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DETERMINATION METHOD OF PARTIAL ELECTRONIC CONDUCTION PARAMETER OF SOLID ELECTROLYTE FOR OXYGEN SENSOR FOR IRON- AND STEELMAKING

Research Project

Project/Area Number 62850123
Research Category

Grant-in-Aid for Developmental Scientific Research

Allocation TypeSingle-year Grants
Research Field 金属精錬・金属化学
Research InstitutionCHIBA INSTITUTE OF TECHNOLOGY

Principal Investigator

SASABE Minoru  CHIBA INSTITUTE OF TECHNOLOGY, DEPARTMENT OF ENGINEERING, PROFESSOR, 工学部, 教授 (00016370)

Co-Investigator(Kenkyū-buntansha) SENOO Hiromi  OOSAKA OXYGEN CO.LTD., ICHIKAWA FACTORY, HEAD DIRECTOR, 計測器機部・市川工場, 工場長
IWASE Masanori  KYOTO UNIVERSITY, DEPARTMENT OF ENGINEERING, ASSOCIATE PROFESSOR, 工学部, 助教授 (00026329)
Project Period (FY) 1987 – 1989
Project Status Completed (Fiscal Year 1989)
Budget Amount *help
¥5,000,000 (Direct Cost: ¥5,000,000)
Fiscal Year 1989: ¥600,000 (Direct Cost: ¥600,000)
Fiscal Year 1988: ¥700,000 (Direct Cost: ¥700,000)
Fiscal Year 1987: ¥3,700,000 (Direct Cost: ¥3,700,000)
KeywordsIron- and Steelmaking / Solid electrolyte / Oxygen sensor / Zirconia / Electronic conductivity / 鉄鋼精錬 / 電子伝導性パラメータ
Research Abstract

An apparatus to determine partial electronic conduction parameter, Pe' , of solid electrolytes for oxygen sensor to determine oxygen contents in molten steel has been developed. Principle of the method has been based on 2 poles impedance method.
The values determined by the apparatus are the same as that by swinkels method. Prominence futures of the apparatus are as follows; 1. Partial electronic conduction parameter of smaller size of solid electrolyte can be measured. 2. Measuring time is much shorter than that of swinkels method.
The partial electronic conduction parameter of commercial grade solid electrolyte of ZrO_2-MgO has been measured by the apparatus. Measured results are as follows; 1. The smaller contents of MgO, the semller Pe'. 2. Different Pe' can be observed when solid electrolytes supplied by different manufacture were observed.

Report

(3 results)
  • 1989 Annual Research Report   Final Research Report Summary
  • 1988 Annual Research Report
  • Research Products

    (24 results)

All Other

All Publications (24 results)

  • [Publications] 雀部実,宋小芳: "ジルコニア固体電解質の熱起電力におよぼす雰囲気の酸素分圧の影響" 鉄と鋼. 76. (1990)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] M.SASABE,他4名: "Development of an Electrochemical Sensor for Determination of Si Contents in Molten Metals" Proc.7th Intl.Conf.on Solid State Ionics.

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] M.SASABE,M.IWASE,他3名: "Collaborate Research Activities of Sensor Sub-Committee of JSPS" Proc.7th Intl.Conf.on Solid State Ionics.

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] M.SASABE,M.IWASE,他3名: "Solid State Sensors Incorporating Auxiliary Electrode for Rapid Determination of Chromium in Molten Iron" Proc.7th Intl.Conf.on Solid State Ionics.

