publications] 田代昌士: Journal of Organic Chemistry. 54. 451-458 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1988 Final Research Report Summary
  • [Publications] Shuntaro Mataka: "[3.3]Orthocyclophanes with Facing Benzene and Naphthalene" Journal of Organic Chemistry. 52. 2653-2656 (1987)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1988 Final Research Report Summary
  • [Publications] Masashi Tashiro: "Metacyclophanes and Related Compounds. 19. Reaction of 8-Methoxy[2.2]-metacyclophanes with Iodine in Benzene Solution. A Preparative Route of Pyrenes" Journal of Organic Chemistry. 52. 3196-3199 (1987)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1988 Final Research Report Summary
  • [Publications] Shin-ichi Murakami: "Photochromism of [2.n]Metacyclophan-I-enes Derivatives" Chemistry Letters. 5-8 (1988)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1988 Final Research Report Summary
  • [Publications] Masashi Tashiro: "Metacyclophanes and Related Compounds. 22. Bromination of 8,16-Di-methyl-5-nitro[2.2]metacyclophane with Bromine and N-Bromosuccinimide" The Report of Graduate School of Engineering Sciences, Kyushu University. 10. 175-179 (1988)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1988 Final Research Report Summary
  • [Publications] Masashi Tashiro: "Metacyclophanes and Related Compounds. 21. Nitration of [2.2]metacyclophanes." Journal of Organic Chemistry. 54. 451-458 (1989)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1988 Final Research Report Summary
  • [Publications] 村上慎一: Chemistry Letters. 5-8 (1988)

    • Related Report
      1988 Annual Research Report
  • [Publications] 田代昌士: 九州大学総合理工学研究科報告. 10. 175-179 (1988)

    • Related Report
      1988 Annual Research Report
  • [Publications] 村上慎一: 染料と薬品. 33. 4-14 (1988)

    • Related Report
      1988 Annual Research Report
  • [Publications] 田代昌士: Journal of Organic Chemistry. 54. 451-458 (1989)

    • Related Report
      1988 Annual Research Report
  • [Publications] 田代昌士: Journal of Organic Chemistry. 55. (1989)

    • Related Report
      1988 Annual Research Report
  • [Publications] 田代昌士: Journal of Organic Chemistry. 55. (1989)

    • Related Report
      1988 Annual Research Report
  • [Publications] 大和武彦: Journal pf Chemical Society Perkin Transaction I. 1-7 (1987)

    • Related Report
      1987 Annual Research Report
  • [Publications] 又賀駿太郎: Journal of Organic Chemistry. 52. 2653-2656 (1987)

    • Related Report
      1987 Annual Research Report
  • [Publications] 大和武彦: Journal of Chemical Research. 198-199 (1987)

    • Related Report
      1987 Annual Research Report
  • [Publications] 田代昌士: Journal of Organic Chemistry. 52. 3196-3199 (1987)

    • Related Report
      1987 Annual Research Report
  • [Publications] 村上慎一: Chemistry Letters. 5-8 (1988)

    • Related Report
      1987 Annual Research Report
  • [Publications] 村上慎一: 日本化学会誌. 221-229 (1988)

    • Related Report
      1987 Annual Research Report

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Published: 1987-04-01   Modified: 2016-04-21  

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