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] M.IWASE: "Rapid Determination of silicon Activities in Hot Metal by Means of Solid State Electrochemical Sensors Equipped with an Auxiliury Electrodes" Scandinavian Journal of Metallugy. 17. 50-56 (1988)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] M.IWASE,H.ABE,H.IRITANI: "Tri-phasec Zirconia Electrolyte for the in-situ Determination of silicon Activities in Hot Metal" Steel Research. 59. 433-437 (1988)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] 雀部実,岩瀬正則,妹尾弘己,他: "製鋼用センサの新しい展開-固体電解質を中心として" 日本学術振興会, 400 (1989)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] M.Sasabe et al.: "Effects of oxygen partial pressure on thermal electromotive force of solid electrolyte of SrO_2 system." Tetsu-to-Hagane, 1990.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] M.Sasabe et al.: "Development of an electrochemical sensor for determination of Si contents in molten metals." Proc.7th Intl.Conf. on Solid state ionics, 1990.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] M.Sasabe, M.Iwase et al.: "Collaborate research activities of sensor sub-committee at JSPS." Proc.7th Intl.Conf. on Solid state ionics, 1990.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] M.Sasabe, M.Iwase et al.: "Solid state sensors incorporating auxiliary electrode for rapid determination of chromium in molten iron." Proc.7th Intl.Conf. on Solid state ionics, 1990.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] M.Iwase: "Rapid determination of silicon activities in hot metal by means of solid state electrochemical sensors equipped with an auxiliary electrodes." Scandinavian Journal of Metallury, 17(1988) p.p.50-56.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] M.Iwase et al.: "Tri-phase zirconia electrolyte for the in-situ determination of silicon activities in hot metal." Steel Research 59(1988) p.p.433-437.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1989 Final Research Report Summary
  • [Publications] 雀部実,宋小芳: "ジルコニア固体電解質の熱超電力におよぼす雰囲気の酸素分圧の影響" 鉄と鋼. 76. (1990)

    • Related Report
      1989 Annual Research Report
  • [Publications] M.SASABE 他4名: "Development of an Electrochemical Sensor for Determination of Si Contents in Molten Metals" Proc.7th Intl.Conf.on Solid State Ionics.

    • Related Report
      1989 Annual Research Report
  • [Publications] M.SASABE,M.IWASE 他3名: "Collaborate Research Activities of Sensor Sub-Committee of JSPS" Proc.7th Intl.Conf.on Sold State Ionics.

    • Related Report
      1989 Annual Research Report
  • [Publications] M.SASABE,M.IWASE 他3名: "Solid state Sensors Incorporating Auxiliary Electrode for Rapid Determination of Chromium in Molten Iron" Proc.7th Intl.Conf.on Solid State Ionics.

    • Related Report
      1989 Annual Research Report
  • [Publications] M.IWASE: "Rapid Determination of silicon Activities in Hot Metal by Means of Solid state Electrochemical Sensors Equippel with on Auxiliury Electrocles" Scandinavian Journal of Metallurgy. 17. 50-56 (1988)

    • Related Report
      1989 Annual Research Report
  • [Publications] M.Iwase,H.ABE H.Iritani: "TriーPnusec Zirconia Electrolyte for the inーsitu Determination of Silicon Activities in Hot Metal" Steel Research. 59. 433-437 (1988)

    • Related Report
      1989 Annual Research Report
  • [Publications] 雀部実,岩瀬正則,妹尾弘己 ほか: "製銅用センサの新しい展開ー固体電解質を中心として" 日本学術振興会, 400 (1989)

    • Related Report
      1989 Annual Research Report
  • [Publications] 宮下正雄,雀部実: 材料とプロセス. 1. 1139 (1988)

    • Related Report
      1988 Annual Research Report
  • [Publications] 浦田栄吉,久保田一,雀部実: 材料とプロセス. 1. 1140 (1988)

    • Related Report
      1988 Annual Research Report
  • [Publications] 先川原正浩,久保田一,雀部実: 材料とプロセス. 1. 1141 (1988)

    • Related Report
      1988 Annual Research Report
  • [Publications] 岩瀬正則: 鉄と鋼. 75. 379-388 (1989)

    • Related Report
      1988 Annual Research Report

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Published: 1987-04-01   Modified: 2016-04-21  

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